NPh3 介导的 WO3 光催化芳基和烷基硼酸半异构羟基化反应

IF 3.6 2区化学 Q1 CHEMISTRY, ORGANIC

Journal of Organic Chemistry Pub Date : 2024-07-17 DOI:10.1021/acs.joc.4c0088510.1021/acs.joc.4c00885

Xiao-Jun Huang, Hong-Tao Ji, Xiao Li, Qing-Xia Luo, Ting Li, Li-Juan Ou* and Wei-Min He*,

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引用次数: 0

摘要

以价格低廉、市场上可买到的 WO3 半导体作为异相光催化剂，以催化量的 NPh3 作为单电子供体，以环境空气作为单电子受体和氧源，开发了烷基和芳基硼酸的半异相光催化羟基化反应。该方法能以极佳的产率获得多种羟基化合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

NPh3-Mediated WO3-Photocatalyzed Semiheterogeneous Hydroxylation of Aryl and Alkyl Boronic Acids

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NPh3-Mediated WO3-Photocatalyzed Semiheterogeneous Hydroxylation of Aryl and Alkyl Boronic Acids

With an inexpensive and commercially available WO₃ semiconductor as the heterogeneous photocatalyst, a catalytic amount of NPh₃ as the single-electron donor, and ambient air as the single-electron acceptor and oxygen source, the semiheterogeneous photocatalytic hydroxylation of alkyl and aryl boronic acids was developed. A broad range of hydroxylated compounds can be obtained in excellent yields.

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来源期刊

Journal of Organic Chemistry 化学-有机化学

CiteScore

6.20

自引率

11.10%

发文量

1467

审稿时长

2 months

期刊介绍： Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.