Yu-Chieh Ho , Heejun Suk , Ching-Ping Liang , Chen-Wuing Liu , Thu-Uyen Nguyen , Jui-Sheng Chen
{"title":"溶解相和吸附相同时耦合的非平衡多物种衰变污染物迁移的递归分析法","authors":"Yu-Chieh Ho , Heejun Suk , Ching-Ping Liang , Chen-Wuing Liu , Thu-Uyen Nguyen , Jui-Sheng Chen","doi":"10.1016/j.advwatres.2024.104777","DOIUrl":null,"url":null,"abstract":"<div><p>Multispecies transport analytical models that solve advection-dispersion equations (ADEs) are efficient tools for evaluating the transport of decaying contaminants and their sequential products. This study develops a novel semi-analytical model to simulate the multispecies transport of decaying contaminants, considering nonequilibrium sorption and decay in both dissolved and sorbed phases. First-order reversible kinetic sorption equations with decay processes are coupled to ADEs. Recursive analytical solutions, using the Laplace transform and generalized integral transform, are developed to address the mathematical complexity of the governing equations. The model's simulation results show excellent agreement with both numerical models and existing analytical solutions. Applied to a four-member radionuclide decay chain, the model reveals that including decay in the sorbed phase results in a lower concentration of the first member and avoids underestimating the radioactivity concentrations of daughter elements. These differences in dissolved radioactivity concentrations between models with and without sorbed phase decay may impact health risk assessments for radioactive waste disposal. Finally, this study provides a more sophisticated mathematical tool for analyzing multispecies transport in real field conditions where nonequilibrium sorption processes predominantly occur.</p></div>","PeriodicalId":7614,"journal":{"name":"Advances in Water Resources","volume":"192 ","pages":"Article 104777"},"PeriodicalIF":4.0000,"publicationDate":"2024-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Recursive analytical solution for nonequilibrium multispecies transport of decaying contaminant simultaneously coupled in both the dissolved and sorbed phases\",\"authors\":\"Yu-Chieh Ho , Heejun Suk , Ching-Ping Liang , Chen-Wuing Liu , Thu-Uyen Nguyen , Jui-Sheng Chen\",\"doi\":\"10.1016/j.advwatres.2024.104777\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Multispecies transport analytical models that solve advection-dispersion equations (ADEs) are efficient tools for evaluating the transport of decaying contaminants and their sequential products. This study develops a novel semi-analytical model to simulate the multispecies transport of decaying contaminants, considering nonequilibrium sorption and decay in both dissolved and sorbed phases. First-order reversible kinetic sorption equations with decay processes are coupled to ADEs. Recursive analytical solutions, using the Laplace transform and generalized integral transform, are developed to address the mathematical complexity of the governing equations. The model's simulation results show excellent agreement with both numerical models and existing analytical solutions. Applied to a four-member radionuclide decay chain, the model reveals that including decay in the sorbed phase results in a lower concentration of the first member and avoids underestimating the radioactivity concentrations of daughter elements. These differences in dissolved radioactivity concentrations between models with and without sorbed phase decay may impact health risk assessments for radioactive waste disposal. Finally, this study provides a more sophisticated mathematical tool for analyzing multispecies transport in real field conditions where nonequilibrium sorption processes predominantly occur.</p></div>\",\"PeriodicalId\":7614,\"journal\":{\"name\":\"Advances in Water Resources\",\"volume\":\"192 \",\"pages\":\"Article 104777\"},\"PeriodicalIF\":4.0000,\"publicationDate\":\"2024-07-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advances in Water Resources\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0309170824001647\",\"RegionNum\":2,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"WATER RESOURCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advances in Water Resources","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0309170824001647","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"WATER RESOURCES","Score":null,"Total":0}
Recursive analytical solution for nonequilibrium multispecies transport of decaying contaminant simultaneously coupled in both the dissolved and sorbed phases
Multispecies transport analytical models that solve advection-dispersion equations (ADEs) are efficient tools for evaluating the transport of decaying contaminants and their sequential products. This study develops a novel semi-analytical model to simulate the multispecies transport of decaying contaminants, considering nonequilibrium sorption and decay in both dissolved and sorbed phases. First-order reversible kinetic sorption equations with decay processes are coupled to ADEs. Recursive analytical solutions, using the Laplace transform and generalized integral transform, are developed to address the mathematical complexity of the governing equations. The model's simulation results show excellent agreement with both numerical models and existing analytical solutions. Applied to a four-member radionuclide decay chain, the model reveals that including decay in the sorbed phase results in a lower concentration of the first member and avoids underestimating the radioactivity concentrations of daughter elements. These differences in dissolved radioactivity concentrations between models with and without sorbed phase decay may impact health risk assessments for radioactive waste disposal. Finally, this study provides a more sophisticated mathematical tool for analyzing multispecies transport in real field conditions where nonequilibrium sorption processes predominantly occur.
期刊介绍:
Advances in Water Resources provides a forum for the presentation of fundamental scientific advances in the understanding of water resources systems. The scope of Advances in Water Resources includes any combination of theoretical, computational, and experimental approaches used to advance fundamental understanding of surface or subsurface water resources systems or the interaction of these systems with the atmosphere, geosphere, biosphere, and human societies. Manuscripts involving case studies that do not attempt to reach broader conclusions, research on engineering design, applied hydraulics, or water quality and treatment, as well as applications of existing knowledge that do not advance fundamental understanding of hydrological processes, are not appropriate for Advances in Water Resources.
Examples of appropriate topical areas that will be considered include the following:
• Surface and subsurface hydrology
• Hydrometeorology
• Environmental fluid dynamics
• Ecohydrology and ecohydrodynamics
• Multiphase transport phenomena in porous media
• Fluid flow and species transport and reaction processes