含钯离子液体修饰的磁性氧化石墨烯纳米复合材料(Fe3O4/GO-IL-Pd)作为硝基苯还原的强力催化剂。

IF 4.6 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Farkhondeh Dadvar and Dawood Elhamifar
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引用次数: 0

摘要

合成了一种新型含钯离子液体修饰的磁性氧化石墨烯纳米复合材料(Fe3O4/GO-IL-Pd),并研究了其在硝基苯还原过程中的催化性能。利用傅立叶变换红外光谱、PXRD、扫描电镜、EDS、VSM 和 TG 分析对 Fe3O4/GO-IL-Pd 纳米复合材料进行了表征。这些分析表明所设计的复合材料具有良好的磁性能和高稳定性。以硝基苯的不同衍生物为底物,在较短的反应时间(10-15 分钟)内就能得到相应的苯胺,产率高达 89%至 96%。此外,还研究了 Fe3O4/GO-IL-Pd 纳米复合材料在应用条件下的稳定性、可重复性和可再利用性。还进行了浸出实验,以研究在所用条件下 Fe3O4/GO-IL-Pd 催化剂的性质。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

A Pd-containing ionic liquid modified magnetic graphene oxide nanocomposite (Fe3O4/GO–IL–Pd) as a powerful catalyst for the reduction of nitrobenzenes

A Pd-containing ionic liquid modified magnetic graphene oxide nanocomposite (Fe3O4/GO–IL–Pd) as a powerful catalyst for the reduction of nitrobenzenes

A Pd-containing ionic liquid modified magnetic graphene oxide nanocomposite (Fe3O4/GO–IL–Pd) as a powerful catalyst for the reduction of nitrobenzenes

A novel palladium-containing ionic liquid-modified magnetic graphene oxide nanocomposite (Fe3O4/GO–IL–Pd) is synthesized and its catalytic performance is studied in the reduction of nitrobenzenes. The Fe3O4/GO–IL–Pd nanocomposite was characterized by using FT-IR, PXRD, SEM, EDS, VSM, and TG analyses. These analyses showed good magnetic properties and high stability of the designed composite. Different derivatives of nitrobenzenes were applied as substrates, giving corresponding anilines in high to excellent yields (89–96%) at short reaction times (10–15 minutes). Also, the stability, reproducibility, and reusability of the Fe3O4/GO–IL–Pd nanocomposite were investigated under applied conditions. A leaching experiment was also performed to study the nature of the Fe3O4/GO–IL–Pd catalyst under the conditions used.

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来源期刊
Nanoscale Advances
Nanoscale Advances Multiple-
CiteScore
8.00
自引率
2.10%
发文量
461
审稿时长
9 weeks
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