{"title":"用于还原二氧化碳的金属聚(庚嗪亚胺)的光催化性能","authors":"","doi":"10.1016/j.cartre.2024.100396","DOIUrl":null,"url":null,"abstract":"<div><p>Poly(heptazine imide) (PHI), a carbon nitride polymer, is a highly efficient visible-light-driven photocatalytic material. We aimed to improve its photocatalytic performance for CO<sub>2</sub> conversion. We prepared M-PHIs by encapsulating different metals (<em>M</em> = <em>K</em>, Li, Rb, and Na) and H-PHIs, in which the metal of each M-PHI was ion-exchanged with a proton. We evaluated their photocatalytic activities for CO<sub>2</sub> conversion and found that Na-PHI and H-PHI, prepared from Na-PHI (H-PHI(NaCl)), showed more than twice the CO production efficiency of melon and other PHIs.</p><p>The high CO production efficiency of Na-PHI and H-PHI(NaCl) was attributed to their extremely smaller particle size compared with those of the other PHIs. By closely examining the synthesis conditions of Na-PHI, we have identified a method to intentionally synthesize M-PHI with small particle size. These results provide a new strategy for highly efficient CO<sub>2</sub> conversion using PHI.</p></div>","PeriodicalId":52629,"journal":{"name":"Carbon Trends","volume":null,"pages":null},"PeriodicalIF":3.1000,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667056924000774/pdfft?md5=912a300dfcfc2857fd587780ab6faf3f&pid=1-s2.0-S2667056924000774-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Photocatalytic performance of metal poly(heptazine imide) for carbon dioxide reduction\",\"authors\":\"\",\"doi\":\"10.1016/j.cartre.2024.100396\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Poly(heptazine imide) (PHI), a carbon nitride polymer, is a highly efficient visible-light-driven photocatalytic material. We aimed to improve its photocatalytic performance for CO<sub>2</sub> conversion. We prepared M-PHIs by encapsulating different metals (<em>M</em> = <em>K</em>, Li, Rb, and Na) and H-PHIs, in which the metal of each M-PHI was ion-exchanged with a proton. We evaluated their photocatalytic activities for CO<sub>2</sub> conversion and found that Na-PHI and H-PHI, prepared from Na-PHI (H-PHI(NaCl)), showed more than twice the CO production efficiency of melon and other PHIs.</p><p>The high CO production efficiency of Na-PHI and H-PHI(NaCl) was attributed to their extremely smaller particle size compared with those of the other PHIs. By closely examining the synthesis conditions of Na-PHI, we have identified a method to intentionally synthesize M-PHI with small particle size. These results provide a new strategy for highly efficient CO<sub>2</sub> conversion using PHI.</p></div>\",\"PeriodicalId\":52629,\"journal\":{\"name\":\"Carbon Trends\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2024-08-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2667056924000774/pdfft?md5=912a300dfcfc2857fd587780ab6faf3f&pid=1-s2.0-S2667056924000774-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Carbon Trends\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2667056924000774\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Carbon Trends","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2667056924000774","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Photocatalytic performance of metal poly(heptazine imide) for carbon dioxide reduction
Poly(heptazine imide) (PHI), a carbon nitride polymer, is a highly efficient visible-light-driven photocatalytic material. We aimed to improve its photocatalytic performance for CO2 conversion. We prepared M-PHIs by encapsulating different metals (M = K, Li, Rb, and Na) and H-PHIs, in which the metal of each M-PHI was ion-exchanged with a proton. We evaluated their photocatalytic activities for CO2 conversion and found that Na-PHI and H-PHI, prepared from Na-PHI (H-PHI(NaCl)), showed more than twice the CO production efficiency of melon and other PHIs.
The high CO production efficiency of Na-PHI and H-PHI(NaCl) was attributed to their extremely smaller particle size compared with those of the other PHIs. By closely examining the synthesis conditions of Na-PHI, we have identified a method to intentionally synthesize M-PHI with small particle size. These results provide a new strategy for highly efficient CO2 conversion using PHI.