{"title":"量子等离子工程改善掺杂 Er3+ 的碲玻璃在受控温度下的 1.53 µm 辐射发射","authors":"","doi":"10.1016/j.materresbull.2024.113038","DOIUrl":null,"url":null,"abstract":"<div><p>The plasmonic applications at low temperatures of metallic nanoparticles in glasses doped with rare-earth ions are not yet covered in-depth analysis in the literature. This paper insights into the coupling between gold nanoparticles and Er<sup>3+</sup> embedded in tellurite glasses via luminescence enhancement of the emission centred at 1.53 µm under controlled temperature. This enhancement is obtained for the sample with 24 h of heat treatment (TErAu24) concerning the Er<sup>3+</sup> single doped (TEr) at room temperature under 980 nm excitation. The enhancement remains under cooling conditions, consequence of the strong coupling between the plasmon and the Er<sup>3+</sup>, attributed to an increment of the localized plasmon mode volume at low temperatures. Further, the band area increment of the TErAu24 sample comparing the spectra at 98 and 348 K is 414 %, whereas for the TEr is about 348 %. These findings provide advanced understanding of the plasmonics on quantum emitters engineering.</p></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":null,"pages":null},"PeriodicalIF":5.3000,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Quantum-plasmonic engineering to improve the 1.53 µm radiative emission in Er3+-doped tellurite glasses under controlled temperature\",\"authors\":\"\",\"doi\":\"10.1016/j.materresbull.2024.113038\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The plasmonic applications at low temperatures of metallic nanoparticles in glasses doped with rare-earth ions are not yet covered in-depth analysis in the literature. This paper insights into the coupling between gold nanoparticles and Er<sup>3+</sup> embedded in tellurite glasses via luminescence enhancement of the emission centred at 1.53 µm under controlled temperature. This enhancement is obtained for the sample with 24 h of heat treatment (TErAu24) concerning the Er<sup>3+</sup> single doped (TEr) at room temperature under 980 nm excitation. The enhancement remains under cooling conditions, consequence of the strong coupling between the plasmon and the Er<sup>3+</sup>, attributed to an increment of the localized plasmon mode volume at low temperatures. Further, the band area increment of the TErAu24 sample comparing the spectra at 98 and 348 K is 414 %, whereas for the TEr is about 348 %. These findings provide advanced understanding of the plasmonics on quantum emitters engineering.</p></div>\",\"PeriodicalId\":18265,\"journal\":{\"name\":\"Materials Research Bulletin\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2024-08-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Research Bulletin\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0025540824003696\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Research Bulletin","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0025540824003696","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
文献中尚未对掺杂稀土离子的玻璃中的金属纳米粒子在低温下的等离子体应用进行深入分析。本文通过在受控温度下以 1.53 µm 为中心的发光增强,深入探讨了嵌入碲玻璃中的金纳米粒子与 Er3+ 之间的耦合。经过 24 小时热处理的样品(TErAu24)在室温下 980 纳米激发下的 Er3+ 单掺杂样品(TEr)的发光强度得到了增强。由于等离子体和 Er3+ 之间的强耦合作用,在低温条件下局部等离子体模式体积增大,因此在冷却条件下仍能保持这种增强效果。此外,对比 98 K 和 348 K 时的光谱,TErAu24 样品的带区增量为 414%,而 TEr 样品的带区增量约为 348%。这些发现为量子发射器工程的等离子体学提供了先进的理解。
Quantum-plasmonic engineering to improve the 1.53 µm radiative emission in Er3+-doped tellurite glasses under controlled temperature
The plasmonic applications at low temperatures of metallic nanoparticles in glasses doped with rare-earth ions are not yet covered in-depth analysis in the literature. This paper insights into the coupling between gold nanoparticles and Er3+ embedded in tellurite glasses via luminescence enhancement of the emission centred at 1.53 µm under controlled temperature. This enhancement is obtained for the sample with 24 h of heat treatment (TErAu24) concerning the Er3+ single doped (TEr) at room temperature under 980 nm excitation. The enhancement remains under cooling conditions, consequence of the strong coupling between the plasmon and the Er3+, attributed to an increment of the localized plasmon mode volume at low temperatures. Further, the band area increment of the TErAu24 sample comparing the spectra at 98 and 348 K is 414 %, whereas for the TEr is about 348 %. These findings provide advanced understanding of the plasmonics on quantum emitters engineering.
期刊介绍:
Materials Research Bulletin is an international journal reporting high-impact research on processing-structure-property relationships in functional materials and nanomaterials with interesting electronic, magnetic, optical, thermal, mechanical or catalytic properties. Papers purely on thermodynamics or theoretical calculations (e.g., density functional theory) do not fall within the scope of the journal unless they also demonstrate a clear link to physical properties. Topics covered include functional materials (e.g., dielectrics, pyroelectrics, piezoelectrics, ferroelectrics, relaxors, thermoelectrics, etc.); electrochemistry and solid-state ionics (e.g., photovoltaics, batteries, sensors, and fuel cells); nanomaterials, graphene, and nanocomposites; luminescence and photocatalysis; crystal-structure and defect-structure analysis; novel electronics; non-crystalline solids; flexible electronics; protein-material interactions; and polymeric ion-exchange membranes.