I. Yu. Perevyazko, P. A. Fetin, I. M. Zorin, A. A. Lezov, A. A. Lezova, N. G. Mikusheva, K. V. Deriabin, R. M. Islamova, N. V. Tsvetkov
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Ferrocene-Containing Polymethacrylates: Synthesis, Molecular Characteristics, and Its Nanoparticles
In this work, a series of samples of a homopolymer of polyferrocenoylethylmethacrylate containing ferrocene groups in side chains is synthesized for the first time using the RAFT polymerization method and comprehensively studied. A homologous series of polymers differing in molar mass is obtained in a range sufficient for conformational analysis. The main hydrodynamic characteristics of polymers (intrinsic viscosity, sedimentation, and translational diffusion coefficients) are studied, and the most probable conformation of polymers in a solution as well as the main conformational parameters (thermodynamic rigidity and polymer-chain diameter) are determined. Also, suspensions of nanoparticles are prepared on the basis of the studied polymers by the method of nanoprecipitation. The sizes of the obtained particles are analyzed both on substrates and in suspensions.
期刊介绍：
Nanobiotechnology Reports publishes interdisciplinary research articles on fundamental aspects of the structure and properties of nanoscale objects and nanomaterials, polymeric and bioorganic molecules, and supramolecular and biohybrid complexes, as well as articles that discuss technologies for their preparation and processing, and practical implementation of products, devices, and nature-like systems based on them. The journal publishes original articles and reviews that meet the highest scientific quality standards in the following areas of science and technology studies: self-organizing structures and nanoassemblies; nanostructures, including nanotubes; functional and structural nanomaterials; polymeric, bioorganic, and hybrid nanomaterials; devices and products based on nanomaterials and nanotechnology; nanobiology and genetics, and omics technologies; nanobiomedicine and nanopharmaceutics; nanoelectronics and neuromorphic computing systems; neurocognitive systems and technologies; nanophotonics; natural science methods in a study of cultural heritage items; metrology, standardization, and monitoring in nanotechnology.
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