Flexible self-supporting photonic crystals: Fabrications and responsive structural colors

Photonic crystals (PCs) play an increasingly significant role in anti-counterfeiting, sensors, displays, and other fields due to their tunable structural colors produced by light manipulation of photonic stop bands. Flexible self-supporting photonic crystals (FSPCs) eliminate the requirement for conventional structures to rely on the existence of hard substrates, as well as the problem of poor mechanical qualities caused by the stiffness of the building blocks. Meanwhile, diverse production techniques and materials provide FSPCs with varied stimulus-responsive color-changing capacities, thus they have received an abundance of focus. This review summarizes the preparation strategies and variable structural colors of FSPCs. First, a series of preparation strategies by integrating polymers with PCs are summarized, including assembly of colloidal spheres on flexible substrates, polymer packaging, polymer-based direct assembly, nanoimprinting, and 3D printing. Subsequently, variable structural colors of FSPCs with different stimulations, such as viewing angle, chemical stimulation (solvents, ions, pH, biomolecules, etc.), temperature, mechanical/magnetic stress, and light, are described in detail. Finally, the outlook and challenges regarding FSPCs are presented, and several potential directions for their fabrication and application are discussed. It's believed that FSPCs will be a valuable platform for advancing the practical implementation of optical metamaterials.