[中国木制家具制造业 VOCs 排放特征及环境影响]。

Q2 Environmental Science
Wen-Wen Liu, Xia Shao, Wei Teng
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引用次数: 0

摘要

木制家具制造业产生的挥发性有机化合物(VOCs)是木制家具制造业的一个重要排放源。为研究木质家具制造行业挥发性有机物的排放特征及其对环境的影响,我们选取了中国 9 家典型的木质家具制造企业进行样品采集和挥发性有机物检测。采用最大增量反应性(MIR)法和二次有机气溶胶(SOA)形成电位法来量化 O3 和 SOA 生成的相应贡献。结果表明:①不同类型涂装废气中 VOCs 的排放浓度不同。溶剂型涂料废气中的 VOCs 排放浓度明显高于水性涂料废气和紫外线(UV)涂料废气,且溶剂型涂料废气中的 VOCs 排放浓度明显高于水性涂料废气和紫外线(UV)涂料废气。涂层废气中的 VOCs 排放浓度分别为 2.82 - 155.37、1.13 - 104.45 和 0.57 - 1.15 mg-m-3。溶剂型涂料废气中的主要有机物为酯类,占 45.88%,醋酸丁酯(31.07%)为主要 VOCs 物种。是 VOCs 的主要种类。水性涂料废气和 UV 涂料废气中的主要有机基团为醇类,水性涂料废气和 UV 涂料废气中的主要 VOCs 种类均为乙醇,分别占 46.63%和 34.32%。溶剂型涂料、水性涂料和 UV 涂料排放的 VOCs 的 OFP 分别为 149.23、50.90 和 1.87 mg-m-3,而不同类型涂料 OFP 的主要贡献成分分别为间二甲苯(26.61%)、乙醇(36.35%)和乙醇(23.98%)。溶剂型涂料、水性涂料和 UV 涂料排放的 VOCs SOA 分别为 0.76、0.25 和 0.01 mg-m-3。各类涂料产生的 SOA 以芳烃为主(96.35%-98.96%),主要活性化合物为甲苯、乙苯和二甲苯。比较溶剂型涂料、水性涂料和 UV 涂料废气对环境的影响发现,溶剂型涂料排放的 VOCs 产生的 OFP 和 SOA 远高于水性涂料和 UV 涂料。因此,从源头上实施水性涂料和紫外线涂料的替代策略,可以有效减少 VOCs 的排放,降低 OFP 和 SOA 的产生。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
[Emission Characteristics and Environmental Impact of VOCs from Wooden Furniture-manufacturing Industry in China].

Volatile organic compounds (VOCs) from the wooden furniture-manufacturing industry are an important emission source. To study the emission characteristics of VOCs from the wooden furniture-manufacturing industry and associated environmental impacts, nine typical wooden furniture manufacturers in China were selected to carry out sample collection and VOCs detection. The maximum incremental reactivity (MIR) method and secondary organic aerosol (SOA) formation potential method were used to quantify the corresponding contributions to the generation of O3 and SOA. The results showed that: ① The concentrations of VOCs emitted from different types of coating exhaust gas were different. The emission concentration of VOCs in solvent-based coating exhaust gas was significantly higher than that in water-based coating exhaust gas and ultra-violet (UV) coating exhaust gas, and the VOCs emission concentrations ranged between 2.82 - 155.37, 1.13 - 104.45, and 0.57 - 1.15 mg·m-3, respectively. ② The main organic group in solvent-based coating exhaust gas was esters, accounting for 45.88%, and butyl acetate (31.07%) was the main VOCs species. The main organic group in water-based coating exhaust gas and UV coating exhaust gas was alcohols, and the main VOCs species in water-based coating exhaust gas and UV coating exhaust gas were both ethanol, accounting for 46.63% and 34.32%, respectively. ③ The OFP of VOCs emitted by solvent-based coating, water-based coating, and UV coating were 149.23, 50.90, and 1.87 mg·m-3, respectively, and the primary contributing components of OFP of different types of coating were m/p-xylene (26.61%), ethanol (36.35%), and ethanol (23.98%), respectively. ④ The SOA of VOCs emitted by solvent-based coating, water-based coating, and UV coating were 0.76, 0.25, and 0.01 mg·m-3, respectively. The SOA generation of various types of coating was dominated by aromatics(96.35%-98.96%), and the main active compounds were toluene, ethylbenzene, and xylene. ⑤ Comparing the environmental impact of exhaust gas from solvent-based coating, water-based coating, and UV coating, it was found that the OFP and SOA generated by the VOCs emitted from solvent-based coating were much higher than those for water-based coating and UV coating. Therefore, the implementation of water-based coating and UV coating substitution strategy from the source could effectively reduce VOCs emissions and abate OFP and SOA productions.

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Huanjing Kexue/Environmental Science
Huanjing Kexue/Environmental Science Environmental Science-Environmental Science (all)
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