Effect of Cu Addition on Abnormal Grain Growth in a FeMnAlNi-Based Superelastic Alloy

Grain size has a significant impact on the superelasticity of alloys. Large-sized grains show superior superelastic properties because the grain boundaries are minimized and the grain constraints caused by triple junctions are reduced. Cyclic heat treatment (CHT) is commonly employed to generate subgrains, whose energy can be consumed to induce abnormal grain growth (AGG) and obtain large-sized grains. In this paper, the effects of adding Cu on the subgrain characteristics during AGG and microstructural evolution of FeMnAlNi-based superelastic alloys were systematically investigated. The addition of Cu reduced the temperature at which the γ phase precipitates and altered the morphology of the γ phase. After the dissolution of the refined γ phases, the average subgrain size became smaller and misorientation increased. These characteristic subgrain changes improved the driving force for AGG and accelerated the grain boundary migration rate. Due to the addition of Cu, the maximum grain size reached 28.2 mm. This study provides a new method for the preparation of FeMnAlNi-based superelastic alloys with large-sized grains.