Validating ex210Pb sediment dating methods applied to a large anthropogenically-impacted river basin

Sediment dynamics in five sites within the Mobile River Basin, Alabama, impacted by (i) dam-and-lock use, (ii) urbanization, (iii) industrial/mining practices, (iv) flooding, and (v) storm surge events were evaluated to understand better anthropogenic impacts on regional sediment budgets. Three widely used sediment dating models based on excess ²¹⁰Pb (ex²¹⁰Pb) (i.e., Constant Rate of Supply, CRS, Constant Initial Concentration, CIC, and Advective Dispersion Equation, ADE) and two recently developed ones (i.e., Porosity Variation, PV and Porosity Variation Without Diffusion, PVWD) were tested to determine their applicability to these anthropogenically altered lacustrine and coastal areas. To verify results from ex²¹⁰Pb models, we used conventional time markers, including regional hydrograph records and historical aerial images. We found that the traditionally used time-marker ¹³⁷Cs is no longer useful due to its current low inventories in the sediments. Drainage-to-lake area ratios were used to determine relative runoff and atmospheric radionuclide contributions. Statistical analysis of physical properties such as porosity, bulk and dry density, water content, and sediment geochemical compositions were utilized to support sediment transport and site development hypotheses. When constructing the sediment history at each site using these proxies, we found that the CIC and ADE models produced unreliable ages because of violation of requirements for exponentially decreasing porosity and ex²¹⁰Pb activity with depth. We found that two new models, PV and PVWD, that account for heterogeneous porosity, produced more reliable sediment depositional ages. These two models produced ages with lower uncertainties than the CRS model, outperforming the other conventional models tested. We conclude that the PV and PVWD models are more applicable for environments experiencing erosional and abrupt depositional events, which in our study resulted from dam construction and storm-surge events. Model sensitivity analysis showed that decreasing average particle density produces younger sediment ages by the PV and PVWD models. Higher ex²¹⁰Pb activity analytical uncertainty resulted in lower sedimentation rates and higher estimated ages by all five models.