{"title":"合成杂三金属卟啉纳米颗粒。","authors":"Songlin Xue, Xiaojuan Lv, Yuting Dong, Tao Zhang, Fengxian Qiu, Jianming Pan, Daiki Kuzuhara, Hiroko Yamada, Naoki Aratani","doi":"10.1002/chem.202402680","DOIUrl":null,"url":null,"abstract":"<p>This work reported “trinitarian” porphyrin nanobelts, contained hetero-trimetal ions. The high-resolution mass spectrometry and X-ray crystallography proved <b>PNBNiCuPd</b> consisting of three different bent porphyrin(2.1.2.1) metal complex moieties. The redox properties indicate porphyrin nanobelts demonstrate the multielectron donating and accepting properties, more than nine redox processes.</p>","PeriodicalId":144,"journal":{"name":"Chemistry - A European Journal","volume":"30 68","pages":""},"PeriodicalIF":3.7000,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of Hetero-Trimetal Porphyrin Nanobelts\",\"authors\":\"Songlin Xue, Xiaojuan Lv, Yuting Dong, Tao Zhang, Fengxian Qiu, Jianming Pan, Daiki Kuzuhara, Hiroko Yamada, Naoki Aratani\",\"doi\":\"10.1002/chem.202402680\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>This work reported “trinitarian” porphyrin nanobelts, contained hetero-trimetal ions. The high-resolution mass spectrometry and X-ray crystallography proved <b>PNBNiCuPd</b> consisting of three different bent porphyrin(2.1.2.1) metal complex moieties. The redox properties indicate porphyrin nanobelts demonstrate the multielectron donating and accepting properties, more than nine redox processes.</p>\",\"PeriodicalId\":144,\"journal\":{\"name\":\"Chemistry - A European Journal\",\"volume\":\"30 68\",\"pages\":\"\"},\"PeriodicalIF\":3.7000,\"publicationDate\":\"2024-08-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemistry - A European Journal\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/chem.202402680\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemistry - A European Journal","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/chem.202402680","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
这项研究报告了含有杂三价金属离子的 "三价 "卟啉纳米颗粒。高分辨率质谱和 X 射线晶体学证明,PNBNiCuPd 由三种不同的弯曲卟啉(2.1.2.1)金属复合物分子组成。氧化还原特性表明,卟啉纳米颗粒具有多电子捐赠和接受特性,可进行九种以上的氧化还原过程。
This work reported “trinitarian” porphyrin nanobelts, contained hetero-trimetal ions. The high-resolution mass spectrometry and X-ray crystallography proved PNBNiCuPd consisting of three different bent porphyrin(2.1.2.1) metal complex moieties. The redox properties indicate porphyrin nanobelts demonstrate the multielectron donating and accepting properties, more than nine redox processes.
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