{"title":"通过费舍尔酯化法使用桐油酸基双子润湿剂提高涂料的润湿性和耐水性","authors":"","doi":"10.1016/j.porgcoat.2024.108779","DOIUrl":null,"url":null,"abstract":"<div><p>As societal awareness of environmental concerns grows, there is a gradual transition towards more environmentally friendly aqueous products, replacing traditional solvent-based ones. However, owing to its short hydrophobic chain segment, polyether defoamer has limitations, including a narrow field of use, poor defoaming ability, and a low defoaming rate. This study employed Fischer esterification to graft tung oil acid (i.e., eleostearic acid) onto 2,5,8,11-tetramethyl-5-decyne-4,7-diol, ethoxylated (TDDE) using p-toluenesulfonic acid as a catalyst. The resulting product, polyether alkynyl alcohol wetting agent (ETDDE), consisted of a tung oil monomer chain (hydrophobic part) and a polyether chain (hydrophilic part). The successful synthesis of ETDDE was confirmed through infrared spectroscopy analysis, gel permeation chromatography testing, and acid value determination. The results showed that the surface tension, defoaming ability, coating gloss, wettability, and water resistance of ETDDE improved with the ratio of eleostearic acid to TDDE.</p></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":null,"pages":null},"PeriodicalIF":6.5000,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enhancing wettability and water resistance of coatings using tung oleic acid-based gemini wetting agent via fischer esterification\",\"authors\":\"\",\"doi\":\"10.1016/j.porgcoat.2024.108779\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>As societal awareness of environmental concerns grows, there is a gradual transition towards more environmentally friendly aqueous products, replacing traditional solvent-based ones. However, owing to its short hydrophobic chain segment, polyether defoamer has limitations, including a narrow field of use, poor defoaming ability, and a low defoaming rate. This study employed Fischer esterification to graft tung oil acid (i.e., eleostearic acid) onto 2,5,8,11-tetramethyl-5-decyne-4,7-diol, ethoxylated (TDDE) using p-toluenesulfonic acid as a catalyst. The resulting product, polyether alkynyl alcohol wetting agent (ETDDE), consisted of a tung oil monomer chain (hydrophobic part) and a polyether chain (hydrophilic part). The successful synthesis of ETDDE was confirmed through infrared spectroscopy analysis, gel permeation chromatography testing, and acid value determination. The results showed that the surface tension, defoaming ability, coating gloss, wettability, and water resistance of ETDDE improved with the ratio of eleostearic acid to TDDE.</p></div>\",\"PeriodicalId\":20834,\"journal\":{\"name\":\"Progress in Organic Coatings\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":6.5000,\"publicationDate\":\"2024-09-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Progress in Organic Coatings\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S030094402400571X\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Organic Coatings","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S030094402400571X","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Enhancing wettability and water resistance of coatings using tung oleic acid-based gemini wetting agent via fischer esterification
As societal awareness of environmental concerns grows, there is a gradual transition towards more environmentally friendly aqueous products, replacing traditional solvent-based ones. However, owing to its short hydrophobic chain segment, polyether defoamer has limitations, including a narrow field of use, poor defoaming ability, and a low defoaming rate. This study employed Fischer esterification to graft tung oil acid (i.e., eleostearic acid) onto 2,5,8,11-tetramethyl-5-decyne-4,7-diol, ethoxylated (TDDE) using p-toluenesulfonic acid as a catalyst. The resulting product, polyether alkynyl alcohol wetting agent (ETDDE), consisted of a tung oil monomer chain (hydrophobic part) and a polyether chain (hydrophilic part). The successful synthesis of ETDDE was confirmed through infrared spectroscopy analysis, gel permeation chromatography testing, and acid value determination. The results showed that the surface tension, defoaming ability, coating gloss, wettability, and water resistance of ETDDE improved with the ratio of eleostearic acid to TDDE.
期刊介绍：
The aim of this international journal is to analyse and publicise the progress and current state of knowledge in the field of organic coatings and related materials. The Editors and the Editorial Board members will solicit both review and research papers from academic and industrial scientists who are actively engaged in research and development or, in the case of review papers, have extensive experience in the subject to be reviewed. Unsolicited manuscripts will be accepted if they meet the journal''s requirements. The journal publishes papers dealing with such subjects as:
• Chemical, physical and technological properties of organic coatings and related materials
• Problems and methods of preparation, manufacture and application of these materials
• Performance, testing and analysis.
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