微波辅助下苯腈氧化物与 1-碘丁-1,3-二炔的环化反应

IF 1.8 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Mariia M. Efremova , Diana D. Khashimova , Nikita S. Kalinin , Andrey A. Shtyrov , Mikhail N. Ryazantsev , Dar’ya V. Spiridonova , Anastasia I. Govdi , Irina A. Balova
{"title":"微波辅助下苯腈氧化物与 1-碘丁-1,3-二炔的环化反应","authors":"Mariia M. Efremova ,&nbsp;Diana D. Khashimova ,&nbsp;Nikita S. Kalinin ,&nbsp;Andrey A. Shtyrov ,&nbsp;Mikhail N. Ryazantsev ,&nbsp;Dar’ya V. Spiridonova ,&nbsp;Anastasia I. Govdi ,&nbsp;Irina A. Balova","doi":"10.1016/j.mencom.2024.06.022","DOIUrl":null,"url":null,"abstract":"<div><p>The microwave-assisted cycloaddition of 2,6-disubstituted benzonitrile oxides to 1-iodobuta-1,3-diynes occurs at the iodo-substituted triple bond giving predominantly 5-alkynyl-4-iodo-1,2,3-isoxazoles. The Suzuki–Miyaura and Sonogashira cross-coupling reactions were used for the modification of the thus obtained 4-iodoisoxazoles.</p></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":"34 4","pages":"Pages 536-539"},"PeriodicalIF":1.8000,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Microwave assisted cycloaddition of benzonitrile oxides to 1-iodobuta-1,3-diynes\",\"authors\":\"Mariia M. Efremova ,&nbsp;Diana D. Khashimova ,&nbsp;Nikita S. Kalinin ,&nbsp;Andrey A. Shtyrov ,&nbsp;Mikhail N. Ryazantsev ,&nbsp;Dar’ya V. Spiridonova ,&nbsp;Anastasia I. Govdi ,&nbsp;Irina A. Balova\",\"doi\":\"10.1016/j.mencom.2024.06.022\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The microwave-assisted cycloaddition of 2,6-disubstituted benzonitrile oxides to 1-iodobuta-1,3-diynes occurs at the iodo-substituted triple bond giving predominantly 5-alkynyl-4-iodo-1,2,3-isoxazoles. The Suzuki–Miyaura and Sonogashira cross-coupling reactions were used for the modification of the thus obtained 4-iodoisoxazoles.</p></div>\",\"PeriodicalId\":18542,\"journal\":{\"name\":\"Mendeleev Communications\",\"volume\":\"34 4\",\"pages\":\"Pages 536-539\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Mendeleev Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0959943624001998\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Mendeleev Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0959943624001998","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

在微波辅助下,2,6-二取代的苯甲腈氧化物与 1-碘-1,3-二炔在碘取代的三键上发生环化反应,主要得到 5-炔基-4-碘-1,2,3-异噁唑。在对由此获得的 4-碘异噁唑进行改性时,使用了铃木-宫浦(Suzuki-Miyaura)和园柄(Sonogashira)交叉偶联反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Microwave assisted cycloaddition of benzonitrile oxides to 1-iodobuta-1,3-diynes

Microwave assisted cycloaddition of benzonitrile oxides to 1-iodobuta-1,3-diynes

The microwave-assisted cycloaddition of 2,6-disubstituted benzonitrile oxides to 1-iodobuta-1,3-diynes occurs at the iodo-substituted triple bond giving predominantly 5-alkynyl-4-iodo-1,2,3-isoxazoles. The Suzuki–Miyaura and Sonogashira cross-coupling reactions were used for the modification of the thus obtained 4-iodoisoxazoles.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Mendeleev Communications
Mendeleev Communications 化学-化学综合
CiteScore
3.00
自引率
21.10%
发文量
226
审稿时长
4-8 weeks
期刊介绍: Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications. Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信