{"title":"干燥条件下混凝土中氧气扩散的跨尺度预测模型","authors":"Chuanye Su, Jun Xu, Wei She, Chuanqing Fu","doi":"10.1007/s11242-024-02116-6","DOIUrl":null,"url":null,"abstract":"<div><p>The rate of oxygen diffusion directly affects the distribution of oxygen concentration within concrete, which in turn influences the corrosion performance of reinforcing steel within the concrete. However, research on cross-scale prediction models for oxygen diffusion in dry concrete is still lacking. In this study, the complex pore structure of concrete is simplified into a sponge model, and three types of diffusion are quantitatively characterized based on the pore size distribution density function. The influence of porosity, water–cement ratio, hydration degree, gel–space ratio and pore tortuosity on the oxygen diffusion coefficient is considered, and a cross-scale prediction model for oxygen diffusion in dry concrete is established. Secondly, an oxygen diffusion coefficient determination device developed independently is used to measure the oxygen diffusion coefficient of concrete specimens under dry conditions. The results show that the experimental values agree well with the calculated values, and the model is compared with other models proposed by scholars, verifying its superiority and accuracy. Finally, a parameter sensitivity analysis is conducted on five microscale parameters and their influence on the behavior of oxygen transmission into concrete is discussed. The establishment of the cross-scale prediction model for oxygen diffusion in dry concrete will first provide a positive role in the theoretical research on reinforcement expansion and cracking, and secondly, it will be able to better explain the mechanism of oxygen diffusion in concrete.</p></div>","PeriodicalId":804,"journal":{"name":"Transport in Porous Media","volume":"151 12","pages":"2357 - 2385"},"PeriodicalIF":2.7000,"publicationDate":"2024-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Cross-Scale Prediction Model of Oxygen Diffusion in Concrete Under Dry Conditions\",\"authors\":\"Chuanye Su, Jun Xu, Wei She, Chuanqing Fu\",\"doi\":\"10.1007/s11242-024-02116-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The rate of oxygen diffusion directly affects the distribution of oxygen concentration within concrete, which in turn influences the corrosion performance of reinforcing steel within the concrete. However, research on cross-scale prediction models for oxygen diffusion in dry concrete is still lacking. In this study, the complex pore structure of concrete is simplified into a sponge model, and three types of diffusion are quantitatively characterized based on the pore size distribution density function. The influence of porosity, water–cement ratio, hydration degree, gel–space ratio and pore tortuosity on the oxygen diffusion coefficient is considered, and a cross-scale prediction model for oxygen diffusion in dry concrete is established. Secondly, an oxygen diffusion coefficient determination device developed independently is used to measure the oxygen diffusion coefficient of concrete specimens under dry conditions. The results show that the experimental values agree well with the calculated values, and the model is compared with other models proposed by scholars, verifying its superiority and accuracy. Finally, a parameter sensitivity analysis is conducted on five microscale parameters and their influence on the behavior of oxygen transmission into concrete is discussed. The establishment of the cross-scale prediction model for oxygen diffusion in dry concrete will first provide a positive role in the theoretical research on reinforcement expansion and cracking, and secondly, it will be able to better explain the mechanism of oxygen diffusion in concrete.</p></div>\",\"PeriodicalId\":804,\"journal\":{\"name\":\"Transport in Porous Media\",\"volume\":\"151 12\",\"pages\":\"2357 - 2385\"},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2024-07-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transport in Porous Media\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11242-024-02116-6\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transport in Porous Media","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s11242-024-02116-6","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Cross-Scale Prediction Model of Oxygen Diffusion in Concrete Under Dry Conditions
The rate of oxygen diffusion directly affects the distribution of oxygen concentration within concrete, which in turn influences the corrosion performance of reinforcing steel within the concrete. However, research on cross-scale prediction models for oxygen diffusion in dry concrete is still lacking. In this study, the complex pore structure of concrete is simplified into a sponge model, and three types of diffusion are quantitatively characterized based on the pore size distribution density function. The influence of porosity, water–cement ratio, hydration degree, gel–space ratio and pore tortuosity on the oxygen diffusion coefficient is considered, and a cross-scale prediction model for oxygen diffusion in dry concrete is established. Secondly, an oxygen diffusion coefficient determination device developed independently is used to measure the oxygen diffusion coefficient of concrete specimens under dry conditions. The results show that the experimental values agree well with the calculated values, and the model is compared with other models proposed by scholars, verifying its superiority and accuracy. Finally, a parameter sensitivity analysis is conducted on five microscale parameters and their influence on the behavior of oxygen transmission into concrete is discussed. The establishment of the cross-scale prediction model for oxygen diffusion in dry concrete will first provide a positive role in the theoretical research on reinforcement expansion and cracking, and secondly, it will be able to better explain the mechanism of oxygen diffusion in concrete.
期刊介绍:
-Publishes original research on physical, chemical, and biological aspects of transport in porous media-
Papers on porous media research may originate in various areas of physics, chemistry, biology, natural or materials science, and engineering (chemical, civil, agricultural, petroleum, environmental, electrical, and mechanical engineering)-
Emphasizes theory, (numerical) modelling, laboratory work, and non-routine applications-
Publishes work of a fundamental nature, of interest to a wide readership, that provides novel insight into porous media processes-
Expanded in 2007 from 12 to 15 issues per year.
Transport in Porous Media publishes original research on physical and chemical aspects of transport phenomena in rigid and deformable porous media. These phenomena, occurring in single and multiphase flow in porous domains, can be governed by extensive quantities such as mass of a fluid phase, mass of component of a phase, momentum, or energy. Moreover, porous medium deformations can be induced by the transport phenomena, by chemical and electro-chemical activities such as swelling, or by external loading through forces and displacements. These porous media phenomena may be studied by researchers from various areas of physics, chemistry, biology, natural or materials science, and engineering (chemical, civil, agricultural, petroleum, environmental, electrical, and mechanical engineering).