水溶性希夫碱配体和金属配合物:考虑到绿色溶剂的概述

IF 4.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
RSC Advances Pub Date : 2024-08-13 DOI:10.1039/D4RA04310C
Md. Tariqul Islam, Nur Amin Bitu, Bijan Mohon Chaki, Md. Jakir Hossain, Md. Ali Asraf, Md. Faruk Hossen, Md. Kudrat-E-Zahan and Md. Abdul Latif
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引用次数: 0

摘要

具有希夫碱(SB)配体的水溶性金属配合物因其稳定性、成本效益、生态友好性、电子负载能力和多种应用而备受绿色化学研究人员的关注。它们具有很高的生物活性潜力,包括抗炎、抗癌、抗菌、抗真菌、抗氧化、DNA 结合和裂解等。近年来,过渡金属配合物在工业中的氢化、羰基化、氧化、还原、环氧化、水解、分解和聚合反应等不同过程中发挥了重要作用。然而,它们有限的水溶性可能是限制其潜在催化、工业和临床应用的主要原因。事实证明,在工业催化过程中,水可以用作溶剂,以最大限度地减少不同反应对环境的影响,并实现简单而彻底的分离。水是一种绿色溶剂,灵活、无毒、安全、易于获得、对环境无害且价格低廉。在希夫碱上添加不同的取代基可以提高水溶性和催化活性。对水溶性 SB 复合物的研究将探索这些方面及其未来在不同应用领域的发展前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Water-soluble Schiff base ligands and metal complexes: an overview considering green solvent

Water-soluble Schiff base ligands and metal complexes: an overview considering green solvent

The water-soluble metal complexes with Schiff base (SB) ligands are of great interest to green chemistry researchers due to their stability, cost-effectiveness, eco-friendly, electron-donating ability, and various applications. They have high potential to express their biological activity including anti-inflammatory, anticancer, antibacterial, antifungal, antioxidant, and DNA binding and cleavage. In the recent era, transition metal complexes have played a significant role in different processes such as hydrogenation, carbonylation, oxidation, reduction, epoxidation, hydrolysis, decomposition, and polymerization reactions in industry. However, their limited aqueous solubility may be the major limitation to their potential catalytic, industrial, and clinical applications. In industrial catalytic processes, it has been proven that water can be used as a solvent to minimize the environmental effect of different reactions as well as simple and complete separation. Water is a green solvent, flexible, non-toxic, safe, readily available, environmentally harmless, and inexpensive. Attaching different substituents on Schiff bases enhances the water solubility and catalytic activity. Studies on water-soluble SB complexes will explore these aspects and their prospects for the future evolution of their diverse applications.

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来源期刊
RSC Advances
RSC Advances chemical sciences-
CiteScore
7.50
自引率
2.60%
发文量
3116
审稿时长
1.6 months
期刊介绍: An international, peer-reviewed journal covering all of the chemical sciences, including multidisciplinary and emerging areas. RSC Advances is a gold open access journal allowing researchers free access to research articles, and offering an affordable open access publishing option for authors around the world.
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