{"title":"基于三元 ErVO4/P@g-C3N4/SnS2 纳米复合材料的选择性和稳定性可见光催化无清除剂光电化学策略,用于检测不同水样中的铅离子。","authors":"Abishek Jayapaul, Sanjay Ballur Prasanna, Lu-Yin Lin, Yeh-Fang Duann, Yu-Chien Lin, Ren-Jei Chung","doi":"10.1016/j.envpol.2024.124892","DOIUrl":null,"url":null,"abstract":"<p><p>Lead ions (Pb<sup>2+</sup>) are heavy metal environmental pollutants that can significantly impact biological health. In this study, the synthesis of a ternary nanocomposite, ErVO<sub>4</sub>/P@g-C<sub>3</sub>N<sub>4</sub>/SnS<sub>2</sub>, was achieved using a combination of hydrothermal synthesis and mechanical grinding. The as-fabricated photoelectrochemical (PEC) sensor was found to be an ideal substrate for Pb<sup>2+</sup> detection with high sensitivity and reliability. The ErVO<sub>4</sub>/P@g-C<sub>3</sub>N<sub>4</sub>/SnS<sub>2</sub>/FTO was selected as the substrate because of its remarkable and reliable photocurrent response. The Pb<sup>2+</sup> sensor exhibited a low detection limit of 0.1 pM and a broad linear range of 0.002-0.2 nM. Moreover, the sensor exhibited outstanding stability, selectivity, and reproducibility. In real-time applications, it exhibited stable recovery and a low relative standard deviation, ensuring reliable and accurate measurements. The as-prepared PEC sensor was highly stable for the detection of Pb<sup>2+</sup> in different water samples. This promising characteristic highlights its significant potential for use in the detection of environmental pollutants.</p>","PeriodicalId":311,"journal":{"name":"Environmental Pollution","volume":" ","pages":"124892"},"PeriodicalIF":7.6000,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Selective and stable visible-light-prompted scavenger-free photoelectrochemical strategy based on a ternary ErVO<sub>4</sub>/P@g-C<sub>3</sub>N<sub>4</sub>/SnS<sub>2</sub> nanocomposite for the detection of lead ions in different water samples.\",\"authors\":\"Abishek Jayapaul, Sanjay Ballur Prasanna, Lu-Yin Lin, Yeh-Fang Duann, Yu-Chien Lin, Ren-Jei Chung\",\"doi\":\"10.1016/j.envpol.2024.124892\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Lead ions (Pb<sup>2+</sup>) are heavy metal environmental pollutants that can significantly impact biological health. In this study, the synthesis of a ternary nanocomposite, ErVO<sub>4</sub>/P@g-C<sub>3</sub>N<sub>4</sub>/SnS<sub>2</sub>, was achieved using a combination of hydrothermal synthesis and mechanical grinding. The as-fabricated photoelectrochemical (PEC) sensor was found to be an ideal substrate for Pb<sup>2+</sup> detection with high sensitivity and reliability. The ErVO<sub>4</sub>/P@g-C<sub>3</sub>N<sub>4</sub>/SnS<sub>2</sub>/FTO was selected as the substrate because of its remarkable and reliable photocurrent response. The Pb<sup>2+</sup> sensor exhibited a low detection limit of 0.1 pM and a broad linear range of 0.002-0.2 nM. Moreover, the sensor exhibited outstanding stability, selectivity, and reproducibility. In real-time applications, it exhibited stable recovery and a low relative standard deviation, ensuring reliable and accurate measurements. The as-prepared PEC sensor was highly stable for the detection of Pb<sup>2+</sup> in different water samples. This promising characteristic highlights its significant potential for use in the detection of environmental pollutants.</p>\",\"PeriodicalId\":311,\"journal\":{\"name\":\"Environmental Pollution\",\"volume\":\" \",\"pages\":\"124892\"},\"PeriodicalIF\":7.6000,\"publicationDate\":\"2024-11-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Environmental Pollution\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://doi.org/10.1016/j.envpol.2024.124892\",\"RegionNum\":2,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/9/4 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q1\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Pollution","FirstCategoryId":"93","ListUrlMain":"https://doi.org/10.1016/j.envpol.2024.124892","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/9/4 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
Selective and stable visible-light-prompted scavenger-free photoelectrochemical strategy based on a ternary ErVO4/P@g-C3N4/SnS2 nanocomposite for the detection of lead ions in different water samples.
Lead ions (Pb2+) are heavy metal environmental pollutants that can significantly impact biological health. In this study, the synthesis of a ternary nanocomposite, ErVO4/P@g-C3N4/SnS2, was achieved using a combination of hydrothermal synthesis and mechanical grinding. The as-fabricated photoelectrochemical (PEC) sensor was found to be an ideal substrate for Pb2+ detection with high sensitivity and reliability. The ErVO4/P@g-C3N4/SnS2/FTO was selected as the substrate because of its remarkable and reliable photocurrent response. The Pb2+ sensor exhibited a low detection limit of 0.1 pM and a broad linear range of 0.002-0.2 nM. Moreover, the sensor exhibited outstanding stability, selectivity, and reproducibility. In real-time applications, it exhibited stable recovery and a low relative standard deviation, ensuring reliable and accurate measurements. The as-prepared PEC sensor was highly stable for the detection of Pb2+ in different water samples. This promising characteristic highlights its significant potential for use in the detection of environmental pollutants.
期刊介绍:
Environmental Pollution is an international peer-reviewed journal that publishes high-quality research papers and review articles covering all aspects of environmental pollution and its impacts on ecosystems and human health.
Subject areas include, but are not limited to:
• Sources and occurrences of pollutants that are clearly defined and measured in environmental compartments, food and food-related items, and human bodies;
• Interlinks between contaminant exposure and biological, ecological, and human health effects, including those of climate change;
• Contaminants of emerging concerns (including but not limited to antibiotic resistant microorganisms or genes, microplastics/nanoplastics, electronic wastes, light, and noise) and/or their biological, ecological, or human health effects;
• Laboratory and field studies on the remediation/mitigation of environmental pollution via new techniques and with clear links to biological, ecological, or human health effects;
• Modeling of pollution processes, patterns, or trends that is of clear environmental and/or human health interest;
• New techniques that measure and examine environmental occurrences, transport, behavior, and effects of pollutants within the environment or the laboratory, provided that they can be clearly used to address problems within regional or global environmental compartments.