己二腈与二苯基锆烯的环化反应

IF 1.8 4区化学 Q3 CHEMISTRY, MULTIDISCIPLINARY

Mendeleev Communications Pub Date : 2024-07-01 DOI:10.1016/j.mencom.2024.06.026

Maxim V. Andreev , Iuliia A. Akishkina , Vyacheslav S. Bogdanov , Alexander F. Smol’yakov , Vladimir V. Burlakov

引用次数: 0

摘要

发现己二腈分子内环化，在锆配位球中形成一个脒基官能团。得到的复合物可在二噁烷中用盐酸进行原解，得到一种新的脒类化合物代表，即盐酸盐形式的 7-苯基-1,3,4,5-四氢-2H-氮杂卓-2-亚胺。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Cyclization of adiponitrile in the reaction with diphenylzirconocene

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Cyclization of adiponitrile in the reaction with diphenylzirconocene

Intramolecular cyclization of adiponitrile with the formation of an amidinate functional group in zirconium coordination sphere was found. The obtained complex can be protolyzed with HCl in dioxane to afford a new representative of amidines, namely, 7-phenyl-1,3,4,5-tetrahydro-2H-azepin-2- imine in hydrochloride form.

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来源期刊

Mendeleev Communications 化学-化学综合

CiteScore

3.00

自引率

21.10%

发文量

226

审稿时长

4-8 weeks

期刊介绍： Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications. Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.