从全氟烷基芳基硫醚到正硫醚。

IF 2.2 4区化学 Q2 CHEMISTRY, ORGANIC

Beilstein Journal of Organic Chemistry Pub Date : 2024-08-23 eCollection Date: 2024-01-01 DOI:10.3762/bjoc.20.181

Yang Li, Guillaume Dagousset, Emmanuel Magnier, Bruce Pégot

引用次数: 0

摘要

通过[3,3]-重排，以一步法和两步法获得了原始的正交硫醚衍生物。通过改变腈或三氟烷基亚砜的起始原料，报告了几种芳基-SCF3 化合物。全氟烷基链的变化也是可能的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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From perfluoroalkyl aryl sulfoxides to ortho thioethers.

Access to original ortho thioether derivatives was achieved through a [3,3]-rearrangement in a one-pot two-step protocol. Several aryl-SCF₃ compounds are reported by variation of the nitrile or of the trifluoroalkyl sulfoxide starting material. The variation of the perfluoroalkyl chain was also possible.

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来源期刊

Beilstein Journal of Organic Chemistry 化学-有机化学

CiteScore

4.90

自引率

3.70%

发文量

167

审稿时长

1.4 months

期刊介绍： The Beilstein Journal of Organic Chemistry is an international, peer-reviewed, Open Access journal. It provides a unique platform for rapid publication without any charges (free for author and reader) – Platinum Open Access. The content is freely accessible 365 days a year to any user worldwide. Articles are available online immediately upon publication and are publicly archived in all major repositories. In addition, it provides a platform for publishing thematic issues (theme-based collections of articles) on topical issues in organic chemistry. The journal publishes high quality research and reviews in all areas of organic chemistry, including organic synthesis, organic reactions, natural product chemistry, structural investigations, supramolecular chemistry and chemical biology.