{"title":"铬含量对 Cu-Cr-Ni 桥梁耐候钢热变形行为和显微组织演变的影响","authors":"Gaoshan Xu, Tenghao Zhang, Ke Zhang, Dangwei Xu, Zhong Huang, Jinghui Li, Zhaodong Li, Zhenyi Huang","doi":"10.1002/srin.202400352","DOIUrl":null,"url":null,"abstract":"<p>The hot compression tests (<i>T</i> = 850–1100 °C, <span></span><math>\n <mover>\n <mi>ε</mi>\n <mo>˙</mo>\n </mover></math> = 0.1–10 s<sup>−1</sup>) of Cu–Cr–Ni bridge weathering steel with different Cr content (0.46% (#1), 0.64% (#2)) were performed on Gleeble-3800-D thermomechanical simulator. The effects of Cr content on hot deformation and microstructure evolution are systematically investigated by the Arrhenius constitutive equation, processing map, electron backscatter diffraction technology, and transmission electron microscope. In the results, it is demonstrated that the increase of Cr content from 0.46% to 0.64% enhances the solution strengthening and inhibits the dynamic recrystallization of the experimental steels during hot compression, resulting in the increase of flow stress. The Arrhenius constitutive equation with strain compensation is constructed. The increase of Cr content results in an augmentation of hot deformation activation energy, rising from <i>Q</i><sub>#1</sub> = 358.47 kJ mol<sup>−1</sup> to <i>Q</i><sub>#2</sub> = 396.79 kJ mol<sup>−1</sup>, causing the increase of deformation resistance of Cu–Cr–Ni bridge weathering steel in hot compression. The optimal hot processing window of #1 and #2 experimental steels is as follows: <span></span><math>\n <mover>\n <mi>ε</mi>\n <mo>˙</mo>\n </mover></math> = 0.1–0.2 s<sup>−1</sup>, <i>T</i> = 1050–1100 °C, <span></span><math>\n <mover>\n <mi>ε</mi>\n <mo>˙</mo>\n </mover></math> = 0.1–0.15 s<sup>−1</sup>, and <i>T</i> = 1050–1100 °C, the increase of Cr content leads to the narrowing of the hot processing window of the experimental steels.</p>","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of Cr Content on Hot Deformation Behavior and Microstructure Evolution of Cu–Cr–Ni Bridge Weathering Steel\",\"authors\":\"Gaoshan Xu, Tenghao Zhang, Ke Zhang, Dangwei Xu, Zhong Huang, Jinghui Li, Zhaodong Li, Zhenyi Huang\",\"doi\":\"10.1002/srin.202400352\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The hot compression tests (<i>T</i> = 850–1100 °C, <span></span><math>\\n <mover>\\n <mi>ε</mi>\\n <mo>˙</mo>\\n </mover></math> = 0.1–10 s<sup>−1</sup>) of Cu–Cr–Ni bridge weathering steel with different Cr content (0.46% (#1), 0.64% (#2)) were performed on Gleeble-3800-D thermomechanical simulator. The effects of Cr content on hot deformation and microstructure evolution are systematically investigated by the Arrhenius constitutive equation, processing map, electron backscatter diffraction technology, and transmission electron microscope. In the results, it is demonstrated that the increase of Cr content from 0.46% to 0.64% enhances the solution strengthening and inhibits the dynamic recrystallization of the experimental steels during hot compression, resulting in the increase of flow stress. The Arrhenius constitutive equation with strain compensation is constructed. The increase of Cr content results in an augmentation of hot deformation activation energy, rising from <i>Q</i><sub>#1</sub> = 358.47 kJ mol<sup>−1</sup> to <i>Q</i><sub>#2</sub> = 396.79 kJ mol<sup>−1</sup>, causing the increase of deformation resistance of Cu–Cr–Ni bridge weathering steel in hot compression. The optimal hot processing window of #1 and #2 experimental steels is as follows: <span></span><math>\\n <mover>\\n <mi>ε</mi>\\n <mo>˙</mo>\\n </mover></math> = 0.1–0.2 s<sup>−1</sup>, <i>T</i> = 1050–1100 °C, <span></span><math>\\n <mover>\\n <mi>ε</mi>\\n <mo>˙</mo>\\n </mover></math> = 0.1–0.15 s<sup>−1</sup>, and <i>T</i> = 1050–1100 °C, the increase of Cr content leads to the narrowing of the hot processing window of the experimental steels.</p>\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-08-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/srin.202400352\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/srin.202400352","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Effect of Cr Content on Hot Deformation Behavior and Microstructure Evolution of Cu–Cr–Ni Bridge Weathering Steel
The hot compression tests (T = 850–1100 °C, = 0.1–10 s−1) of Cu–Cr–Ni bridge weathering steel with different Cr content (0.46% (#1), 0.64% (#2)) were performed on Gleeble-3800-D thermomechanical simulator. The effects of Cr content on hot deformation and microstructure evolution are systematically investigated by the Arrhenius constitutive equation, processing map, electron backscatter diffraction technology, and transmission electron microscope. In the results, it is demonstrated that the increase of Cr content from 0.46% to 0.64% enhances the solution strengthening and inhibits the dynamic recrystallization of the experimental steels during hot compression, resulting in the increase of flow stress. The Arrhenius constitutive equation with strain compensation is constructed. The increase of Cr content results in an augmentation of hot deformation activation energy, rising from Q#1 = 358.47 kJ mol−1 to Q#2 = 396.79 kJ mol−1, causing the increase of deformation resistance of Cu–Cr–Ni bridge weathering steel in hot compression. The optimal hot processing window of #1 and #2 experimental steels is as follows: = 0.1–0.2 s−1, T = 1050–1100 °C, = 0.1–0.15 s−1, and T = 1050–1100 °C, the increase of Cr content leads to the narrowing of the hot processing window of the experimental steels.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
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