{"title":"生物质气化制取富氢合成气过程中 Pr1-xCexCoO3/dolomite 催化剂对节能减碳的影响分析","authors":"","doi":"10.1016/j.joei.2024.101766","DOIUrl":null,"url":null,"abstract":"<div><p>Biomass is considered a renewable green coal, and its clean and efficient utilization is of great significance for energy conservation and carbon reduction. One of the most critical aspects of biomass gasification is the selection of an appropriate catalyst. In this study, we synthesized a catalyst with 10 % Pr<sub>1-x</sub>Ce<sub>x</sub>CoO<sub>3</sub> supported on dolomite using the sol-gel method. We conducted graded internal circulation gasification experiments to produce hydrogen-rich syngas. The effects of element substitution in PrCoO<sub>3</sub>, temperature, catalyst composition, and steam injection rate on the products were investigated. The optimal gasification conditions were determined through response surface regression analysis. The data indicate that this catalyst can improve gasification efficiency, with Pr<sub>0.4</sub>Ce<sub>0.6</sub>CoO<sub>3</sub>/Dol showing the best catalytic performance. It effectively reduces the required gasification temperature and steam amount, decreases CO<sub>2</sub> production, and increases CO and H<sub>2</sub> yields. The catalyst accelerates the cleavage and ring-opening reactions of hydrocarbons, leading to terminal chain hydroxylation, followed by the dehydration-condensation of methyl groups into ethers. As the temperature rises, the rate of carboxyl group removal gradually exceeds the rate of carboxyl group formation via the oxidation of hydroxyl and ether chains, resulting in an initial increase and then a decrease in the number of carboxyl groups. Under optimal gasification conditions, CO<sub>2</sub> production is reduced by one-fourth compared to using a dolomite catalyst.</p></div>","PeriodicalId":17287,"journal":{"name":"Journal of The Energy Institute","volume":null,"pages":null},"PeriodicalIF":5.6000,"publicationDate":"2024-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Analysis of the effects of Pr1-xCexCoO3/dolomite catalyst on energy saving and carbon reduction in biomass gasification for the production of hydrogen-rich syngas\",\"authors\":\"\",\"doi\":\"10.1016/j.joei.2024.101766\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Biomass is considered a renewable green coal, and its clean and efficient utilization is of great significance for energy conservation and carbon reduction. One of the most critical aspects of biomass gasification is the selection of an appropriate catalyst. In this study, we synthesized a catalyst with 10 % Pr<sub>1-x</sub>Ce<sub>x</sub>CoO<sub>3</sub> supported on dolomite using the sol-gel method. We conducted graded internal circulation gasification experiments to produce hydrogen-rich syngas. The effects of element substitution in PrCoO<sub>3</sub>, temperature, catalyst composition, and steam injection rate on the products were investigated. The optimal gasification conditions were determined through response surface regression analysis. The data indicate that this catalyst can improve gasification efficiency, with Pr<sub>0.4</sub>Ce<sub>0.6</sub>CoO<sub>3</sub>/Dol showing the best catalytic performance. It effectively reduces the required gasification temperature and steam amount, decreases CO<sub>2</sub> production, and increases CO and H<sub>2</sub> yields. The catalyst accelerates the cleavage and ring-opening reactions of hydrocarbons, leading to terminal chain hydroxylation, followed by the dehydration-condensation of methyl groups into ethers. As the temperature rises, the rate of carboxyl group removal gradually exceeds the rate of carboxyl group formation via the oxidation of hydroxyl and ether chains, resulting in an initial increase and then a decrease in the number of carboxyl groups. Under optimal gasification conditions, CO<sub>2</sub> production is reduced by one-fourth compared to using a dolomite catalyst.</p></div>\",\"PeriodicalId\":17287,\"journal\":{\"name\":\"Journal of The Energy Institute\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2024-08-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Energy Institute\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1743967124002447\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Energy Institute","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1743967124002447","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
摘要
生物质被认为是一种可再生的绿色煤炭,其清洁高效的利用对节能减碳具有重要意义。生物质气化最关键的一点是选择合适的催化剂。在本研究中,我们采用溶胶-凝胶法合成了一种在白云石上支撑有 10 % Pr1-xCexCoO3 的催化剂。我们进行了分级内循环气化实验,以产生富氢合成气。研究了 PrCoO3 中的元素替代、温度、催化剂成分和蒸汽喷射速率对产物的影响。通过响应面回归分析确定了最佳气化条件。数据表明,这种催化剂可以提高气化效率,其中 Pr0.4Ce0.6CoO3/Dol 的催化性能最佳。它有效降低了所需的气化温度和蒸汽量,减少了 CO2 的产生,提高了 CO 和 H2 的产量。催化剂可加速碳氢化合物的裂解和开环反应,导致末端链羟基化,然后甲基脱水缩合成醚。随着温度的升高,羧基脱除的速度逐渐超过通过羟基和醚链氧化形成羧基的速度,从而导致羧基数量先增加后减少。在最佳气化条件下,与使用白云石催化剂相比,二氧化碳的产生量减少了四分之一。
Analysis of the effects of Pr1-xCexCoO3/dolomite catalyst on energy saving and carbon reduction in biomass gasification for the production of hydrogen-rich syngas
Biomass is considered a renewable green coal, and its clean and efficient utilization is of great significance for energy conservation and carbon reduction. One of the most critical aspects of biomass gasification is the selection of an appropriate catalyst. In this study, we synthesized a catalyst with 10 % Pr1-xCexCoO3 supported on dolomite using the sol-gel method. We conducted graded internal circulation gasification experiments to produce hydrogen-rich syngas. The effects of element substitution in PrCoO3, temperature, catalyst composition, and steam injection rate on the products were investigated. The optimal gasification conditions were determined through response surface regression analysis. The data indicate that this catalyst can improve gasification efficiency, with Pr0.4Ce0.6CoO3/Dol showing the best catalytic performance. It effectively reduces the required gasification temperature and steam amount, decreases CO2 production, and increases CO and H2 yields. The catalyst accelerates the cleavage and ring-opening reactions of hydrocarbons, leading to terminal chain hydroxylation, followed by the dehydration-condensation of methyl groups into ethers. As the temperature rises, the rate of carboxyl group removal gradually exceeds the rate of carboxyl group formation via the oxidation of hydroxyl and ether chains, resulting in an initial increase and then a decrease in the number of carboxyl groups. Under optimal gasification conditions, CO2 production is reduced by one-fourth compared to using a dolomite catalyst.
期刊介绍:
The Journal of the Energy Institute provides peer reviewed coverage of original high quality research on energy, engineering and technology.The coverage is broad and the main areas of interest include:
Combustion engineering and associated technologies; process heating; power generation; engines and propulsion; emissions and environmental pollution control; clean coal technologies; carbon abatement technologies
Emissions and environmental pollution control; safety and hazards;
Clean coal technologies; carbon abatement technologies, including carbon capture and storage, CCS;
Petroleum engineering and fuel quality, including storage and transport
Alternative energy sources; biomass utilisation and biomass conversion technologies; energy from waste, incineration and recycling
Energy conversion, energy recovery and energy efficiency; space heating, fuel cells, heat pumps and cooling systems
Energy storage
The journal''s coverage reflects changes in energy technology that result from the transition to more efficient energy production and end use together with reduced carbon emission.