{"title":"提高锌离子超级电容器性能的先进设计策略和机理洞察的多重视角","authors":"","doi":"10.1016/j.ccr.2024.216097","DOIUrl":null,"url":null,"abstract":"<div><p>Zinc-ion supercapacitors (ZSCs), emerging as advanced electrochemical energy storage devices, boast of high safety, power density and energy density, as well as eco-friendliness. However, there are three key factors currently impeding the development of ZSCs, including capacity decay of unstable cathodes, hydrogen evolution in the electrolyte, and dendrite formation on the zinc anode surface. To effectively tackle these challenges, the design of ZSCs should be approached comprehensively, considering various aspects. This work delves into the fundamental principles, advantages, and prospective applications of ZSCs. Detailed strategies for enhancing ZSC performance is summarized and the underlying mechanisms is elucidated, focusing on boosting cathode capacity, inhibiting dendrite growth on the anode, and regulating the ion–solvent structure in the electrolyte. Furthermore, this work analyzes future research directions for ZSCs, aiming to expand the voltage window, enhance energy density, extend cycle life, explore various application scenarios, and more effectively address the evolving requirements of future energy storage. The comprehensive optimization of the ZSC design shows great potential for unleashing their capabilities as a high-performance energy storage technology, playing a crucial role in the domain of sustainable energy.</p></div>","PeriodicalId":289,"journal":{"name":"Coordination Chemistry Reviews","volume":null,"pages":null},"PeriodicalIF":20.3000,"publicationDate":"2024-07-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Multiple perspectives of advanced design strategies and mechanism insights on enhancing the performance of zinc-ion supercapacitors\",\"authors\":\"\",\"doi\":\"10.1016/j.ccr.2024.216097\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Zinc-ion supercapacitors (ZSCs), emerging as advanced electrochemical energy storage devices, boast of high safety, power density and energy density, as well as eco-friendliness. However, there are three key factors currently impeding the development of ZSCs, including capacity decay of unstable cathodes, hydrogen evolution in the electrolyte, and dendrite formation on the zinc anode surface. To effectively tackle these challenges, the design of ZSCs should be approached comprehensively, considering various aspects. This work delves into the fundamental principles, advantages, and prospective applications of ZSCs. Detailed strategies for enhancing ZSC performance is summarized and the underlying mechanisms is elucidated, focusing on boosting cathode capacity, inhibiting dendrite growth on the anode, and regulating the ion–solvent structure in the electrolyte. Furthermore, this work analyzes future research directions for ZSCs, aiming to expand the voltage window, enhance energy density, extend cycle life, explore various application scenarios, and more effectively address the evolving requirements of future energy storage. The comprehensive optimization of the ZSC design shows great potential for unleashing their capabilities as a high-performance energy storage technology, playing a crucial role in the domain of sustainable energy.</p></div>\",\"PeriodicalId\":289,\"journal\":{\"name\":\"Coordination Chemistry Reviews\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":20.3000,\"publicationDate\":\"2024-07-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Coordination Chemistry Reviews\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0010854524004430\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Coordination Chemistry Reviews","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010854524004430","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Multiple perspectives of advanced design strategies and mechanism insights on enhancing the performance of zinc-ion supercapacitors
Zinc-ion supercapacitors (ZSCs), emerging as advanced electrochemical energy storage devices, boast of high safety, power density and energy density, as well as eco-friendliness. However, there are three key factors currently impeding the development of ZSCs, including capacity decay of unstable cathodes, hydrogen evolution in the electrolyte, and dendrite formation on the zinc anode surface. To effectively tackle these challenges, the design of ZSCs should be approached comprehensively, considering various aspects. This work delves into the fundamental principles, advantages, and prospective applications of ZSCs. Detailed strategies for enhancing ZSC performance is summarized and the underlying mechanisms is elucidated, focusing on boosting cathode capacity, inhibiting dendrite growth on the anode, and regulating the ion–solvent structure in the electrolyte. Furthermore, this work analyzes future research directions for ZSCs, aiming to expand the voltage window, enhance energy density, extend cycle life, explore various application scenarios, and more effectively address the evolving requirements of future energy storage. The comprehensive optimization of the ZSC design shows great potential for unleashing their capabilities as a high-performance energy storage technology, playing a crucial role in the domain of sustainable energy.
期刊介绍:
Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers.
The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.