芳香族三氟乙烯基醚与全氟环丁基 (PFCB) 嵌段聚合物的一步法共聚反应

IF 4.1 2区化学 Q2 POLYMER SCIENCE

Polymer Chemistry Pub Date : 2024-09-20 DOI:10.1039/d4py00149d

Jiyoung Park , Tugba G. Kucukkal , Jung-Min Oh , Steven J. Stuart , Stephen E. Creager , Gustavo Muñoz , Dennis W. Smith Jr.

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引用次数: 0

摘要

我们报告了芳基三氟乙烯基醚（TFVE）向分段共聚物的选择性[2 + 2]环共聚。实验和计算研究证实，相对富电子的 TFVE 单体和贫电子的 TFVE 单体在一次聚合过程中会产生分段共聚物。此外，还研究了微结构对聚合物骨架后磺化的影响。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

One-pot single-step copolymerization of aromatic trifluorovinyl ethers toward perfluorocyclobutyl (PFCB) segmented copolymers†

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One-pot single-step copolymerization of aromatic trifluorovinyl ethers toward perfluorocyclobutyl (PFCB) segmented copolymers†

We report a selective [2 + 2] cyclo-copolymerization of aryl trifluorovinyl ethers (TFVEs) toward segmented copolymers. Experimental and computational studies confirm that copolymerization of relatively electron-rich and electron-poor TFVE monomers results in segmented copolymers in a single polymerization. The effect of microstructures on post-sulfonation in the polymer backbones was also investigated.

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来源期刊

Polymer Chemistry POLYMER SCIENCE-

CiteScore

8.60

自引率

8.70%

发文量

535

审稿时长

1.7 months

期刊介绍： Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.