用于还原二氧化碳的金属聚(庚嗪亚胺)的光催化性能

IF 3.1 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
{"title":"用于还原二氧化碳的金属聚(庚嗪亚胺)的光催化性能","authors":"","doi":"10.1016/j.cartre.2024.100396","DOIUrl":null,"url":null,"abstract":"<div><p>Poly(heptazine imide) (PHI), a carbon nitride polymer, is a highly efficient visible-light-driven photocatalytic material. We aimed to improve its photocatalytic performance for CO<sub>2</sub> conversion. We prepared M-PHIs by encapsulating different metals (<em>M</em> = <em>K</em>, Li, Rb, and Na) and H-PHIs, in which the metal of each M-PHI was ion-exchanged with a proton. We evaluated their photocatalytic activities for CO<sub>2</sub> conversion and found that Na-PHI and H-PHI, prepared from Na-PHI (H-PHI(NaCl)), showed more than twice the CO production efficiency of melon and other PHIs.</p><p>The high CO production efficiency of Na-PHI and H-PHI(NaCl) was attributed to their extremely smaller particle size compared with those of the other PHIs. By closely examining the synthesis conditions of Na-PHI, we have identified a method to intentionally synthesize M-PHI with small particle size. These results provide a new strategy for highly efficient CO<sub>2</sub> conversion using PHI.</p></div>","PeriodicalId":52629,"journal":{"name":"Carbon Trends","volume":null,"pages":null},"PeriodicalIF":3.1000,"publicationDate":"2024-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667056924000774/pdfft?md5=912a300dfcfc2857fd587780ab6faf3f&pid=1-s2.0-S2667056924000774-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Photocatalytic performance of metal poly(heptazine imide) for carbon dioxide reduction\",\"authors\":\"\",\"doi\":\"10.1016/j.cartre.2024.100396\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Poly(heptazine imide) (PHI), a carbon nitride polymer, is a highly efficient visible-light-driven photocatalytic material. We aimed to improve its photocatalytic performance for CO<sub>2</sub> conversion. We prepared M-PHIs by encapsulating different metals (<em>M</em> = <em>K</em>, Li, Rb, and Na) and H-PHIs, in which the metal of each M-PHI was ion-exchanged with a proton. We evaluated their photocatalytic activities for CO<sub>2</sub> conversion and found that Na-PHI and H-PHI, prepared from Na-PHI (H-PHI(NaCl)), showed more than twice the CO production efficiency of melon and other PHIs.</p><p>The high CO production efficiency of Na-PHI and H-PHI(NaCl) was attributed to their extremely smaller particle size compared with those of the other PHIs. By closely examining the synthesis conditions of Na-PHI, we have identified a method to intentionally synthesize M-PHI with small particle size. These results provide a new strategy for highly efficient CO<sub>2</sub> conversion using PHI.</p></div>\",\"PeriodicalId\":52629,\"journal\":{\"name\":\"Carbon Trends\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2024-08-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2667056924000774/pdfft?md5=912a300dfcfc2857fd587780ab6faf3f&pid=1-s2.0-S2667056924000774-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Carbon Trends\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2667056924000774\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Carbon Trends","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2667056924000774","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

聚(庚嗪亚胺)(PHI)是一种氮化碳聚合物,是一种高效的可见光光催化材料。我们的目标是提高其在二氧化碳转化方面的光催化性能。我们通过封装不同的金属(M = K、Li、Rb 和 Na)制备了 M-PHIs 和 H-PHIs,其中每种 M-PHI 的金属都与质子进行了离子交换。我们评估了它们转化二氧化碳的光催化活性,发现由 Na-PHI 制备的 Na-PHI 和 H-PHI(H-PHI(NaCl))的二氧化碳生成效率是甜瓜和其他 PHI 的两倍多。通过仔细研究 Na-PHI 的合成条件,我们找到了一种有意合成小粒径 M-PHI 的方法。这些结果为利用 PHI 高效转化二氧化碳提供了一种新策略。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Photocatalytic performance of metal poly(heptazine imide) for carbon dioxide reduction

Photocatalytic performance of metal poly(heptazine imide) for carbon dioxide reduction

Poly(heptazine imide) (PHI), a carbon nitride polymer, is a highly efficient visible-light-driven photocatalytic material. We aimed to improve its photocatalytic performance for CO2 conversion. We prepared M-PHIs by encapsulating different metals (M = K, Li, Rb, and Na) and H-PHIs, in which the metal of each M-PHI was ion-exchanged with a proton. We evaluated their photocatalytic activities for CO2 conversion and found that Na-PHI and H-PHI, prepared from Na-PHI (H-PHI(NaCl)), showed more than twice the CO production efficiency of melon and other PHIs.

The high CO production efficiency of Na-PHI and H-PHI(NaCl) was attributed to their extremely smaller particle size compared with those of the other PHIs. By closely examining the synthesis conditions of Na-PHI, we have identified a method to intentionally synthesize M-PHI with small particle size. These results provide a new strategy for highly efficient CO2 conversion using PHI.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Carbon Trends
Carbon Trends Materials Science-Materials Science (miscellaneous)
CiteScore
4.60
自引率
0.00%
发文量
88
审稿时长
77 days
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信