紫外和可见光下光催化降解阳离子染料的 SnO2-TiO2 材料及壳聚糖复合膜研究

IF 5.2 2区 化学 Q1 CHEMISTRY, APPLIED
Lourdes A. Etshindo , Célia Sousa , Priscila Tamiasso-Martinhon , Marcos V. Colaço , Alexandre R. Camara , Angela S. Rocha
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引用次数: 0

摘要

将二氧化锡掺入和固定为薄膜形成复合材料的可能性为二氧化钛分别利用可见光和促进光催化过程开辟了新的前景。在这项研究中,通过溶胶-凝胶法加入氨水共沉淀,将 0 %、1 % 和 10 % 重量级的 SnO2 加入 TiO2(SnO2-TiO2),然后在 500 °C 煅烧。光催化剂的表征方法包括 N2 吸附-解吸、傅立叶红外光谱、XRD Rietveld 精炼、TG-DTG、SEM-EDS、DRS 和元素分析。在可见光和紫外光照射下,于 25 °C 下光催化降解水相中的阳离子染料亚甲基蓝 2 小时,对所有固体的性能进行了评估。结果表明,在二氧化钛中加入锡可改善其质地特性并降低其带隙。所有固体都只呈现出典型的二氧化钛衍射图,以锐钛矿相为主,但含有 10% 二氧化锡的催化剂也呈现出褐铁矿相,推断出锡原子被掺入到二氧化钛结构中,MEV 结果也证实了这一点。所有锡基光催化剂在紫外线和可见光下都表现出很高的活性,其中 10% 的二氧化锡材料在紫外线和可见光辐射下 2 小时后的降解率分别达到 83% 和 88%。这种材料作为固定薄膜进行了测试,脱色率达到 14%,同时还对其再利用情况进行了评估。我们的研究表明,SnO2-TiO2 催化剂可在批量反应器中作为粉末在紫外线和可见光下分解染料,并与壳聚糖固定为复合薄膜,这为促进太阳能光的应用开辟了新的前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
SnO2-TiO2 materials for photocatalytic degradation of cationic dye under UV and visible light and a chitosan composite film investigation

The possibility of SnO2 incorporation and immobilization as films forming composites opens new perspectives for TiO2 to profit visible light and to facilitate the photocatalytic process, respectively. In this study, 0 %, 1 % and 10 % wt. of SnO2 was incorporated into TiO2 (SnO2-TiO2) by coprecipitation in a sol-gel method by ammonia addition, followed for calcination at 500 °C. The photocatalysts were characterized by N2 adsorption-desorption, FTIR spectroscopy, XRD Rietveld refinement, TG-DTG, SEM-EDS, DRS and elemental analysis. The performance of all solids was evaluated in the photocatalytic degradation of the cationic dye methylene blue in aqueous phase, under visible and UV irradiation, at 25 °C for 2 h. The results showed that the incorporation of Sn into TiO2 improved the textural properties and decreased the bandgap. All solids presented only TiO2 typical diffractograms, with anatase as the main phase, but catalyst with 10 % SnO2 presented also brookite phase, inferring that Sn atoms were incorporated into TiO2 structure, corroborated by MEV results. All tin-based photocatalysts show high activity under UV and visible light, with the 10 % SnO2 material reaching 83 % and 88 % degradation after 2 h under UV and visible radiation, respectively. This material was tested as an immobilized film, achieving 14 % of decolorization, and the reuse was also evaluated. Our investigation demonstrates that SnO2-TiO2 catalysts could be used to decompose a dye under UV and Visible light as powder in a batch reactor and immobilized as a composite film with chitosan, that opens new perspectives to facilitate the application using solar light.

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来源期刊
Catalysis Today
Catalysis Today 化学-工程:化工
CiteScore
11.50
自引率
3.80%
发文量
573
审稿时长
2.9 months
期刊介绍: Catalysis Today focuses on the rapid publication of original invited papers devoted to currently important topics in catalysis and related subjects. The journal only publishes special issues (Proposing a Catalysis Today Special Issue), each of which is supervised by Guest Editors who recruit individual papers and oversee the peer review process. Catalysis Today offers researchers in the field of catalysis in-depth overviews of topical issues. Both fundamental and applied aspects of catalysis are covered. Subjects such as catalysis of immobilized organometallic and biocatalytic systems are welcome. Subjects related to catalysis such as experimental techniques, adsorption, process technology, synthesis, in situ characterization, computational, theoretical modeling, imaging and others are included if there is a clear relationship to catalysis.
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