粉煤灰和二氧化碳固化对磷酸镁钾水泥性能的影响

IF 7.2 2区 工程技术 Q1 CHEMISTRY, MULTIDISCIPLINARY
Ling Qin , Qijie Xie , Junyi Yang , Jiuwen Bao , Qiang Song , Sheng Wang , Qi Yu , Ditao Niu , Peng Zhang
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引用次数: 0

摘要

本研究探讨了粉煤灰(FA)和二氧化碳固化对磷酸镁钾水泥(MKPC)抗弯强度、抗压强度和耐水性的综合影响。此外,还使用 X 射线衍射 (XRD)、热重分析 (TGA)、注汞孔隙率 (MIP) 和扫描电子显微镜 (SEM) 对 MKPC 和 MKPC-FA 混合物的水化产物和微观结构进行了研究。结果表明,碳化固化可通过细化孔隙结构和降低孔隙率来有效提高 MKPC-FA 混合物的机械强度和耐水性。在磷酸镁水泥中掺入粉煤灰可延长凝结时间,并适当提高 MKPC-FA 混合料的耐水性。值得一提的是,随着粉煤灰含量的增加,MKPC-FA 混合料的机械强度会下降,而碳化固化可部分改善这些负面影响。因此,加入粉煤灰和储存二氧化碳对 MKPC 制备过程中的耐久性和环境可持续性方面都有积极影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of coal fly ash and CO2 curing on performance of magnesium potassium phosphate cement

This study explores the combined effects of coal fly ash (FA) and CO2 curing on the flexural strength, compressive strength, and water resistance of magnesium potassium phosphate cement (MKPC). Additionally, the hydration products and microstructure of MKPC and MKPC-FA blends are examined using X-ray diffraction (XRD), thermogravimetric analysis (TGA), mercury injection porosity (MIP), and scanning electron microscopy (SEM). The results demonstrate that carbonation curing effectively improves the mechanical strength and water resistance of MKPC-FA blends by refining the pore structure and reducing porosity. Incorporating fly ash into magnesium phosphate cement leads to a longer setting time and appropriate enhancement in the water resistance of MKPC-FA blends. It should be mentioned that the mechanical strength of MKPC-FA blends declines with increasing fly ash content, and carbonation curing can partially ameliorate these negative effects. Therefore, both incorporating fly ash and storing carbon dioxide have positive effects on the durability and environmental sustainability aspects associated with MKPC preparation.

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来源期刊
Journal of CO2 Utilization
Journal of CO2 Utilization CHEMISTRY, MULTIDISCIPLINARY-ENGINEERING, CHEMICAL
CiteScore
13.90
自引率
10.40%
发文量
406
审稿时长
2.8 months
期刊介绍: The Journal of CO2 Utilization offers a single, multi-disciplinary, scholarly platform for the exchange of novel research in the field of CO2 re-use for scientists and engineers in chemicals, fuels and materials. The emphasis is on the dissemination of leading-edge research from basic science to the development of new processes, technologies and applications. The Journal of CO2 Utilization publishes original peer-reviewed research papers, reviews, and short communications, including experimental and theoretical work, and analytical models and simulations.
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