{"title":"从根本上了解普鲁士蓝及其类似物,以实现卓越的电容式去离子:从纳米建筑学的角度看问题","authors":"","doi":"10.1016/j.ccr.2024.216100","DOIUrl":null,"url":null,"abstract":"<div><p>Capacitive deionization (CDI) offers an appealing electrochemical solution for water treatment, where electrode materials play a crucial role in ensuring the efficiency of CDI devices. The quest for novel electrode materials is driven by the need to enhance desalination capacity, cycling stability, ion selectivity, and energy efficiency, given that traditional carbon materials relying on electric double layer electrosorption principle often exhibit subpar desalination capabilities. Among the standout options, Prussian blue (Fe<sub>4</sub>[Fe(CN)<sub>6</sub>]<sub>3</sub>) and its analogs (PB/PBAs) have stood out in CDI systems due to their superior performance and durability as coordination polymers. Nevertheless, challenges persist in leveraging their full potential for CDI, stemming from issues like low desalination capacity, slow kinetics, poor conductivity, structural vulnerability, and limited electrochemical activity. Recent years have witnessed the emergence of innovative strategies aimed at addressing these obstacles, particularly through advancements in structural and compositional manipulation. This review seeks to consolidate the latest advancements in the nanoarchitectonics of PB/PBAs, exploring their classification, and synthesis methodologies, and delving into the fundamental principles governing their utility in CDI applications—anchored in considerations of thermodynamics, kinetics, and mechanisms. Notably, the review underscores the prevailing challenges faced by PB/PBAs in CDI deployment, prompting the discussion of proactive approaches to guide future material innovation and usage. By shedding light on the ongoing efforts to enhance PB/PBAs for CDI, this review anticipates that advancements in nanoarchitectonics will unlock fresh possibilities in the realm of high-performance CDI material design and implementation.</p></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":null,"pages":null},"PeriodicalIF":20.3000,"publicationDate":"2024-08-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fundamental understanding of Prussian blue and its analogues for superior capacitive deionization: A perspective from nanoarchitectonics\",\"authors\":\"\",\"doi\":\"10.1016/j.ccr.2024.216100\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Capacitive deionization (CDI) offers an appealing electrochemical solution for water treatment, where electrode materials play a crucial role in ensuring the efficiency of CDI devices. The quest for novel electrode materials is driven by the need to enhance desalination capacity, cycling stability, ion selectivity, and energy efficiency, given that traditional carbon materials relying on electric double layer electrosorption principle often exhibit subpar desalination capabilities. Among the standout options, Prussian blue (Fe<sub>4</sub>[Fe(CN)<sub>6</sub>]<sub>3</sub>) and its analogs (PB/PBAs) have stood out in CDI systems due to their superior performance and durability as coordination polymers. Nevertheless, challenges persist in leveraging their full potential for CDI, stemming from issues like low desalination capacity, slow kinetics, poor conductivity, structural vulnerability, and limited electrochemical activity. Recent years have witnessed the emergence of innovative strategies aimed at addressing these obstacles, particularly through advancements in structural and compositional manipulation. This review seeks to consolidate the latest advancements in the nanoarchitectonics of PB/PBAs, exploring their classification, and synthesis methodologies, and delving into the fundamental principles governing their utility in CDI applications—anchored in considerations of thermodynamics, kinetics, and mechanisms. Notably, the review underscores the prevailing challenges faced by PB/PBAs in CDI deployment, prompting the discussion of proactive approaches to guide future material innovation and usage. By shedding light on the ongoing efforts to enhance PB/PBAs for CDI, this review anticipates that advancements in nanoarchitectonics will unlock fresh possibilities in the realm of high-performance CDI material design and implementation.</p></div>\",\"PeriodicalId\":289,\"journal\":{\"name\":\"Coordination Chemistry Reviews\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":20.3000,\"publicationDate\":\"2024-08-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Coordination Chemistry Reviews\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0010854524004466\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coordination Chemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010854524004466","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Fundamental understanding of Prussian blue and its analogues for superior capacitive deionization: A perspective from nanoarchitectonics
Capacitive deionization (CDI) offers an appealing electrochemical solution for water treatment, where electrode materials play a crucial role in ensuring the efficiency of CDI devices. The quest for novel electrode materials is driven by the need to enhance desalination capacity, cycling stability, ion selectivity, and energy efficiency, given that traditional carbon materials relying on electric double layer electrosorption principle often exhibit subpar desalination capabilities. Among the standout options, Prussian blue (Fe4[Fe(CN)6]3) and its analogs (PB/PBAs) have stood out in CDI systems due to their superior performance and durability as coordination polymers. Nevertheless, challenges persist in leveraging their full potential for CDI, stemming from issues like low desalination capacity, slow kinetics, poor conductivity, structural vulnerability, and limited electrochemical activity. Recent years have witnessed the emergence of innovative strategies aimed at addressing these obstacles, particularly through advancements in structural and compositional manipulation. This review seeks to consolidate the latest advancements in the nanoarchitectonics of PB/PBAs, exploring their classification, and synthesis methodologies, and delving into the fundamental principles governing their utility in CDI applications—anchored in considerations of thermodynamics, kinetics, and mechanisms. Notably, the review underscores the prevailing challenges faced by PB/PBAs in CDI deployment, prompting the discussion of proactive approaches to guide future material innovation and usage. By shedding light on the ongoing efforts to enhance PB/PBAs for CDI, this review anticipates that advancements in nanoarchitectonics will unlock fresh possibilities in the realm of high-performance CDI material design and implementation.
期刊介绍:
Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers.
The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.