{"title":"基于 MDEA 的二氧化碳吸收和解吸实验","authors":"","doi":"10.1016/j.cep.2024.109931","DOIUrl":null,"url":null,"abstract":"<div><p>The global climate change problem has brought much attention to CO<sub>2</sub> capture technology. N-methyldiethanolamine (MDEA), as an efficient and environmentally friendly absorbent, is widely used in CO<sub>2</sub> capture. However, it is difficult for a single MDEA to meet the demand for efficient absorption and desorption under certain conditions, so the addition of promoters to improve its performance has become a hot research topic. The aim of this study is to deeply investigate the effects of different accelerators on the absorption and desorption of CO<sub>2</sub> by MDEA. Experiments were conducted to measure the absorption capacity of the MDEA compound solution for CO<sub>2</sub> in a bubbling reactor at 30°C and to evaluate its desorption effect in a desorption system at 90°C. The experimental results showed that increasing the promoter concentration in the MDEA-based absorbent solution significantly enhanced the absorption capacity and circulation capacity. However, in terms of desorption efficiency, the added concentrations of MEA and DEA were negatively correlated with the desorption efficiency. Notably, the addition of 0.1 mol/L DEA significantly enhanced the desorption efficiency by 16% compared with MDEA.</p></div>","PeriodicalId":9929,"journal":{"name":"Chemical Engineering and Processing - Process Intensification","volume":null,"pages":null},"PeriodicalIF":3.8000,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Carbon dioxide absorption and desorption experiments based on MDEA\",\"authors\":\"\",\"doi\":\"10.1016/j.cep.2024.109931\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The global climate change problem has brought much attention to CO<sub>2</sub> capture technology. N-methyldiethanolamine (MDEA), as an efficient and environmentally friendly absorbent, is widely used in CO<sub>2</sub> capture. However, it is difficult for a single MDEA to meet the demand for efficient absorption and desorption under certain conditions, so the addition of promoters to improve its performance has become a hot research topic. The aim of this study is to deeply investigate the effects of different accelerators on the absorption and desorption of CO<sub>2</sub> by MDEA. Experiments were conducted to measure the absorption capacity of the MDEA compound solution for CO<sub>2</sub> in a bubbling reactor at 30°C and to evaluate its desorption effect in a desorption system at 90°C. The experimental results showed that increasing the promoter concentration in the MDEA-based absorbent solution significantly enhanced the absorption capacity and circulation capacity. However, in terms of desorption efficiency, the added concentrations of MEA and DEA were negatively correlated with the desorption efficiency. Notably, the addition of 0.1 mol/L DEA significantly enhanced the desorption efficiency by 16% compared with MDEA.</p></div>\",\"PeriodicalId\":9929,\"journal\":{\"name\":\"Chemical Engineering and Processing - Process Intensification\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":3.8000,\"publicationDate\":\"2024-08-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Engineering and Processing - Process Intensification\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0255270124002691\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Engineering and Processing - Process Intensification","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0255270124002691","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
摘要
全球气候变化问题使二氧化碳捕集技术备受关注。N-甲基二乙醇胺(MDEA)作为一种高效、环保的吸收剂,被广泛应用于二氧化碳捕集领域。然而,单一的 MDEA 难以满足特定条件下高效吸收和解吸的需求,因此添加促进剂以提高其性能成为研究热点。本研究旨在深入探讨不同促进剂对 MDEA 吸收和解吸 CO2 的影响。实验在 30°C 的鼓泡反应器中测量了 MDEA 复合物溶液对 CO2 的吸收能力,并在 90°C 的解吸系统中评估了其解吸效果。实验结果表明,增加基于 MDEA 的吸收剂溶液中的促进剂浓度可显著提高吸收能力和循环能力。但在解吸效率方面,MEA 和 DEA 的添加浓度与解吸效率呈负相关。值得注意的是,与 MDEA 相比,添加 0.1 mol/L 的 DEA 可使解吸效率显著提高 16%。
Carbon dioxide absorption and desorption experiments based on MDEA
The global climate change problem has brought much attention to CO2 capture technology. N-methyldiethanolamine (MDEA), as an efficient and environmentally friendly absorbent, is widely used in CO2 capture. However, it is difficult for a single MDEA to meet the demand for efficient absorption and desorption under certain conditions, so the addition of promoters to improve its performance has become a hot research topic. The aim of this study is to deeply investigate the effects of different accelerators on the absorption and desorption of CO2 by MDEA. Experiments were conducted to measure the absorption capacity of the MDEA compound solution for CO2 in a bubbling reactor at 30°C and to evaluate its desorption effect in a desorption system at 90°C. The experimental results showed that increasing the promoter concentration in the MDEA-based absorbent solution significantly enhanced the absorption capacity and circulation capacity. However, in terms of desorption efficiency, the added concentrations of MEA and DEA were negatively correlated with the desorption efficiency. Notably, the addition of 0.1 mol/L DEA significantly enhanced the desorption efficiency by 16% compared with MDEA.
期刊介绍:
Chemical Engineering and Processing: Process Intensification is intended for practicing researchers in industry and academia, working in the field of Process Engineering and related to the subject of Process Intensification.Articles published in the Journal demonstrate how novel discoveries, developments and theories in the field of Process Engineering and in particular Process Intensification may be used for analysis and design of innovative equipment and processing methods with substantially improved sustainability, efficiency and environmental performance.