用于绿色合成氨生产的新兴电催化剂:最新进展和未来展望

IF 5.3 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Sajid Mahmood , Shahid Iqbal , Zeping Wang , Muhammad Ammar , Muhammad Javed Iqbal , Ali Bahadur , Nasser S. Awwad , Hala A. Ibrahium
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引用次数: 0

摘要

哈伯-博世工艺(HBp)利用升高的压力和温度产生浓度更高的氮气和氢气,2016 年全球产生的 1.75 亿吨 NH3 中,有 90% 是通过该工艺生产的。根据可持续合成氨生产路线图,用水作为还原剂是近距离环境固氮的最有效方法。本文对电催化还原氮的理论和实践工作进行了全面阐述,并特别关注了氮还原成氨与质子还原成氢相比选择性较低的问题。由于它们对准确实现高产氮和法拉第效率(FE)至关重要,因此其信息概述了电催化剂、电解质选择标准和管理实验设计。在不同条件下,对理论和实验的演变进行了研究。最后,对这一领域目前存在的问题和前景进行了反馈。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Emerging electrocatalysts for green ammonia production: Recent progress and future outlook

In the Haber-Bosch process (HBp), which uses elevated pressure and temperature to produce more concentration of nitrogen and hydrogen gases, 90% of the 175 million metric tons of NH3 generated worldwide in 2016 were manufactured in this process. According to the road plan for sustainable ammonia production sustainably, using water as a reducing agent is the most effective way to fix nitrogen in close-quarters ambiance. A complete explanation of theoretical and practical work on electrocatalytic nitrogen reduction is provided in this article, with special attention paid to the low selectivity of nitrogen reduction to ammonia in comparison to protons to hydrogen. Since they are essential for accurately achieving high nitrogen production and Faradaic efficiency (FE), their information outlines electrocatalysts, electrolyte selection criteria, and managed experiment design. Under diverse conditions, the evolution of theory and experiment is examined. Finally, feedback is given on this field’s present issues and prospects.

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来源期刊
Arabian Journal of Chemistry
Arabian Journal of Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
10.80
自引率
3.30%
发文量
763
审稿时长
63 days
期刊介绍: The Arabian Journal of Chemistry is an English language, peer-reviewed scholarly publication in the area of chemistry. The Arabian Journal of Chemistry publishes original papers, reviews and short reports on, but not limited to: inorganic, physical, organic, analytical and biochemistry. The Arabian Journal of Chemistry is issued by the Arab Union of Chemists and is published by King Saud University together with the Saudi Chemical Society in collaboration with Elsevier and is edited by an international group of eminent researchers.
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