{"title":"基于 ZIF-67/MWCNTs/Nafion 的 Cu2+ 传感器的电化学研究","authors":"Qiang Li, Lifeng Ding, Yuru Song, Qi Wang, Jie Zhang, Zhengwei Song, Shengling Li, Jiayu Liu, Xin Zhang","doi":"10.1007/s10008-024-06017-y","DOIUrl":null,"url":null,"abstract":"<div><p>In this work, a ZIF-67/MWCNTs/Nafion sensor platform was constructed based on the good adsorption capacity of ZIF-67, the electrical conductivity of multiwalled carbon nanotubes (MWCNTs), and the excellent chemical stability of Nafion for the detection of Cu<sup>2+</sup> in water. Meanwhile, the modified materials were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), BET-specific surface area test, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and Fourier-transform infrared spectrometry (FTIR). Cyclic voltammetry (CV), electrochemical impedance (EIS), and square wave stripping voltammetry (SWSV) electrochemical methods were used to perform applied test studies on ZIF-67/MWCNTs/Nafion/GCE. The results show that ZIF-67/MWCNTs/Nafion/GCE has high sensitivity (57.5 μA/μM) and a low limit of detection (15.0 nM) for the electrochemical detection of Cu<sup>2+</sup> ions in an electrochemical sensing system. It has high adsorption selectivity for Cu<sup>2+</sup>, and the recovery of Cu<sup>2+</sup> in real water reached 98.6–103%. The modified electrode has good repeatability, reproducibility, anti-interference, and stability, which means this sensing platform can be practically applied to the detection of domestic water.</p></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"28 11","pages":"4181 - 4192"},"PeriodicalIF":2.6000,"publicationDate":"2024-07-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Electrochemical study of the Cu2+ sensor based on ZIF-67/MWCNTs/Nafion\",\"authors\":\"Qiang Li, Lifeng Ding, Yuru Song, Qi Wang, Jie Zhang, Zhengwei Song, Shengling Li, Jiayu Liu, Xin Zhang\",\"doi\":\"10.1007/s10008-024-06017-y\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this work, a ZIF-67/MWCNTs/Nafion sensor platform was constructed based on the good adsorption capacity of ZIF-67, the electrical conductivity of multiwalled carbon nanotubes (MWCNTs), and the excellent chemical stability of Nafion for the detection of Cu<sup>2+</sup> in water. Meanwhile, the modified materials were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), BET-specific surface area test, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and Fourier-transform infrared spectrometry (FTIR). Cyclic voltammetry (CV), electrochemical impedance (EIS), and square wave stripping voltammetry (SWSV) electrochemical methods were used to perform applied test studies on ZIF-67/MWCNTs/Nafion/GCE. The results show that ZIF-67/MWCNTs/Nafion/GCE has high sensitivity (57.5 μA/μM) and a low limit of detection (15.0 nM) for the electrochemical detection of Cu<sup>2+</sup> ions in an electrochemical sensing system. It has high adsorption selectivity for Cu<sup>2+</sup>, and the recovery of Cu<sup>2+</sup> in real water reached 98.6–103%. The modified electrode has good repeatability, reproducibility, anti-interference, and stability, which means this sensing platform can be practically applied to the detection of domestic water.</p></div>\",\"PeriodicalId\":665,\"journal\":{\"name\":\"Journal of Solid State Electrochemistry\",\"volume\":\"28 11\",\"pages\":\"4181 - 4192\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2024-07-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Solid State Electrochemistry\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s10008-024-06017-y\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Solid State Electrochemistry","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s10008-024-06017-y","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
Electrochemical study of the Cu2+ sensor based on ZIF-67/MWCNTs/Nafion
In this work, a ZIF-67/MWCNTs/Nafion sensor platform was constructed based on the good adsorption capacity of ZIF-67, the electrical conductivity of multiwalled carbon nanotubes (MWCNTs), and the excellent chemical stability of Nafion for the detection of Cu2+ in water. Meanwhile, the modified materials were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), BET-specific surface area test, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and Fourier-transform infrared spectrometry (FTIR). Cyclic voltammetry (CV), electrochemical impedance (EIS), and square wave stripping voltammetry (SWSV) electrochemical methods were used to perform applied test studies on ZIF-67/MWCNTs/Nafion/GCE. The results show that ZIF-67/MWCNTs/Nafion/GCE has high sensitivity (57.5 μA/μM) and a low limit of detection (15.0 nM) for the electrochemical detection of Cu2+ ions in an electrochemical sensing system. It has high adsorption selectivity for Cu2+, and the recovery of Cu2+ in real water reached 98.6–103%. The modified electrode has good repeatability, reproducibility, anti-interference, and stability, which means this sensing platform can be practically applied to the detection of domestic water.
期刊介绍：
The Journal of Solid State Electrochemistry is devoted to all aspects of solid-state chemistry and solid-state physics in electrochemistry.
The Journal of Solid State Electrochemistry publishes papers on all aspects of electrochemistry of solid compounds, including experimental and theoretical, basic and applied work. It equally publishes papers on the thermodynamics and kinetics of electrochemical reactions if at least one actively participating phase is solid. Also of interest are articles on the transport of ions and electrons in solids whenever these processes are relevant to electrochemical reactions and on the use of solid-state electrochemical reactions in the analysis of solids and their surfaces.
The journal covers solid-state electrochemistry and focusses on the following fields: mechanisms of solid-state electrochemical reactions, semiconductor electrochemistry, electrochemical batteries, accumulators and fuel cells, electrochemical mineral leaching, galvanic metal plating, electrochemical potential memory devices, solid-state electrochemical sensors, ion and electron transport in solid materials and polymers, electrocatalysis, photoelectrochemistry, corrosion of solid materials, solid-state electroanalysis, electrochemical machining of materials, electrochromism and electrochromic devices, new electrochemical solid-state synthesis.
The Journal of Solid State Electrochemistry makes the professional in research and industry aware of this swift progress and its importance for future developments and success in the above-mentioned fields.
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