浸渍了 Aliquat-336 的硅聚苯乙烯吸附铯（I）、锶（II）和钇（III）的分离可行性

IF 1.5 3区化学 Q3 CHEMISTRY, ANALYTICAL

Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2024-08-07 DOI:10.1007/s10967-024-09617-0

Moubarak A. Sayed, Mohamed I. Aly, Sahar I. El-Dessouky, Emad H. Borai

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引用次数: 0

摘要

使用浸渍有 Aliquat-336 (A-336) 和三氟丙酮（Theonyl triflouroacetone，HTTA）的硅聚苯乙烯（SPS）研究了水溶液中 Cs(I)、Sr(II) 和 Y(III)的吸附。使用傅立叶变换红外光谱、X 射线衍射和扫描电镜对合成材料 SPS、A-336@SPS 和 HTTA@SPS 进行了表征。吸附容量的顺序为铯(I)>锶(II)>钇(III)。铯（I）、锶（II）和镱（III）的吸附容量（qe）分别为 2.3、0.75 和 0.55 毫克/克。SF(Cs/Sr)、SF(Cs/Y)和 SF(Sr/Y)的最大分离因子分别为 16.01、29.32 和 1.83。A-336@SPS 对铯(I)的选择性吸附是由于 A-336@SPS 的氮原子与铯(I)形成了强络合物。

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Separation feasibility of Cs(I), Sr(II) and Y(III) adsorbed by silica polystyrene impregnated with Aliquat-336

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Separation feasibility of Cs(I), Sr(II) and Y(III) adsorbed by silica polystyrene impregnated with Aliquat-336

The adsorption of Cs(I), Sr(II) and Y(III) from aqueous solutions using silica polystyrene (SPS) impregnated with Aliquat-336 (A-336) and Theonyl triflouroacetone (HTTA) was investigated. The synthesized materials; SPS, A-336@SPS and HTTA@SPS were characterized using FTIR, XRD and SEM. The order of adsorption capacity is Cs(I)>Sr(II)>Y(III). The adsorption capacity (q_e) for Cs(I), Sr(II) and Y(III) was found to be 2.3, 0.75 and 0.55 mg/g, respectively. The maximum separation factor of SF(Cs/Sr), SF(Cs/Y) and SF(Sr/Y) was 16.01, 29.32, and 1.83, respectively. The selective adsorption of Cs(I) by A-336@SPS is attributed to the formation of strong complex between nitrogen atom of A-336@SPS and Cs(I).

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来源期刊

Journal of Radioanalytical and Nuclear Chemistry 化学-分析化学

CiteScore

2.80

自引率

18.80%

发文量

504

审稿时长

2.2 months

期刊介绍： An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.