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引用次数: 0
摘要
封面展示的是中国流行的扑克游戏--斗地主,其中四张相似牌的组合被称为 "炸弹",可以击败其他组合,因此 "炸弹 "在这个游戏中就像王牌一样。在过去的几十年里,人们开发出了多种二氟甲基自由基前体化合物,它们具有高效率、良好的选择性和广泛的底物范围,可用于自由基二氟甲基化反应。在这里,这些试剂被形象地比喻为 "爆炸性 "生成二氟甲基自由基的 "牌";它们可以被视为自由基二氟甲基化反应中的 "王牌"。有一张牌还没有翻开,这表明它是一种尚未发现的试剂。它的结构是什么?它会成为强力的自由基二氟甲基化试剂,形成 "王牌炸弹 "吗?让我们拭目以待。更多信息,请参阅 X. Li 和 Q. Song 的综述(DOI: 10.1002/ejoc.202400423)。
Front Cover: Introduction of Difluoromethyl Through Radical Pathways (Eur. J. Org. Chem. 31/2024)
The Front Cover shows a popular Chinese poker game, Dou Di Zhu “fight the landlord”, in which a combination of four similar cards, referred to as a “bomb”, can beat other combinations, so “bombs” are like trumps in this game. During the past decades, a diverse range of difluoromethyl radical precursor compounds with high efficiency, good selectivities, and broad substrate scopes have been developed for radical difluoromethylation reactions. Here, these reagents are visualized as cards to “explosively” generate the difluoromethyl radical; they can be regarded as the “trumps” in the radical difluoromethylation. One card has still not been turned over; this indicates that it is an undiscovered reagent. What is its structure? Will it become a powerful radical difluoromethylation reagent to form an “ace bomb”? Let's wait and see. More information can be found in the Review by X. Li and Q. Song (DOI: 10.1002/ejoc.202400423).
期刊介绍:
The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies.
The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry:
Liebigs Annalen
Bulletin des Sociétés Chimiques Belges
Bulletin de la Société Chimique de France
Gazzetta Chimica Italiana
Recueil des Travaux Chimiques des Pays-Bas
Anales de Química
Chimika Chronika
Revista Portuguesa de Química
ACH—Models in Chemistry
Polish Journal of Chemistry.