{"title":"正极颗粒涂层均匀性对锂离子电池性能的影响","authors":"Tomoya Ohno, Jeevan Kumar Padarti, Shigeto Hirai, Takeshi Matsuda","doi":"10.1016/j.apt.2024.104608","DOIUrl":null,"url":null,"abstract":"<div><p>Ensuring the stability of cathodes under high voltage (>4.3 V vs. Li/Li + ) necessitates particle-scale surface protection. Research varies on the optimal structure, and systematic studies on the impact of nanoscale coating coverage on cathode particle surfaces and stability are lacking. This study presents a quantitative analysis of coating homogeneity dependency on cathode particles and their stability under high voltage conditions. A metal alkoxide precursor-based coating methodology was used, manipulating the coating structure by understanding the pH dependence of the zeta potential for core particles and altering the precursor evaporation rate. Ta-substituted Li<sub>7</sub>La<sub>3</sub>Zr<sub>2</sub>O<sub>12</sub> was chosen as the coating material on Li(Ni<sub>1/3</sub>,Co<sub>1/3</sub>,Mn<sub>1/3</sub>)O<sub>2</sub> cathode particles, varying the coating structure while maintaining the same coating concentration. Coating structure was verified using X-ray fluorescence (XRF), X-ray photoelectron spectroscopy (XPS), and electrochemical impedance spectroscopy (EIS). Results showed that cathode particles with more homogeneous coatings exhibited significantly improved cycle stability and lower charge transfer resistance at potentials above 3.9 V. Optimizing coating homogeneity can significantly enhance battery performance, offering insights for more efficient lithium-ion batteries.</p></div>","PeriodicalId":7232,"journal":{"name":"Advanced Powder Technology","volume":"35 9","pages":"Article 104608"},"PeriodicalIF":4.2000,"publicationDate":"2024-08-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S092188312400284X/pdfft?md5=bb4a69ae9e8b1e6e345539168199dd7b&pid=1-s2.0-S092188312400284X-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Effects of coating layer homogeneity of cathode particles on lithium ion battery performance\",\"authors\":\"Tomoya Ohno, Jeevan Kumar Padarti, Shigeto Hirai, Takeshi Matsuda\",\"doi\":\"10.1016/j.apt.2024.104608\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Ensuring the stability of cathodes under high voltage (>4.3 V vs. Li/Li + ) necessitates particle-scale surface protection. Research varies on the optimal structure, and systematic studies on the impact of nanoscale coating coverage on cathode particle surfaces and stability are lacking. This study presents a quantitative analysis of coating homogeneity dependency on cathode particles and their stability under high voltage conditions. A metal alkoxide precursor-based coating methodology was used, manipulating the coating structure by understanding the pH dependence of the zeta potential for core particles and altering the precursor evaporation rate. Ta-substituted Li<sub>7</sub>La<sub>3</sub>Zr<sub>2</sub>O<sub>12</sub> was chosen as the coating material on Li(Ni<sub>1/3</sub>,Co<sub>1/3</sub>,Mn<sub>1/3</sub>)O<sub>2</sub> cathode particles, varying the coating structure while maintaining the same coating concentration. Coating structure was verified using X-ray fluorescence (XRF), X-ray photoelectron spectroscopy (XPS), and electrochemical impedance spectroscopy (EIS). 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引用次数: 0
摘要
要确保阴极在高电压(4.3 V vs. Li/Li +)下的稳定性,就必须对颗粒表面进行保护。有关最佳结构的研究各不相同,而有关纳米级涂层覆盖率对阴极颗粒表面和稳定性影响的系统性研究则十分缺乏。本研究定量分析了涂层均匀性对阴极颗粒的依赖性及其在高压条件下的稳定性。研究采用了一种基于金属氧化物前驱体的镀膜方法,通过了解核心颗粒 zeta 电位的 pH 依赖性和改变前驱体蒸发速率来操纵镀膜结构。选择 Ta 取代的 Li7La3Zr2O12 作为 Li(Ni1/3,Co1/3,Mn1/3)O2 阴极粒子的涂层材料,在保持相同涂层浓度的情况下改变涂层结构。使用 X 射线荧光 (XRF)、X 射线光电子能谱 (XPS) 和电化学阻抗能谱 (EIS) 验证了涂层结构。结果表明,涂层更均匀的正极颗粒在电位高于 3.9 V 时的循环稳定性明显提高,电荷转移电阻更低。
Effects of coating layer homogeneity of cathode particles on lithium ion battery performance
Ensuring the stability of cathodes under high voltage (>4.3 V vs. Li/Li + ) necessitates particle-scale surface protection. Research varies on the optimal structure, and systematic studies on the impact of nanoscale coating coverage on cathode particle surfaces and stability are lacking. This study presents a quantitative analysis of coating homogeneity dependency on cathode particles and their stability under high voltage conditions. A metal alkoxide precursor-based coating methodology was used, manipulating the coating structure by understanding the pH dependence of the zeta potential for core particles and altering the precursor evaporation rate. Ta-substituted Li7La3Zr2O12 was chosen as the coating material on Li(Ni1/3,Co1/3,Mn1/3)O2 cathode particles, varying the coating structure while maintaining the same coating concentration. Coating structure was verified using X-ray fluorescence (XRF), X-ray photoelectron spectroscopy (XPS), and electrochemical impedance spectroscopy (EIS). Results showed that cathode particles with more homogeneous coatings exhibited significantly improved cycle stability and lower charge transfer resistance at potentials above 3.9 V. Optimizing coating homogeneity can significantly enhance battery performance, offering insights for more efficient lithium-ion batteries.
期刊介绍:
The aim of Advanced Powder Technology is to meet the demand for an international journal that integrates all aspects of science and technology research on powder and particulate materials. The journal fulfills this purpose by publishing original research papers, rapid communications, reviews, and translated articles by prominent researchers worldwide.
The editorial work of Advanced Powder Technology, which was founded as the International Journal of the Society of Powder Technology, Japan, is now shared by distinguished board members, who operate in a unique framework designed to respond to the increasing global demand for articles on not only powder and particles, but also on various materials produced from them.
Advanced Powder Technology covers various areas, but a discussion of powder and particles is required in articles. Topics include: Production of powder and particulate materials in gases and liquids(nanoparticles, fine ceramics, pharmaceuticals, novel functional materials, etc.); Aerosol and colloidal processing; Powder and particle characterization; Dynamics and phenomena; Calculation and simulation (CFD, DEM, Monte Carlo method, population balance, etc.); Measurement and control of powder processes; Particle modification; Comminution; Powder handling and operations (storage, transport, granulation, separation, fluidization, etc.)