实现紫苏萜 A 和 B 的立体化学分配：天然产物可能结构的全合成。

IF 2.7 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2024-09-18 DOI:10.1039/d4ob01118j

Kenichi Kobayashi , Yusuke Honma , Kosaku Tanaka , Momoko Suzuki , Kazuhiko Takatori , Hiroshi Kogen

引用次数: 0

摘要

合成了紫罗兰茄素 A 和 B 的可能结构。我们的合成结果表明，考虑到它们的推定生物合成途径，紫罗兰香精 A 可能是（2R,3R,4S,7S）和（2S,3S,4R,7S）异构体的混合物，而紫罗兰香精 B 可能是（2R,3S,4S,7S）和（2S,3R,4R,7S）异构体的混合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Toward the stereochemical assignment of euvesperins A and B: total synthesis of the possible structures of the natural products†

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Toward the stereochemical assignment of euvesperins A and B: total synthesis of the possible structures of the natural products†

The possible structures of euvesperins A and B were synthesized. The results of our synthesis suggest that euvesperin A may be a mixture of the (2R,3R,4S,7S) and (2S,3S,4R,7S) isomers and euvesperin B may be a mixture of the (2R,3S,4S,7S) and (2S,3R,4R,7S) isomers in consideration of their putative biosynthetic pathways.

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.