Soochan Kim, Pravin N. Didwal, Juliane Fiates, James A. Dawson, Robert S. Weatherup, Michael De Volder
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Effect of the Formation Rate on the Stability of Anode-Free Lithium Metal Batteries
Anode-free Li-ion batteries (AFBs), where a Cu current collector is used to plate and strip Li instead of a classic anode, are promising technologies to increase the energy density of batteries. In addition, AFBs are safer and easier to manufacture than competing Li-metal anodes and solid-state batteries. However, the loss of Li inventory that occurs during the operation of AFBs limits their lifespan and practical application. In this study, we find that, in particular, the current density used during the formation of AFBs has a considerable impact on the cycling stability of the cell. We optimize the formation protocol based on experimental and computational observations of thresholds associated with morphological changes in the plated Li and the chemical composition of the solid–electrolyte interphase. Unlike graphite anodes, which require slow formation cycles, AFBs exhibit improved cycling behavior when formed at the highest current densities that avoid dendritic Li formation. We verify that this strategy for optimizing the formation current density is effective for three different electrolyte formulations and, therefore, provides a straightforward universal rationale to optimize the formation protocols for AFBs.
ACS Energy Letters Energy-Renewable Energy, Sustainability and the Environment
CiteScore
31.20
自引率
5.00%
发文量
469
审稿时长
1 months
期刊介绍:
ACS Energy Letters is a monthly journal that publishes papers reporting new scientific advances in energy research. The journal focuses on topics that are of interest to scientists working in the fundamental and applied sciences. Rapid publication is a central criterion for acceptance, and the journal is known for its quick publication times, with an average of 4-6 weeks from submission to web publication in As Soon As Publishable format.
ACS Energy Letters is ranked as the number one journal in the Web of Science Electrochemistry category. It also ranks within the top 10 journals for Physical Chemistry, Energy & Fuels, and Nanoscience & Nanotechnology.
The journal offers several types of articles, including Letters, Energy Express, Perspectives, Reviews, Editorials, Viewpoints and Energy Focus. Additionally, authors have the option to submit videos that summarize or support the information presented in a Perspective or Review article, which can be highlighted on the journal's website. ACS Energy Letters is abstracted and indexed in Chemical Abstracts Service/SciFinder, EBSCO-summon, PubMed, Web of Science, Scopus and Portico.