Bryan Gross, Guy Schlatter, Pascal Hébraud, Flavien Mouillard, Lotfi Chehma, Anne Hébraud, Emeline Lobry
{"title":"水中高浓度聚氨酯悬浮液的绿色电纺丝:从流变学到纤维形态学","authors":"Bryan Gross, Guy Schlatter, Pascal Hébraud, Flavien Mouillard, Lotfi Chehma, Anne Hébraud, Emeline Lobry","doi":"10.1002/mame.202400157","DOIUrl":null,"url":null,"abstract":"<p>Suspension electrospinning allows the environmental-friendly fabrication of nano-micro-fibrous membranes since it is based on the processing of an aqueous particle suspension in which a hydrosoluble template polymer is added to insure the formation of a continuous fiber. Here, the case of polyurethane (PU) aqueous suspensions formulated with poly(ethylene oxide) (PEO) as the template polymer is studied. The effect of several parameters (particle size, PU/PEO ratio, PEO molar mass, and PEO concentration in the continuous phase) on particle-particle and particle-template polymer interactions that influence the rheological properties of the formulation and finally the electrospinning and the fiber morphology, is studied. The goal is to process a formulation with the highest particle content as possible. Thanks to a deep rheological investigation and the study of interactions and suspension morphology by zeta potential and diffusing wave spectroscopy, it is shown that regular fibers are efficiently produced when small particles are electrospun under favorable particle-template polymer interactions and without screening the electrostatic repulsion between particles. Finally, a fibrous membrane is obtained from a formulation with a PU/PEO weight ratio equal to 50 under very stable and efficient production conditions.</p>","PeriodicalId":18151,"journal":{"name":"Macromolecular Materials and Engineering","volume":"309 12","pages":""},"PeriodicalIF":4.2000,"publicationDate":"2024-08-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/mame.202400157","citationCount":"0","resultStr":"{\"title\":\"Green Electrospinning of Highly Concentrated Polyurethane Suspensions in Water: From the Rheology to the Fiber Morphology\",\"authors\":\"Bryan Gross, Guy Schlatter, Pascal Hébraud, Flavien Mouillard, Lotfi Chehma, Anne Hébraud, Emeline Lobry\",\"doi\":\"10.1002/mame.202400157\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Suspension electrospinning allows the environmental-friendly fabrication of nano-micro-fibrous membranes since it is based on the processing of an aqueous particle suspension in which a hydrosoluble template polymer is added to insure the formation of a continuous fiber. Here, the case of polyurethane (PU) aqueous suspensions formulated with poly(ethylene oxide) (PEO) as the template polymer is studied. The effect of several parameters (particle size, PU/PEO ratio, PEO molar mass, and PEO concentration in the continuous phase) on particle-particle and particle-template polymer interactions that influence the rheological properties of the formulation and finally the electrospinning and the fiber morphology, is studied. The goal is to process a formulation with the highest particle content as possible. Thanks to a deep rheological investigation and the study of interactions and suspension morphology by zeta potential and diffusing wave spectroscopy, it is shown that regular fibers are efficiently produced when small particles are electrospun under favorable particle-template polymer interactions and without screening the electrostatic repulsion between particles. Finally, a fibrous membrane is obtained from a formulation with a PU/PEO weight ratio equal to 50 under very stable and efficient production conditions.</p>\",\"PeriodicalId\":18151,\"journal\":{\"name\":\"Macromolecular Materials and Engineering\",\"volume\":\"309 12\",\"pages\":\"\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2024-08-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/mame.202400157\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Macromolecular Materials and Engineering\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/mame.202400157\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Macromolecular Materials and Engineering","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/mame.202400157","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Green Electrospinning of Highly Concentrated Polyurethane Suspensions in Water: From the Rheology to the Fiber Morphology
Suspension electrospinning allows the environmental-friendly fabrication of nano-micro-fibrous membranes since it is based on the processing of an aqueous particle suspension in which a hydrosoluble template polymer is added to insure the formation of a continuous fiber. Here, the case of polyurethane (PU) aqueous suspensions formulated with poly(ethylene oxide) (PEO) as the template polymer is studied. The effect of several parameters (particle size, PU/PEO ratio, PEO molar mass, and PEO concentration in the continuous phase) on particle-particle and particle-template polymer interactions that influence the rheological properties of the formulation and finally the electrospinning and the fiber morphology, is studied. The goal is to process a formulation with the highest particle content as possible. Thanks to a deep rheological investigation and the study of interactions and suspension morphology by zeta potential and diffusing wave spectroscopy, it is shown that regular fibers are efficiently produced when small particles are electrospun under favorable particle-template polymer interactions and without screening the electrostatic repulsion between particles. Finally, a fibrous membrane is obtained from a formulation with a PU/PEO weight ratio equal to 50 under very stable and efficient production conditions.
期刊介绍:
Macromolecular Materials and Engineering is the high-quality polymer science journal dedicated to the design, modification, characterization, processing and application of advanced polymeric materials, including membranes, sensors, sustainability, composites, fibers, foams, 3D printing, actuators as well as energy and electronic applications.
Macromolecular Materials and Engineering is among the top journals publishing original research in polymer science.
The journal presents strictly peer-reviewed Research Articles, Reviews, Perspectives and Comments.
ISSN: 1438-7492 (print). 1439-2054 (online).
Readership:Polymer scientists, chemists, physicists, materials scientists, engineers
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