{"title":"含钯离子液体修饰的磁性氧化石墨烯纳米复合材料(Fe3O4/GO-IL-Pd)作为硝基苯还原的强力催化剂。","authors":"Farkhondeh Dadvar and Dawood Elhamifar","doi":"10.1039/D4NA00475B","DOIUrl":null,"url":null,"abstract":"<p >A novel palladium-containing ionic liquid-modified magnetic graphene oxide nanocomposite (Fe<small><sub>3</sub></small>O<small><sub>4</sub></small>/GO–IL–Pd) is synthesized and its catalytic performance is studied in the reduction of nitrobenzenes. The Fe<small><sub>3</sub></small>O<small><sub>4</sub></small>/GO–IL–Pd nanocomposite was characterized by using FT-IR, PXRD, SEM, EDS, VSM, and TG analyses. These analyses showed good magnetic properties and high stability of the designed composite. Different derivatives of nitrobenzenes were applied as substrates, giving corresponding anilines in high to excellent yields (89–96%) at short reaction times (10–15 minutes). Also, the stability, reproducibility, and reusability of the Fe<small><sub>3</sub></small>O<small><sub>4</sub></small>/GO–IL–Pd nanocomposite were investigated under applied conditions. A leaching experiment was also performed to study the nature of the Fe<small><sub>3</sub></small>O<small><sub>4</sub></small>/GO–IL–Pd catalyst under the conditions used.</p>","PeriodicalId":18806,"journal":{"name":"Nanoscale Advances","volume":null,"pages":null},"PeriodicalIF":4.6000,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11376075/pdf/","citationCount":"0","resultStr":"{\"title\":\"A Pd-containing ionic liquid modified magnetic graphene oxide nanocomposite (Fe3O4/GO–IL–Pd) as a powerful catalyst for the reduction of nitrobenzenes\",\"authors\":\"Farkhondeh Dadvar and Dawood Elhamifar\",\"doi\":\"10.1039/D4NA00475B\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >A novel palladium-containing ionic liquid-modified magnetic graphene oxide nanocomposite (Fe<small><sub>3</sub></small>O<small><sub>4</sub></small>/GO–IL–Pd) is synthesized and its catalytic performance is studied in the reduction of nitrobenzenes. The Fe<small><sub>3</sub></small>O<small><sub>4</sub></small>/GO–IL–Pd nanocomposite was characterized by using FT-IR, PXRD, SEM, EDS, VSM, and TG analyses. These analyses showed good magnetic properties and high stability of the designed composite. Different derivatives of nitrobenzenes were applied as substrates, giving corresponding anilines in high to excellent yields (89–96%) at short reaction times (10–15 minutes). Also, the stability, reproducibility, and reusability of the Fe<small><sub>3</sub></small>O<small><sub>4</sub></small>/GO–IL–Pd nanocomposite were investigated under applied conditions. A leaching experiment was also performed to study the nature of the Fe<small><sub>3</sub></small>O<small><sub>4</sub></small>/GO–IL–Pd catalyst under the conditions used.</p>\",\"PeriodicalId\":18806,\"journal\":{\"name\":\"Nanoscale Advances\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":4.6000,\"publicationDate\":\"2024-08-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11376075/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nanoscale Advances\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.rsc.org/en/content/articlelanding/2024/na/d4na00475b\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nanoscale Advances","FirstCategoryId":"88","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/na/d4na00475b","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
A Pd-containing ionic liquid modified magnetic graphene oxide nanocomposite (Fe3O4/GO–IL–Pd) as a powerful catalyst for the reduction of nitrobenzenes
A novel palladium-containing ionic liquid-modified magnetic graphene oxide nanocomposite (Fe3O4/GO–IL–Pd) is synthesized and its catalytic performance is studied in the reduction of nitrobenzenes. The Fe3O4/GO–IL–Pd nanocomposite was characterized by using FT-IR, PXRD, SEM, EDS, VSM, and TG analyses. These analyses showed good magnetic properties and high stability of the designed composite. Different derivatives of nitrobenzenes were applied as substrates, giving corresponding anilines in high to excellent yields (89–96%) at short reaction times (10–15 minutes). Also, the stability, reproducibility, and reusability of the Fe3O4/GO–IL–Pd nanocomposite were investigated under applied conditions. A leaching experiment was also performed to study the nature of the Fe3O4/GO–IL–Pd catalyst under the conditions used.