{"title":"基于 Ti3C2Tx 的多功能环氧复合涂层,实现智能响应和耐腐蚀/耐磨性","authors":"","doi":"10.1016/j.porgcoat.2024.108746","DOIUrl":null,"url":null,"abstract":"<div><p>Questions remain about the unreasonable collocation of Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> and nanocontainers resulting in the performance degradation of multi-function Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>-based epoxy composite coating. Here, mesoporous SiO<sub>2</sub> nanocontainers (SNT) containing both potassium thiocyanate and hexadecyl trimethyl ammonium bromide (CTAB) were loaded on MXene-based platform (SNT-on-MP) to achieve a novel epoxy coating (SNT-on-MP@EP) with the integrated functions of self-warning, self-healing, anti-corrosion and anti-wear. In the damaged area, the thiocyanate groups combined with Fe<sup>3+</sup> ions to form a blood-red color display, and the formed coordination compound and CTAB as corrosion inhibitors were deposited on the metal substrate, thus showing intelligent response function. Besides, because of passive and active synergistic protection functions, the lowest-frequency impedance value of SNT-on-MP@EP maintained 5.74 × 10<sup>7</sup> Ω·cm<sup>2</sup> after 4 weeks of exposure in salt water environment, which was increased by two orders of magnitude compared with pure epoxy coating. Under the reciprocating sliding friction, the wear rate of SNT-on-MP@EP reached 5.32 × 10<sup>−5</sup> mm<sup>3</sup>/N·m, and was reduced by 58.29 %, owing to the formation of lubricant film at the friction interface and the enhancement of the deformation resistance of the coating. The reasonable collocation of SNT and Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>-based platform eliminated the problem of weak interaction between traditional inorganic nanocontainer and water-based epoxy coating, thus giving full play to the advantages of both.</p></div>","PeriodicalId":20834,"journal":{"name":"Progress in Organic Coatings","volume":null,"pages":null},"PeriodicalIF":6.5000,"publicationDate":"2024-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Multifunctional Ti3C2Tx-based epoxy composite coating towards intelligent response and corrosion/wear resistance\",\"authors\":\"\",\"doi\":\"10.1016/j.porgcoat.2024.108746\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Questions remain about the unreasonable collocation of Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> and nanocontainers resulting in the performance degradation of multi-function Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>-based epoxy composite coating. Here, mesoporous SiO<sub>2</sub> nanocontainers (SNT) containing both potassium thiocyanate and hexadecyl trimethyl ammonium bromide (CTAB) were loaded on MXene-based platform (SNT-on-MP) to achieve a novel epoxy coating (SNT-on-MP@EP) with the integrated functions of self-warning, self-healing, anti-corrosion and anti-wear. In the damaged area, the thiocyanate groups combined with Fe<sup>3+</sup> ions to form a blood-red color display, and the formed coordination compound and CTAB as corrosion inhibitors were deposited on the metal substrate, thus showing intelligent response function. Besides, because of passive and active synergistic protection functions, the lowest-frequency impedance value of SNT-on-MP@EP maintained 5.74 × 10<sup>7</sup> Ω·cm<sup>2</sup> after 4 weeks of exposure in salt water environment, which was increased by two orders of magnitude compared with pure epoxy coating. Under the reciprocating sliding friction, the wear rate of SNT-on-MP@EP reached 5.32 × 10<sup>−5</sup> mm<sup>3</sup>/N·m, and was reduced by 58.29 %, owing to the formation of lubricant film at the friction interface and the enhancement of the deformation resistance of the coating. The reasonable collocation of SNT and Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub>-based platform eliminated the problem of weak interaction between traditional inorganic nanocontainer and water-based epoxy coating, thus giving full play to the advantages of both.</p></div>\",\"PeriodicalId\":20834,\"journal\":{\"name\":\"Progress in Organic Coatings\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":6.5000,\"publicationDate\":\"2024-08-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Progress in Organic Coatings\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0300944024005381\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Progress in Organic Coatings","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0300944024005381","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Multifunctional Ti3C2Tx-based epoxy composite coating towards intelligent response and corrosion/wear resistance
Questions remain about the unreasonable collocation of Ti3C2Tx and nanocontainers resulting in the performance degradation of multi-function Ti3C2Tx-based epoxy composite coating. Here, mesoporous SiO2 nanocontainers (SNT) containing both potassium thiocyanate and hexadecyl trimethyl ammonium bromide (CTAB) were loaded on MXene-based platform (SNT-on-MP) to achieve a novel epoxy coating (SNT-on-MP@EP) with the integrated functions of self-warning, self-healing, anti-corrosion and anti-wear. In the damaged area, the thiocyanate groups combined with Fe3+ ions to form a blood-red color display, and the formed coordination compound and CTAB as corrosion inhibitors were deposited on the metal substrate, thus showing intelligent response function. Besides, because of passive and active synergistic protection functions, the lowest-frequency impedance value of SNT-on-MP@EP maintained 5.74 × 107 Ω·cm2 after 4 weeks of exposure in salt water environment, which was increased by two orders of magnitude compared with pure epoxy coating. Under the reciprocating sliding friction, the wear rate of SNT-on-MP@EP reached 5.32 × 10−5 mm3/N·m, and was reduced by 58.29 %, owing to the formation of lubricant film at the friction interface and the enhancement of the deformation resistance of the coating. The reasonable collocation of SNT and Ti3C2Tx-based platform eliminated the problem of weak interaction between traditional inorganic nanocontainer and water-based epoxy coating, thus giving full play to the advantages of both.
期刊介绍:
The aim of this international journal is to analyse and publicise the progress and current state of knowledge in the field of organic coatings and related materials. The Editors and the Editorial Board members will solicit both review and research papers from academic and industrial scientists who are actively engaged in research and development or, in the case of review papers, have extensive experience in the subject to be reviewed. Unsolicited manuscripts will be accepted if they meet the journal''s requirements. The journal publishes papers dealing with such subjects as:
• Chemical, physical and technological properties of organic coatings and related materials
• Problems and methods of preparation, manufacture and application of these materials
• Performance, testing and analysis.