实现高性能铝电池的 ZCNC 珠状异质结构。

IF 8.2 2区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY
ACS Applied Materials & Interfaces Pub Date : 2024-08-28 Epub Date: 2024-08-16 DOI:10.1021/acsami.4c09943
Wenbin Luo, Zhen Zhang, Yi Yu, Jian Li, Zisheng Chao, JinCheng Fan
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引用次数: 0

摘要

我们设计并制备了用于铝电池(ABs)的 ZnSe/CoSe2@NC/CNTs (ZCNC) 阴极材料。ZCNC(ZnSe/CoSe2@NC)由交织的碳纳米管(CNT)导电网络连接形成珠状结构。CNT 和有机配体碳化形成的碳有利于提高材料的导电性,减少循环过程中的结构损坏。异质结构界面产生的内部电场可促进电子/离子的转移。这种特殊结构使 ZCNC 具有优异的电化学性能。在 100 mA/g 的条件下,首次放电的比容量达到 338 mAh/g,而循环 500 次后的比容量仍能达到 217 mAh/g。与 ZCN 和 CN(CoSe2@NC)相比,它具有极大的优势。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

ZCNC Beaded Heterostructure toward High-Performance Aluminum Batteries.

ZCNC Beaded Heterostructure toward High-Performance Aluminum Batteries.

We designed and prepared the ZnSe/CoSe2@NC/CNTs (ZCNC) cathode material for aluminum batteries (ABs). The ZCN (ZnSe/CoSe2@NC) is connected by the interwoven carbon nanotube (CNT) conductive network to form a beaded structure. CNTs and the carbon formed by carbonization of organic ligands is beneficial to improving the electrical conductivity of the material and reducing structural damage during cycling. The internal electric field generated at the interface of heterostructures can promote the transfer of electrons/ions. This special structure promotes ZCNC excellent electrochemical properties. At 100 mA/g, the specific capacity of the first discharge reaches 338 mAh/g, while the specific capacity after 500 cycles still reaches 217 mAh/g. Compared with ZCN and CN(CoSe2@NC), it demonstrates a great advantage.

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来源期刊
ACS Applied Materials & Interfaces
ACS Applied Materials & Interfaces 工程技术-材料科学:综合
CiteScore
16.00
自引率
6.30%
发文量
4978
审稿时长
1.8 months
期刊介绍: ACS Applied Materials & Interfaces is a leading interdisciplinary journal that brings together chemists, engineers, physicists, and biologists to explore the development and utilization of newly-discovered materials and interfacial processes for specific applications. Our journal has experienced remarkable growth since its establishment in 2009, both in terms of the number of articles published and the impact of the research showcased. We are proud to foster a truly global community, with the majority of published articles originating from outside the United States, reflecting the rapid growth of applied research worldwide.
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