{"title":"二异丁烯+ PRF/TRF 混合物层流燃烧速度的实验和数值研究","authors":"","doi":"10.1016/j.joei.2024.101802","DOIUrl":null,"url":null,"abstract":"<div><p>DIB (Diisobutylene, JC<sub>8</sub>H<sub>16</sub>) strongly correlates with real gasoline and significantly impacts the combustion behavior of alternative fuels designed as gasoline substitutes. However, accuracy concerns persist in laminar burning velocity data reported in literature. In this paper, the laminar burning velocities of DIB + air, DIB + PRF + air, and DIB + TRF + air mixtures were measured by the heat flux method at 1 atm. (PRF, Primary Reference Fuel; TRF, Toluene Reference Fuel) The equivalence ratio was controlled within 0.6–1.3, and the initial temperatures were set at 298K, 318K, and 338K. Additionally, by employing the mechanism proposed by Ren et al., the simulated values align with the experimental data, thus prompting the conduction of a reaction kinetic analysis. The analysis of chemical reaction kinetics reveals the reaction pathways of DIB, with a notable observation that an increase in temperature or a decrease in equivalence ratio can both lead to an elevation in the degree of unsaturation in the bonds of intermediate species. During laminar flame combustion, PRF and TRF compete with DIB for oxygen, with PRF appearing to have a stronger ability to capture oxygen. In addition, the laminar burning velocity temperature dependence coefficient α decreases first and then increases with the increase of the equivalence ratio, where the minimum α is obtained at equivalence ratio = 1.1. Additionally, the laminar burning velocity at higher initial temperatures is estimated by the extrapolation method and compared with the experimental data reported in literature.</p></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":null,"pages":null},"PeriodicalIF":5.6000,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Experimental and numerical study of laminar burning velocity for Diisobutylene+ PRF/TRF mixtures\",\"authors\":\"\",\"doi\":\"10.1016/j.joei.2024.101802\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>DIB (Diisobutylene, JC<sub>8</sub>H<sub>16</sub>) strongly correlates with real gasoline and significantly impacts the combustion behavior of alternative fuels designed as gasoline substitutes. However, accuracy concerns persist in laminar burning velocity data reported in literature. In this paper, the laminar burning velocities of DIB + air, DIB + PRF + air, and DIB + TRF + air mixtures were measured by the heat flux method at 1 atm. (PRF, Primary Reference Fuel; TRF, Toluene Reference Fuel) The equivalence ratio was controlled within 0.6–1.3, and the initial temperatures were set at 298K, 318K, and 338K. Additionally, by employing the mechanism proposed by Ren et al., the simulated values align with the experimental data, thus prompting the conduction of a reaction kinetic analysis. The analysis of chemical reaction kinetics reveals the reaction pathways of DIB, with a notable observation that an increase in temperature or a decrease in equivalence ratio can both lead to an elevation in the degree of unsaturation in the bonds of intermediate species. During laminar flame combustion, PRF and TRF compete with DIB for oxygen, with PRF appearing to have a stronger ability to capture oxygen. In addition, the laminar burning velocity temperature dependence coefficient α decreases first and then increases with the increase of the equivalence ratio, where the minimum α is obtained at equivalence ratio = 1.1. Additionally, the laminar burning velocity at higher initial temperatures is estimated by the extrapolation method and compared with the experimental data reported in literature.</p></div>\",\"PeriodicalId\":17287,\"journal\":{\"name\":\"Journal of The Energy Institute\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2024-08-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Energy Institute\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1743967124002800\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Energy Institute","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1743967124002800","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Experimental and numerical study of laminar burning velocity for Diisobutylene+ PRF/TRF mixtures
DIB (Diisobutylene, JC8H16) strongly correlates with real gasoline and significantly impacts the combustion behavior of alternative fuels designed as gasoline substitutes. However, accuracy concerns persist in laminar burning velocity data reported in literature. In this paper, the laminar burning velocities of DIB + air, DIB + PRF + air, and DIB + TRF + air mixtures were measured by the heat flux method at 1 atm. (PRF, Primary Reference Fuel; TRF, Toluene Reference Fuel) The equivalence ratio was controlled within 0.6–1.3, and the initial temperatures were set at 298K, 318K, and 338K. Additionally, by employing the mechanism proposed by Ren et al., the simulated values align with the experimental data, thus prompting the conduction of a reaction kinetic analysis. The analysis of chemical reaction kinetics reveals the reaction pathways of DIB, with a notable observation that an increase in temperature or a decrease in equivalence ratio can both lead to an elevation in the degree of unsaturation in the bonds of intermediate species. During laminar flame combustion, PRF and TRF compete with DIB for oxygen, with PRF appearing to have a stronger ability to capture oxygen. In addition, the laminar burning velocity temperature dependence coefficient α decreases first and then increases with the increase of the equivalence ratio, where the minimum α is obtained at equivalence ratio = 1.1. Additionally, the laminar burning velocity at higher initial temperatures is estimated by the extrapolation method and compared with the experimental data reported in literature.
期刊介绍:
The Journal of the Energy Institute provides peer reviewed coverage of original high quality research on energy, engineering and technology.The coverage is broad and the main areas of interest include:
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