预氧化改性烟煤基硬质碳以储存高质量钠离子

IF 3 4区 材料科学 Q3 CHEMISTRY, PHYSICAL
Youyu Zhu , Xiaofang Tang , Zhenghan Kong , Zonglin You , Yixi Zhang , Yingfeng Duan , Yating Zhang
{"title":"预氧化改性烟煤基硬质碳以储存高质量钠离子","authors":"Youyu Zhu ,&nbsp;Xiaofang Tang ,&nbsp;Zhenghan Kong ,&nbsp;Zonglin You ,&nbsp;Yixi Zhang ,&nbsp;Yingfeng Duan ,&nbsp;Yating Zhang","doi":"10.1016/j.ssi.2024.116668","DOIUrl":null,"url":null,"abstract":"<div><p>Bituminous coal, with its moderate anthracene content, high reactivity, and ease of modulation, stands out as a favorable choice as a precursor for hard carbon. However, due to the highly condensed aromatic rings in bituminous coal, it tends to form highly graphitized structures after high-temperature carbonization. Therefore, pretreatment of bituminous coal is necessary to suppress the graphitization process. Here, we combine pre-oxidation techniques with high-temperature carbonization to produce a cost-effective, high carbon yield, and superior performance coal-based hard carbon. When utilized as anode for sodium-ion batteries, the prepared coal-based hard carbon exhibits a high reversible capacity of 313.5 mAh g<sup>−1</sup>, along with excellent rate capability and long cycling stability.</p></div>","PeriodicalId":431,"journal":{"name":"Solid State Ionics","volume":"416 ","pages":"Article 116668"},"PeriodicalIF":3.0000,"publicationDate":"2024-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Pre-oxidation modification of bituminous coal-based hard carbon for high-quality sodium ion storage\",\"authors\":\"Youyu Zhu ,&nbsp;Xiaofang Tang ,&nbsp;Zhenghan Kong ,&nbsp;Zonglin You ,&nbsp;Yixi Zhang ,&nbsp;Yingfeng Duan ,&nbsp;Yating Zhang\",\"doi\":\"10.1016/j.ssi.2024.116668\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Bituminous coal, with its moderate anthracene content, high reactivity, and ease of modulation, stands out as a favorable choice as a precursor for hard carbon. However, due to the highly condensed aromatic rings in bituminous coal, it tends to form highly graphitized structures after high-temperature carbonization. Therefore, pretreatment of bituminous coal is necessary to suppress the graphitization process. Here, we combine pre-oxidation techniques with high-temperature carbonization to produce a cost-effective, high carbon yield, and superior performance coal-based hard carbon. When utilized as anode for sodium-ion batteries, the prepared coal-based hard carbon exhibits a high reversible capacity of 313.5 mAh g<sup>−1</sup>, along with excellent rate capability and long cycling stability.</p></div>\",\"PeriodicalId\":431,\"journal\":{\"name\":\"Solid State Ionics\",\"volume\":\"416 \",\"pages\":\"Article 116668\"},\"PeriodicalIF\":3.0000,\"publicationDate\":\"2024-08-24\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Solid State Ionics\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0167273824002169\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solid State Ionics","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0167273824002169","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

摘要

烟煤具有蒽含量适中、反应活性高、易于调制等特点,是硬质碳前驱体的理想选择。然而,由于烟煤中的芳香环高度缩合,在高温碳化后容易形成高度石墨化的结构。因此,有必要对烟煤进行预处理,以抑制石墨化过程。在这里,我们将预氧化技术与高温碳化技术相结合,生产出了一种成本低、产炭率高、性能优越的煤基硬质碳。将制备的煤基硬质碳用作钠离子电池的负极时,其可逆容量高达 313.5 mAh g-1,同时还具有优异的速率能力和长循环稳定性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Pre-oxidation modification of bituminous coal-based hard carbon for high-quality sodium ion storage

Pre-oxidation modification of bituminous coal-based hard carbon for high-quality sodium ion storage

Bituminous coal, with its moderate anthracene content, high reactivity, and ease of modulation, stands out as a favorable choice as a precursor for hard carbon. However, due to the highly condensed aromatic rings in bituminous coal, it tends to form highly graphitized structures after high-temperature carbonization. Therefore, pretreatment of bituminous coal is necessary to suppress the graphitization process. Here, we combine pre-oxidation techniques with high-temperature carbonization to produce a cost-effective, high carbon yield, and superior performance coal-based hard carbon. When utilized as anode for sodium-ion batteries, the prepared coal-based hard carbon exhibits a high reversible capacity of 313.5 mAh g−1, along with excellent rate capability and long cycling stability.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Solid State Ionics
Solid State Ionics 物理-物理:凝聚态物理
CiteScore
6.10
自引率
3.10%
发文量
152
审稿时长
58 days
期刊介绍: This interdisciplinary journal is devoted to the physics, chemistry and materials science of diffusion, mass transport, and reactivity of solids. The major part of each issue is devoted to articles on: (i) physics and chemistry of defects in solids; (ii) reactions in and on solids, e.g. intercalation, corrosion, oxidation, sintering; (iii) ion transport measurements, mechanisms and theory; (iv) solid state electrochemistry; (v) ionically-electronically mixed conducting solids. Related technological applications are also included, provided their characteristics are interpreted in terms of the basic solid state properties. Review papers and relevant symposium proceedings are welcome.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信