{"title":"轻松构建二维/二维 BiOCl/NiAl-LDHs S 型异质结,实现高效光催化染料和抗生素降解","authors":"Weiwei Wang , Jialiang Yao","doi":"10.1016/j.clay.2024.107519","DOIUrl":null,"url":null,"abstract":"<div><p>2D/2D van der Waals heterojunctions have been proved to be a feasible strategy to enhance photocatalytic activity. In this work, two-dimensional (2D) BiOCl and layered double hydroxides (NiAl-LDHs) were composited using a simple mechanical mixing method at room temperature. The 2D/2D BiOCl/NiAl-LDHs S-scheme heterojunctions with a sheet-on-sheet interface contact were formed. The effects of interface contact and band structure between BiOCl and NiAl-LDHs on the photocatalytic properties were investigated. Experimental results showed that the reaction rate constants of BiOCl/NiAl-LDHs S-scheme heterojunctions for the degradation of methyl orange, methylene blue and levofoxacin were 13, 59 and 3 times of BiOCl and 141, 83 and 27 times of NiAl-LDHs, respectively. BiOCl/NiAl-LDHs heterojunctions displayed good stability and regeneration capacity. After four times of recycling, the degradation rates were more than 97 % for methyl orange and methylene blue, and 94.5 % for levofoxacin. The enhancement in photocatalytic activity was attributed to the formation of S-scheme van der Waals heterojunctions with sheet-on-sheet contact, which provided a short charge transfer distance and enabled rapid charge separation at the interface. The formation of S-scheme heterojunctions was confirmed by X-ray photoelectron spectroscopy, experimental calculations and radical trapping experiments. Using the same method, BiOX(X = Br and I)/NiAl-LDHs composites with sheet-on-sheet contact were also obtained. This work could provide valuable reference for constructing 2D/2D van der Waals heterojunctions.</p></div>","PeriodicalId":245,"journal":{"name":"Applied Clay Science","volume":"260 ","pages":"Article 107519"},"PeriodicalIF":5.3000,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Facile construction of 2D/2D BiOCl/NiAl-LDHs S-scheme heterojunctions for efficient photocatalytic dye and antibiotic degradation\",\"authors\":\"Weiwei Wang , Jialiang Yao\",\"doi\":\"10.1016/j.clay.2024.107519\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>2D/2D van der Waals heterojunctions have been proved to be a feasible strategy to enhance photocatalytic activity. In this work, two-dimensional (2D) BiOCl and layered double hydroxides (NiAl-LDHs) were composited using a simple mechanical mixing method at room temperature. The 2D/2D BiOCl/NiAl-LDHs S-scheme heterojunctions with a sheet-on-sheet interface contact were formed. The effects of interface contact and band structure between BiOCl and NiAl-LDHs on the photocatalytic properties were investigated. Experimental results showed that the reaction rate constants of BiOCl/NiAl-LDHs S-scheme heterojunctions for the degradation of methyl orange, methylene blue and levofoxacin were 13, 59 and 3 times of BiOCl and 141, 83 and 27 times of NiAl-LDHs, respectively. BiOCl/NiAl-LDHs heterojunctions displayed good stability and regeneration capacity. After four times of recycling, the degradation rates were more than 97 % for methyl orange and methylene blue, and 94.5 % for levofoxacin. The enhancement in photocatalytic activity was attributed to the formation of S-scheme van der Waals heterojunctions with sheet-on-sheet contact, which provided a short charge transfer distance and enabled rapid charge separation at the interface. The formation of S-scheme heterojunctions was confirmed by X-ray photoelectron spectroscopy, experimental calculations and radical trapping experiments. Using the same method, BiOX(X = Br and I)/NiAl-LDHs composites with sheet-on-sheet contact were also obtained. This work could provide valuable reference for constructing 2D/2D van der Waals heterojunctions.</p></div>\",\"PeriodicalId\":245,\"journal\":{\"name\":\"Applied Clay Science\",\"volume\":\"260 \",\"pages\":\"Article 107519\"},\"PeriodicalIF\":5.3000,\"publicationDate\":\"2024-08-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Applied Clay Science\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0169131724002679\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Clay Science","FirstCategoryId":"89","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0169131724002679","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0
摘要
二维/二维范德华异质结已被证明是提高光催化活性的可行策略。本研究采用简单的机械混合方法,在室温下将二维(2D)BiOCl 和层状双氢氧化物(NiAl-LDHs)复合在一起。形成了具有片对片界面接触的二维/二维 BiOCl/NiAl-LDHs S 型异质结。研究了界面接触和 BiOCl 与 NiAl-LDHs 之间的能带结构对光催化性能的影响。实验结果表明,BiOCl/NiAl-LDHs S 型异质结降解甲基橙、亚甲基蓝和左氧氟沙星的反应速率常数分别是 BiOCl 的 13 倍、59 倍和 3 倍,NiAl-LDHs 的 141 倍、83 倍和 27 倍。BiOCl/NiAl-LDHs 异质结显示出良好的稳定性和再生能力。经过四次循环后,甲基橙和亚甲蓝的降解率超过 97%,左氧氟沙星的降解率为 94.5%。光催化活性的提高归功于片对片接触形成的 S 型范德华异质结,它提供了较短的电荷转移距离,使电荷能够在界面上快速分离。X 射线光电子能谱、实验计算和自由基捕获实验证实了 S 型异质结的形成。使用相同的方法,还获得了具有片上接触的 BiOX(X = Br 和 I)/NiAl-LDHs 复合材料。这项工作可为构建二维/二维范德华异质结提供有价值的参考。
Facile construction of 2D/2D BiOCl/NiAl-LDHs S-scheme heterojunctions for efficient photocatalytic dye and antibiotic degradation
2D/2D van der Waals heterojunctions have been proved to be a feasible strategy to enhance photocatalytic activity. In this work, two-dimensional (2D) BiOCl and layered double hydroxides (NiAl-LDHs) were composited using a simple mechanical mixing method at room temperature. The 2D/2D BiOCl/NiAl-LDHs S-scheme heterojunctions with a sheet-on-sheet interface contact were formed. The effects of interface contact and band structure between BiOCl and NiAl-LDHs on the photocatalytic properties were investigated. Experimental results showed that the reaction rate constants of BiOCl/NiAl-LDHs S-scheme heterojunctions for the degradation of methyl orange, methylene blue and levofoxacin were 13, 59 and 3 times of BiOCl and 141, 83 and 27 times of NiAl-LDHs, respectively. BiOCl/NiAl-LDHs heterojunctions displayed good stability and regeneration capacity. After four times of recycling, the degradation rates were more than 97 % for methyl orange and methylene blue, and 94.5 % for levofoxacin. The enhancement in photocatalytic activity was attributed to the formation of S-scheme van der Waals heterojunctions with sheet-on-sheet contact, which provided a short charge transfer distance and enabled rapid charge separation at the interface. The formation of S-scheme heterojunctions was confirmed by X-ray photoelectron spectroscopy, experimental calculations and radical trapping experiments. Using the same method, BiOX(X = Br and I)/NiAl-LDHs composites with sheet-on-sheet contact were also obtained. This work could provide valuable reference for constructing 2D/2D van der Waals heterojunctions.
期刊介绍:
Applied Clay Science aims to be an international journal attracting high quality scientific papers on clays and clay minerals, including research papers, reviews, and technical notes. The journal covers typical subjects of Fundamental and Applied Clay Science such as:
• Synthesis and purification
• Structural, crystallographic and mineralogical properties of clays and clay minerals
• Thermal properties of clays and clay minerals
• Physico-chemical properties including i) surface and interface properties; ii) thermodynamic properties; iii) mechanical properties
• Interaction with water, with polar and apolar molecules
• Colloidal properties and rheology
• Adsorption, Intercalation, Ionic exchange
• Genesis and deposits of clay minerals
• Geology and geochemistry of clays
• Modification of clays and clay minerals properties by thermal and physical treatments
• Modification by chemical treatments with organic and inorganic molecules(organoclays, pillared clays)
• Modification by biological microorganisms. etc...