固定在蛋壳膜上的[BMIM]Cl-AgNPs 作为吸附剂固相萃取湖水和自来水中的磺胺甲噁唑

IF 2.7 4区材料科学 Q3 CHEMISTRY, PHYSICAL

Particle & Particle Systems Characterization Pub Date : 2024-08-07 DOI:10.1002/ppsc.202400122

Nur Azila Mhd Wahi, Faris Darwish Fadzil, Sharifah Mohamad, Arniza Khairani Mohd Jamil

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引用次数: 0

摘要

通过简单的还原法合成[BMIM]Cl-AgNPs，并直接固定在ESM上，开发了一种替代固相萃取（SPE）材料--1-丁基-3-甲基氯化咪唑-银纳米颗粒/蛋壳膜（[BMIM]Cl-AgNPs/ESM）。通过高效液相色谱-二极管阵列检测器（HPLC-DAD），新开发的材料被成功应用于萃取和检测环境水样中的磺胺甲噁唑（SMX）。通过傅立叶变换红外（FTIR）和场发射扫描电子显微镜/能量色散 X 射线（FESEM/EDX）进行表征，证实了[BMIM]Cl-AgNPs 在 ESM 上的存在。采用一次一个变量（OVAT）的方法对基于[BMIM]Cl-AgNPs/ESM 的 SPE 方法进行了优化。方法验证表明，在 10-500 µg L-1 范围内线性关系良好（R2 = 0.9995），检出限和定量限分别为 3.07 µg L-1 和 9.31 µg L-1。此外，可重复使用性研究表明，所开发的材料可在不显著降低效率的情况下提取 SMX 达三个循环。在加标自来水和湖水中卓越的回收率（90.07-104.08%）证明了[BMIM]Cl-AgNPs/ESM 在痕量污染物检测方面的潜力。

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[BMIM]Cl‐AgNPs Immobilized on Eggshell Membrane as an Adsorbent for Solid Phase Extraction of Sulfamethoxazole in Lake and Tap Water

An alternative solid phase extraction (SPE) material, 1‐butyl‐3‐methylimidazolium chloride–silver nanoparticles/eggshell membrane ([BMIM]Cl‐AgNPs/ESM), is developed by synthesizing [BMIM]Cl‐AgNPs using a simple reduction method and immobilizing directly on ESM. The newly developed material is successfully applied for extraction and detection of sulfamethoxazole (SMX) in environmental aqueous samples via a high‐performance liquid chromatography‐diode array detector (HPLC‐DAD). Characterization is accomplished by Fourier transform infrared (FTIR) and field emission scanning electron microscopy/energy dispersive X‐ray (FESEM/EDX), confirming the presence of [BMIM]Cl‐AgNPs on ESM. The optimization of [BMIM]Cl‐AgNPs/ESM‐based SPE method is studied by the one variable at a time (OVAT) approach. Method validation shows good linearity (R2 = 0.9995) in the range of 10–500 µg L−1, with the detection and quantification limits determined to be 3.07 and 9.31 µg L−1 respectively. Additionally, a reusability study shows the developed material can extract SMX up for three cycles without significant reduction in its efficiency. Excellent recoveries (90.07–104.08%) in spiked tap and lake water demonstrate the potential of [BMIM]Cl‐AgNPs/ESM for trace‐level detection of pollutants.

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来源期刊

Particle & Particle Systems Characterization 工程技术-材料科学：表征与测试

CiteScore

5.50

自引率

0.00%

发文量

114

审稿时长

3.0 months

期刊介绍： Particle & Particle Systems Characterization is an international, peer-reviewed, interdisciplinary journal focusing on all aspects of particle research. The journal joined the Advanced Materials family of journals in 2013. Particle has an impact factor of 4.194 (2018 Journal Impact Factor, Journal Citation Reports (Clarivate Analytics, 2019)). Topics covered include the synthesis, characterization, and application of particles in a variety of systems and devices. Particle covers nanotubes, fullerenes, micelles and alloy clusters, organic and inorganic materials, polymers, quantum dots, 2D materials, proteins, and other molecular biological systems. Particle Systems include those in biomedicine, catalysis, energy-storage materials, environmental science, micro/nano-electromechanical systems, micro/nano-fluidics, molecular electronics, photonics, sensing, and others. Characterization methods include microscopy, spectroscopy, electrochemical, diffraction, magnetic, and scattering techniques.