利用反应分子动力学研究微孔对煤热解过程的影响

IF 5.6 2区 工程技术 Q2 ENERGY & FUELS
Mo Zheng , Xiaoxia Li
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引用次数: 0

摘要

微孔结构可以作为煤热解过程中中间产物和轻焦油产物的扩散通道,这对于调制所需的焦油或焦炭产物非常重要。本研究利用大规模 ReaxFF MD 模拟和人工添加微孔策略的合理模型,首次从原子模拟的角度探讨了海拉尔煤热解过程中微孔对产物分布和反应机理的影响。结果表明,微孔结构确实对高温下煤热解过程中主要焦油产物的分布和竞争反应有重要影响。微孔能显著加速 C-C 键的断裂,从而促进分解反应,并抑制伴随着更多 sp2 结构碳形成的炭的重组反应。根据煤热解过程中得到的焦炭产物中的含氧键行为,可以发现煤结构中的微孔越多,焦炭前驱体中的 Csp3-O 键就越多,Csp2-O 键就越少。特别是带环状基团的轻质焦油产物比链状产物受微孔结构的影响更大。考虑到现有实验技术在微孔检测方面的局限性,该策略为深入研究微孔对反应的影响提供了新的思路,可为实验观察和焦油产物调控提供补充。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Micropore effects on coal pyrolysis process investigated by using reactive molecular dynamics

The micropore structure can serve as the diffusion channels for intermediates and light tar products during coal pyrolysis, which is very important for modulating the desired tar or char products. In this work, the micropore effects on product distribution and the reaction mechanisms during Hailaer coal pyrolysis was explored for the first time from the atomistic simulation point of view by using large-scale ReaxFF MD simulation and the reasonable model with the artificially adding micropore strategy. The results suggest that the micropore structure indeed has a significant impact on the major tar product distribution and competitive reactions during coal pyrolysis process at high temperature. The micropore can promote decomposition reactions through accelerating C–C bond breaking significantly and inhibit the recombination reactions accompanied with the char formation with more carbon in sp2 structure. Based on the oxygen-containing bond behaviors in char products obtained from coal pyrolysis process, it is unraveled that the more micropore exits in coal structure, the more Csp3-O bonds and less Csp2-O bonds in char precursors. Particularly, the light tar products with ring groups are more influenced by micorpore structures than those chain products. Considering that the limitation of current experimental techniques in micropore detection, the strategy sheds new light on the depth investigation of micropore effects on reactions, which can provide complement for experimental observations and tar product modulation.

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来源期刊
Journal of The Energy Institute
Journal of The Energy Institute 工程技术-能源与燃料
CiteScore
10.60
自引率
5.30%
发文量
166
审稿时长
16 days
期刊介绍: The Journal of the Energy Institute provides peer reviewed coverage of original high quality research on energy, engineering and technology.The coverage is broad and the main areas of interest include: Combustion engineering and associated technologies; process heating; power generation; engines and propulsion; emissions and environmental pollution control; clean coal technologies; carbon abatement technologies Emissions and environmental pollution control; safety and hazards; Clean coal technologies; carbon abatement technologies, including carbon capture and storage, CCS; Petroleum engineering and fuel quality, including storage and transport Alternative energy sources; biomass utilisation and biomass conversion technologies; energy from waste, incineration and recycling Energy conversion, energy recovery and energy efficiency; space heating, fuel cells, heat pumps and cooling systems Energy storage The journal''s coverage reflects changes in energy technology that result from the transition to more efficient energy production and end use together with reduced carbon emission.
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