Xiaolin Zhang , Lin Weng , Mingyu Chen , Defang Zhao , Qi Wang , Zhe Liu
{"title":"用海藻酸纤维辅助 MXene 对废纤维素纤维进行简单回收，制成防火和电磁干扰屏蔽复合材料","authors":"Xiaolin Zhang , Lin Weng , Mingyu Chen , Defang Zhao , Qi Wang , Zhe Liu","doi":"10.1016/j.polymdegradstab.2024.110955","DOIUrl":null,"url":null,"abstract":"<div><p>Textile wastes rapidly grow into a challenge when a significant portion of them are processed by landfilling or incineration, leading to hazardous solid and volatile pollutants. This work investigated the utilization of wasted cellulose fiber by recycling it with calcium alginate fiber into a fireproof composite filler as a circular economy strategy, followed by the modification with MXene dispersion to further enhance its fire resistance and offer it the electromagnetic interference shielding ability. A comprehensive investigation elucidated the flame retardant mechanism of the composite felt via studying its combustion behavior, the microstructural morphology of residue char, and the gasous compounds produced. The results indicated that this composite felt generated a large number of nonflammable gas species and fibrous residue char, serving as a natural barrier to impede the fuel supply and suppress heat diffusion, thereby endowing the composite felt with an outstanding fire retardant performance and reduced carbon footprint. Compared to other textile waste recycling processes, the opening-carding-needling punch technique employed in this study was more energy-efficient and environmentally friendly. The recycling of waste cellulose fiber into functional fireproof composites not only extended the practical applications of waste resources but also mitigated the negative environmental impact of textile disposal.</p></div>","PeriodicalId":406,"journal":{"name":"Polymer Degradation and Stability","volume":"229 ","pages":"Article 110955"},"PeriodicalIF":6.3000,"publicationDate":"2024-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"MXene assisted simple recycle of waste cellulose fiber with alginate fiber into fireproof and electromagnetic interference shielding composite\",\"authors\":\"Xiaolin Zhang , Lin Weng , Mingyu Chen , Defang Zhao , Qi Wang , Zhe Liu\",\"doi\":\"10.1016/j.polymdegradstab.2024.110955\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Textile wastes rapidly grow into a challenge when a significant portion of them are processed by landfilling or incineration, leading to hazardous solid and volatile pollutants. This work investigated the utilization of wasted cellulose fiber by recycling it with calcium alginate fiber into a fireproof composite filler as a circular economy strategy, followed by the modification with MXene dispersion to further enhance its fire resistance and offer it the electromagnetic interference shielding ability. A comprehensive investigation elucidated the flame retardant mechanism of the composite felt via studying its combustion behavior, the microstructural morphology of residue char, and the gasous compounds produced. The results indicated that this composite felt generated a large number of nonflammable gas species and fibrous residue char, serving as a natural barrier to impede the fuel supply and suppress heat diffusion, thereby endowing the composite felt with an outstanding fire retardant performance and reduced carbon footprint. Compared to other textile waste recycling processes, the opening-carding-needling punch technique employed in this study was more energy-efficient and environmentally friendly. The recycling of waste cellulose fiber into functional fireproof composites not only extended the practical applications of waste resources but also mitigated the negative environmental impact of textile disposal.</p></div>\",\"PeriodicalId\":406,\"journal\":{\"name\":\"Polymer Degradation and Stability\",\"volume\":\"229 \",\"pages\":\"Article 110955\"},\"PeriodicalIF\":6.3000,\"publicationDate\":\"2024-08-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Degradation and Stability\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0141391024002994\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Degradation and Stability","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0141391024002994","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
MXene assisted simple recycle of waste cellulose fiber with alginate fiber into fireproof and electromagnetic interference shielding composite
Textile wastes rapidly grow into a challenge when a significant portion of them are processed by landfilling or incineration, leading to hazardous solid and volatile pollutants. This work investigated the utilization of wasted cellulose fiber by recycling it with calcium alginate fiber into a fireproof composite filler as a circular economy strategy, followed by the modification with MXene dispersion to further enhance its fire resistance and offer it the electromagnetic interference shielding ability. A comprehensive investigation elucidated the flame retardant mechanism of the composite felt via studying its combustion behavior, the microstructural morphology of residue char, and the gasous compounds produced. The results indicated that this composite felt generated a large number of nonflammable gas species and fibrous residue char, serving as a natural barrier to impede the fuel supply and suppress heat diffusion, thereby endowing the composite felt with an outstanding fire retardant performance and reduced carbon footprint. Compared to other textile waste recycling processes, the opening-carding-needling punch technique employed in this study was more energy-efficient and environmentally friendly. The recycling of waste cellulose fiber into functional fireproof composites not only extended the practical applications of waste resources but also mitigated the negative environmental impact of textile disposal.
期刊介绍：
Polymer Degradation and Stability deals with the degradation reactions and their control which are a major preoccupation of practitioners of the many and diverse aspects of modern polymer technology.
Deteriorative reactions occur during processing, when polymers are subjected to heat, oxygen and mechanical stress, and during the useful life of the materials when oxygen and sunlight are the most important degradative agencies. In more specialised applications, degradation may be induced by high energy radiation, ozone, atmospheric pollutants, mechanical stress, biological action, hydrolysis and many other influences. The mechanisms of these reactions and stabilisation processes must be understood if the technology and application of polymers are to continue to advance. The reporting of investigations of this kind is therefore a major function of this journal.
However there are also new developments in polymer technology in which degradation processes find positive applications. For example, photodegradable plastics are now available, the recycling of polymeric products will become increasingly important, degradation and combustion studies are involved in the definition of the fire hazards which are associated with polymeric materials and the microelectronics industry is vitally dependent upon polymer degradation in the manufacture of its circuitry. Polymer properties may also be improved by processes like curing and grafting, the chemistry of which can be closely related to that which causes physical deterioration in other circumstances.
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