磷酸二苯酯夹杂镁铝镧氢铝酸盐对聚氯乙烯热稳定性和机械性能的影响

IF 3.9 3区 化学 Q2 POLYMER SCIENCE
Jinsheng Duan, Zhaogang Liu, Yilin Li, Peijie Jia, Yanhong Hu, Jinxiu Wu
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引用次数: 0

摘要

用磷酸二苯基对镁铝镧氢滑石(MgAlLa-CO3-LDHs)进行改性,得到磷酸二苯基插层镁铝镧氢滑石(MgAlLa-P-LDHs)。对制备的材料 MgAlLa-CO3-LDHs 和 MgAlLa-P-LDHs 进行了表征技术研究,包括傅立叶变换红外光谱(FTIR)、X 射线衍射(XRD)和扫描电子显微镜(SEM),以确定其结构和形态特征。随后,将这些基于氢铝酸盐的热稳定剂加入聚氯乙烯(PVC)中,制成复合材料。通过热老化试验、拉伸实验和塑化试验,对复合材料的热稳定性、机械性能和塑化性能进行了综合评价。研究结果表明,引入基于氢铝酸盐的热稳定剂后,聚氯乙烯材料的热稳定性明显提高。此外,还观察到了机械性能和塑化性能的改善。这项研究为稀土氢铝酸盐热稳定剂在聚氯乙烯中的应用提供了全面的实验和理论基础,为开发和应用环保型聚氯乙烯热稳定剂提供了宝贵的见解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

The Effect of Diphenylphosphate Intercalated Magnesium Aluminum Lanthanum Hydrotalcite on the Thermal Stability and Mechanical Properties of Poly(Vinyl Chloride)

The Effect of Diphenylphosphate Intercalated Magnesium Aluminum Lanthanum Hydrotalcite on the Thermal Stability and Mechanical Properties of Poly(Vinyl Chloride)

Magnesium aluminum lanthanum hydrotalcite (MgAlLa-CO3-LDHs) was modified with diphenyl phosphate to obtain diphenyl phosphate-intercalated magnesium aluminum lanthanum hydrotalcite (MgAlLa-P-LDHs). The prepared materials, MgAlLa-CO3-LDHs and MgAlLa-P-LDHs, were subjected to characterization techniques, including Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), and Scanning Electron Microscopy (SEM), to ascertain their structural and morphological characteristics. Subsequently, these hydrotalcite-based thermal stabilizers were incorporated into polyvinyl chloride (PVC) to fabricate composite materials. The comprehensive evaluation of the composite materials’ thermal stability, mechanical properties, and plasticization performance was conducted through thermal aging tests, tensile experiments, and plasticization tests. The research findings indicate a significant enhancement in the thermal stability of PVC materials with the introduction of hydrotalcite-based thermal stabilizers. Additionally, there were observed improvements in mechanical properties and plasticization performance. This study provides a thorough experimental and theoretical foundation for the application of rare earth hydrotalcite-based thermal stabilizers in PVC, offering valuable insights for the development and application of environmentally friendly PVC thermal stabilizers.

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来源期刊
CiteScore
8.30
自引率
7.50%
发文量
335
审稿时长
1.8 months
期刊介绍: Journal of Inorganic and Organometallic Polymers and Materials [JIOP or JIOPM] is a comprehensive resource for reports on the latest theoretical and experimental research. This bimonthly journal encompasses a broad range of synthetic and natural substances which contain main group, transition, and inner transition elements. The publication includes fully peer-reviewed original papers and shorter communications, as well as topical review papers that address the synthesis, characterization, evaluation, and phenomena of inorganic and organometallic polymers, materials, and supramolecular systems.
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