使用甲基异丁基酮作为弹性二维 MIBK-Sn 纳米片的骨架,基于 AIEE 的恩诺沙星荧光检测技术

IF 5.9 3区 材料科学 Q2 CHEMISTRY, PHYSICAL
Deepak Dabur , Yun Cheih Chiu , Hui-Fen Wu
{"title":"使用甲基异丁基酮作为弹性二维 MIBK-Sn 纳米片的骨架,基于 AIEE 的恩诺沙星荧光检测技术","authors":"Deepak Dabur ,&nbsp;Yun Cheih Chiu ,&nbsp;Hui-Fen Wu","doi":"10.1016/j.flatc.2024.100723","DOIUrl":null,"url":null,"abstract":"<div><p>For the first time, we proposed a novel approach to create enduring and robust fluorescent nanosheets by using MIBK as the backbone to form the 2D MIBK-Sn nanosheets (2D MIBK-Sn NS) for detecting ENR. These nanosheets were synthesized in situ using probe ultrasonication to facilitate the formation of MIBK-based 2D tin nanosheets. The LOD and LOQ for ENR in aqueous solutions was 4.90 and 16.1 nM, respectively. Linear calibration curves were obtained with correlation coefficient (R<sup>2</sup>) = 0.9920 in a linear range of 0–2 µM. Recovery results from real samples ranged from 90 to 106 % of the nominal values. Milk and urine samples were analyzed at concentrations ranging from 0.3 to 1.7 µM.</p></div>","PeriodicalId":316,"journal":{"name":"FlatChem","volume":"47 ","pages":"Article 100723"},"PeriodicalIF":5.9000,"publicationDate":"2024-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"AIEE based fluorescent detection of Enrofloxacin using methyl isobutyl ketone as a backbone for the resilient 2D MIBK-Sn nanosheets\",\"authors\":\"Deepak Dabur ,&nbsp;Yun Cheih Chiu ,&nbsp;Hui-Fen Wu\",\"doi\":\"10.1016/j.flatc.2024.100723\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>For the first time, we proposed a novel approach to create enduring and robust fluorescent nanosheets by using MIBK as the backbone to form the 2D MIBK-Sn nanosheets (2D MIBK-Sn NS) for detecting ENR. These nanosheets were synthesized in situ using probe ultrasonication to facilitate the formation of MIBK-based 2D tin nanosheets. The LOD and LOQ for ENR in aqueous solutions was 4.90 and 16.1 nM, respectively. Linear calibration curves were obtained with correlation coefficient (R<sup>2</sup>) = 0.9920 in a linear range of 0–2 µM. Recovery results from real samples ranged from 90 to 106 % of the nominal values. Milk and urine samples were analyzed at concentrations ranging from 0.3 to 1.7 µM.</p></div>\",\"PeriodicalId\":316,\"journal\":{\"name\":\"FlatChem\",\"volume\":\"47 \",\"pages\":\"Article 100723\"},\"PeriodicalIF\":5.9000,\"publicationDate\":\"2024-08-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"FlatChem\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S245226272400117X\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"FlatChem","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S245226272400117X","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

摘要

我们首次提出了一种新方法,以 MIBK 为骨架形成二维 MIBK-Sn 纳米片(二维 MIBK-Sn NS),用于检测 ENR,从而制造出持久而坚固的荧光纳米片。这些纳米片是利用探针超声原位合成的,以促进基于 MIBK 的二维锡纳米片的形成。ENR在水溶液中的LOD和LOQ分别为4.90和16.1 nM。在 0-2 µM 的线性范围内,线性校准曲线的相关系数 (R2) = 0.9920。实际样品的回收率为标称值的 90% 至 106%。牛奶和尿液样品的分析浓度为 0.3 至 1.7 µM。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

AIEE based fluorescent detection of Enrofloxacin using methyl isobutyl ketone as a backbone for the resilient 2D MIBK-Sn nanosheets

AIEE based fluorescent detection of Enrofloxacin using methyl isobutyl ketone as a backbone for the resilient 2D MIBK-Sn nanosheets

For the first time, we proposed a novel approach to create enduring and robust fluorescent nanosheets by using MIBK as the backbone to form the 2D MIBK-Sn nanosheets (2D MIBK-Sn NS) for detecting ENR. These nanosheets were synthesized in situ using probe ultrasonication to facilitate the formation of MIBK-based 2D tin nanosheets. The LOD and LOQ for ENR in aqueous solutions was 4.90 and 16.1 nM, respectively. Linear calibration curves were obtained with correlation coefficient (R2) = 0.9920 in a linear range of 0–2 µM. Recovery results from real samples ranged from 90 to 106 % of the nominal values. Milk and urine samples were analyzed at concentrations ranging from 0.3 to 1.7 µM.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
FlatChem
FlatChem Multiple-
CiteScore
8.40
自引率
6.50%
发文量
104
审稿时长
26 days
期刊介绍: FlatChem - Chemistry of Flat Materials, a new voice in the community, publishes original and significant, cutting-edge research related to the chemistry of graphene and related 2D & layered materials. The overall aim of the journal is to combine the chemistry and applications of these materials, where the submission of communications, full papers, and concepts should contain chemistry in a materials context, which can be both experimental and/or theoretical. In addition to original research articles, FlatChem also offers reviews, minireviews, highlights and perspectives on the future of this research area with the scientific leaders in fields related to Flat Materials. Topics of interest include, but are not limited to, the following: -Design, synthesis, applications and investigation of graphene, graphene related materials and other 2D & layered materials (for example Silicene, Germanene, Phosphorene, MXenes, Boron nitride, Transition metal dichalcogenides) -Characterization of these materials using all forms of spectroscopy and microscopy techniques -Chemical modification or functionalization and dispersion of these materials, as well as interactions with other materials -Exploring the surface chemistry of these materials for applications in: Sensors or detectors in electrochemical/Lab on a Chip devices, Composite materials, Membranes, Environment technology, Catalysis for energy storage and conversion (for example fuel cells, supercapacitors, batteries, hydrogen storage), Biomedical technology (drug delivery, biosensing, bioimaging)
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信