{"title":"利用反应分子动力学研究微孔对煤热解过程的影响","authors":"Mo Zheng , Xiaoxia Li","doi":"10.1016/j.joei.2024.101798","DOIUrl":null,"url":null,"abstract":"<div><p>The micropore structure can serve as the diffusion channels for intermediates and light tar products during coal pyrolysis, which is very important for modulating the desired tar or char products. In this work, the micropore effects on product distribution and the reaction mechanisms during Hailaer coal pyrolysis was explored for the first time from the atomistic simulation point of view by using large-scale ReaxFF MD simulation and the reasonable model with the artificially adding micropore strategy. The results suggest that the micropore structure indeed has a significant impact on the major tar product distribution and competitive reactions during coal pyrolysis process at high temperature. The micropore can promote decomposition reactions through accelerating C–C bond breaking significantly and inhibit the recombination reactions accompanied with the char formation with more carbon in <em>sp2</em> structure. Based on the oxygen-containing bond behaviors in char products obtained from coal pyrolysis process, it is unraveled that the more micropore exits in coal structure, the more C<sub><em>sp3</em></sub>-O bonds and less C<sub><em>sp2</em></sub>-O bonds in char precursors. Particularly, the light tar products with ring groups are more influenced by micorpore structures than those chain products. Considering that the limitation of current experimental techniques in micropore detection, the strategy sheds new light on the depth investigation of micropore effects on reactions, which can provide complement for experimental observations and tar product modulation.</p></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":"117 ","pages":"Article 101798"},"PeriodicalIF":5.6000,"publicationDate":"2024-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Micropore effects on coal pyrolysis process investigated by using reactive molecular dynamics\",\"authors\":\"Mo Zheng , Xiaoxia Li\",\"doi\":\"10.1016/j.joei.2024.101798\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The micropore structure can serve as the diffusion channels for intermediates and light tar products during coal pyrolysis, which is very important for modulating the desired tar or char products. In this work, the micropore effects on product distribution and the reaction mechanisms during Hailaer coal pyrolysis was explored for the first time from the atomistic simulation point of view by using large-scale ReaxFF MD simulation and the reasonable model with the artificially adding micropore strategy. The results suggest that the micropore structure indeed has a significant impact on the major tar product distribution and competitive reactions during coal pyrolysis process at high temperature. The micropore can promote decomposition reactions through accelerating C–C bond breaking significantly and inhibit the recombination reactions accompanied with the char formation with more carbon in <em>sp2</em> structure. Based on the oxygen-containing bond behaviors in char products obtained from coal pyrolysis process, it is unraveled that the more micropore exits in coal structure, the more C<sub><em>sp3</em></sub>-O bonds and less C<sub><em>sp2</em></sub>-O bonds in char precursors. Particularly, the light tar products with ring groups are more influenced by micorpore structures than those chain products. Considering that the limitation of current experimental techniques in micropore detection, the strategy sheds new light on the depth investigation of micropore effects on reactions, which can provide complement for experimental observations and tar product modulation.</p></div>\",\"PeriodicalId\":17287,\"journal\":{\"name\":\"Journal of The Energy Institute\",\"volume\":\"117 \",\"pages\":\"Article 101798\"},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2024-08-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Energy Institute\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1743967124002769\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Energy Institute","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1743967124002769","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Micropore effects on coal pyrolysis process investigated by using reactive molecular dynamics
The micropore structure can serve as the diffusion channels for intermediates and light tar products during coal pyrolysis, which is very important for modulating the desired tar or char products. In this work, the micropore effects on product distribution and the reaction mechanisms during Hailaer coal pyrolysis was explored for the first time from the atomistic simulation point of view by using large-scale ReaxFF MD simulation and the reasonable model with the artificially adding micropore strategy. The results suggest that the micropore structure indeed has a significant impact on the major tar product distribution and competitive reactions during coal pyrolysis process at high temperature. The micropore can promote decomposition reactions through accelerating C–C bond breaking significantly and inhibit the recombination reactions accompanied with the char formation with more carbon in sp2 structure. Based on the oxygen-containing bond behaviors in char products obtained from coal pyrolysis process, it is unraveled that the more micropore exits in coal structure, the more Csp3-O bonds and less Csp2-O bonds in char precursors. Particularly, the light tar products with ring groups are more influenced by micorpore structures than those chain products. Considering that the limitation of current experimental techniques in micropore detection, the strategy sheds new light on the depth investigation of micropore effects on reactions, which can provide complement for experimental observations and tar product modulation.
期刊介绍:
The Journal of the Energy Institute provides peer reviewed coverage of original high quality research on energy, engineering and technology.The coverage is broad and the main areas of interest include:
Combustion engineering and associated technologies; process heating; power generation; engines and propulsion; emissions and environmental pollution control; clean coal technologies; carbon abatement technologies
Emissions and environmental pollution control; safety and hazards;
Clean coal technologies; carbon abatement technologies, including carbon capture and storage, CCS;
Petroleum engineering and fuel quality, including storage and transport
Alternative energy sources; biomass utilisation and biomass conversion technologies; energy from waste, incineration and recycling
Energy conversion, energy recovery and energy efficiency; space heating, fuel cells, heat pumps and cooling systems
Energy storage
The journal''s coverage reflects changes in energy technology that result from the transition to more efficient energy production and end use together with reduced carbon emission.