Lingfeng Xu , Lili Zeng , Ting Ouyang , Xinmin Deng , Xinya Liu , Runlin Han
{"title":"优化芥酸提取物,作为液体安全粘度检测的天然探针","authors":"Lingfeng Xu , Lili Zeng , Ting Ouyang , Xinmin Deng , Xinya Liu , Runlin Han","doi":"10.1016/j.arabjc.2024.105954","DOIUrl":null,"url":null,"abstract":"<div><p>As the main substate participating during the liquid metamorphism processes, the abnormal micro-environmental viscosity is closely associated with the occurrence and development of objective circumstance degradation. Thus, it is of great importance to establish the convenient detection method toward viscosity monitoring. This work is focused on extracting one kind of erucic acid-based molecular probe (EAd) for sensing viscosity fluctuations in liquids. The electron donor phenolic hydroxyl group and acceptor carboxyl have established in this molecular structure <em>via</em> a coincidental pathway. Twisted intramolecular charge transfer (TICT) was formed, and the rotatable conjugate structure was utilized as the recognition site. Due to the restriction of rotatable parts, higher emission fluorescent signal can be found in the high-viscosity micro-environment. And a large Stokes shift (83.3 nm in glycerol), narrower energy band, high selectivity (x = 0.56), adaptability, sensitivity, and good photo-stability, the applications of signal releasing in the complex liquid system can be achieved. Moreover, this natural probe EAd can identify the thickening efficiency in a non-invasively mode, in particular, viscosity fluctuations have been screened and spoiled samples can be distinguished by analyzing signal intensities. We hope that natural scaffold will provide a new reference toward liquid quality and safety inspection.</p></div>","PeriodicalId":249,"journal":{"name":"Arabian Journal of Chemistry","volume":"17 10","pages":"Article 105954"},"PeriodicalIF":5.3000,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S1878535224003563/pdfft?md5=a5be383905a739f377d7b7eaa9f8bf29&pid=1-s2.0-S1878535224003563-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Optimized erucic acid-based extract as a natural probe for viscosity detection of liquid safety\",\"authors\":\"Lingfeng Xu , Lili Zeng , Ting Ouyang , Xinmin Deng , Xinya Liu , Runlin Han\",\"doi\":\"10.1016/j.arabjc.2024.105954\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>As the main substate participating during the liquid metamorphism processes, the abnormal micro-environmental viscosity is closely associated with the occurrence and development of objective circumstance degradation. Thus, it is of great importance to establish the convenient detection method toward viscosity monitoring. This work is focused on extracting one kind of erucic acid-based molecular probe (EAd) for sensing viscosity fluctuations in liquids. The electron donor phenolic hydroxyl group and acceptor carboxyl have established in this molecular structure <em>via</em> a coincidental pathway. Twisted intramolecular charge transfer (TICT) was formed, and the rotatable conjugate structure was utilized as the recognition site. Due to the restriction of rotatable parts, higher emission fluorescent signal can be found in the high-viscosity micro-environment. And a large Stokes shift (83.3 nm in glycerol), narrower energy band, high selectivity (x = 0.56), adaptability, sensitivity, and good photo-stability, the applications of signal releasing in the complex liquid system can be achieved. Moreover, this natural probe EAd can identify the thickening efficiency in a non-invasively mode, in particular, viscosity fluctuations have been screened and spoiled samples can be distinguished by analyzing signal intensities. We hope that natural scaffold will provide a new reference toward liquid quality and safety inspection.</p></div>\",\"PeriodicalId\":249,\"journal\":{\"name\":\"Arabian Journal of Chemistry\",\"volume\":\"17 10\",\"pages\":\"Article 105954\"},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2024-08-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S1878535224003563/pdfft?md5=a5be383905a739f377d7b7eaa9f8bf29&pid=1-s2.0-S1878535224003563-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Arabian Journal of Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1878535224003563\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Arabian Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1878535224003563","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Optimized erucic acid-based extract as a natural probe for viscosity detection of liquid safety
As the main substate participating during the liquid metamorphism processes, the abnormal micro-environmental viscosity is closely associated with the occurrence and development of objective circumstance degradation. Thus, it is of great importance to establish the convenient detection method toward viscosity monitoring. This work is focused on extracting one kind of erucic acid-based molecular probe (EAd) for sensing viscosity fluctuations in liquids. The electron donor phenolic hydroxyl group and acceptor carboxyl have established in this molecular structure via a coincidental pathway. Twisted intramolecular charge transfer (TICT) was formed, and the rotatable conjugate structure was utilized as the recognition site. Due to the restriction of rotatable parts, higher emission fluorescent signal can be found in the high-viscosity micro-environment. And a large Stokes shift (83.3 nm in glycerol), narrower energy band, high selectivity (x = 0.56), adaptability, sensitivity, and good photo-stability, the applications of signal releasing in the complex liquid system can be achieved. Moreover, this natural probe EAd can identify the thickening efficiency in a non-invasively mode, in particular, viscosity fluctuations have been screened and spoiled samples can be distinguished by analyzing signal intensities. We hope that natural scaffold will provide a new reference toward liquid quality and safety inspection.
期刊介绍:
The Arabian Journal of Chemistry is an English language, peer-reviewed scholarly publication in the area of chemistry. The Arabian Journal of Chemistry publishes original papers, reviews and short reports on, but not limited to: inorganic, physical, organic, analytical and biochemistry.
The Arabian Journal of Chemistry is issued by the Arab Union of Chemists and is published by King Saud University together with the Saudi Chemical Society in collaboration with Elsevier and is edited by an international group of eminent researchers.