基于用碱性哈洛石纳米管增强的聚丁二酸丁二醇酯薄膜的活性包装膜:生产、性能和水果包装应用

IF 5.3 2区 地球科学 Q2 CHEMISTRY, PHYSICAL
Bedriye Ucpinar Durmaz , Filiz Ugur Nigiz , Ayse Aytac
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引用次数: 0

摘要

采用熔融混合和溶剂浇注技术将经碱性处理的哈洛石纳米管(aHal)引入聚丁二酸丁二醇酯(PBS)基质中,以增强其功能特性。对薄膜的形态、热、机械、抗菌、阻隔和乙烯清除性能进行了表征,以用于新鲜食品包装。由于 aHal 的内腔直径增大,薄膜具有乙烯清除性能。在两种生产方法中,乙烯清除性能最高的是 5 wt% 的 aHal(5-aHal)负载量。在挤压和溶剂浇铸 5-aHal 的情况下,气密容器中的乙烯量分别减少了 80% 和 75%。虽然 PBS/aHal 薄膜的机械性能与推荐用于食品包装的其他薄膜相当,但挤压薄膜比溶剂浇铸薄膜更具柔韧性和耐久性。此外,还发现挤压薄膜的水蒸气阻隔性更高。还对在室温条件下存放 7 天的番茄片和苹果片进行了包装测试。5-aHal 薄膜在延长水果保质期方面表现最佳。从所有结果来看,熔融混合薄膜的性能更优越。生物基 PBS/aHal 薄膜作为生态友好型活性食品包装材料,能够极大地促进食品安全。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Active packaging films based on poly(butylene succinate) films reinforced with alkaline halloysite nanotubes: Production, properties, and fruit packaging applications

Alkaline treated halloysite nanotubes (aHal) were introduced into poly(butylene succinate) (PBS) matrix using melt blending and solvent casting techniques to enhance the functional properties. The films were characterized for morphological, thermal, mechanical, antibacterial, barrier, and ethylene scavenging properties for their fresh food packaging use. The films exhibited ethylene scavenging performance because of the increased lumen diameter of aHal. The highest ethylene scavenging performance was achieved at 5 wt% aHal (5-aHal) loading for both production methods. The amount of ethylene in the gas-tight container decreased by 80% and 75% in the presence of extruded and solvent-cast 5-aHal, respectively. While PBS/aHal films have mechanical properties comparable to other films recommended for food packaging, extruded films were more flexible and durable than solvent-cast films. In addition, extruded films were found to have a higher water vapor barrier. A packaging test has also been carried out on sliced tomatoes and apples stored at room conditions for 7 days. 5-aHal films showed the best performance in extending the fruit's shelf life. Considering all the results, the melt blending films offer superior performance. Bio-based PBS/aHal films have the capability to contribute significantly to the food safety by serving as eco-friendly, active food packaging materials.

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来源期刊
Applied Clay Science
Applied Clay Science 地学-矿物学
CiteScore
10.30
自引率
10.70%
发文量
289
审稿时长
39 days
期刊介绍: Applied Clay Science aims to be an international journal attracting high quality scientific papers on clays and clay minerals, including research papers, reviews, and technical notes. The journal covers typical subjects of Fundamental and Applied Clay Science such as: • Synthesis and purification • Structural, crystallographic and mineralogical properties of clays and clay minerals • Thermal properties of clays and clay minerals • Physico-chemical properties including i) surface and interface properties; ii) thermodynamic properties; iii) mechanical properties • Interaction with water, with polar and apolar molecules • Colloidal properties and rheology • Adsorption, Intercalation, Ionic exchange • Genesis and deposits of clay minerals • Geology and geochemistry of clays • Modification of clays and clay minerals properties by thermal and physical treatments • Modification by chemical treatments with organic and inorganic molecules(organoclays, pillared clays) • Modification by biological microorganisms. etc...
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