{"title":"幸运一击:测试二氧化锰粉末在尼安德特人撞击生火中的作用","authors":"Andrew C. Sorensen","doi":"10.1007/s12520-024-02047-9","DOIUrl":null,"url":null,"abstract":"<div><p>Late Middle Palaeolithic Neandertals in France are known to have engaged in the collection and grinding of black minerals rich in manganese dioxide (MnO<sub>2</sub>), generally presumed for symbolic use as powdered pigments. However, lab-based experiments conducted by Heyes and colleagues (Sci Rep 6: 22159, 2016) have shown that the addition of powdered MnO<sub>2</sub> to wood turnings both reduces the temperature required for combustion by ca. 80–180 °C and significantly increases the rate of combustion. This special pyrotechnic property of powdered MnO<sub>2</sub> may have been observed and leveraged by Neandertals to aid in fire making—a technology known to Neandertals in this region by at least 50,000 years ago. To test this idea, a series of actualistic fire-making experiments were performed to determine the practical applicability of MnO<sub>2</sub> as a tinder-enhancing additive. The flint-and-pyrite percussive fire-making method was employed to produce sparks that were directed onto eight different types of tinder common to temperate Northwest Europe to determine if and to what degree the addition of MnO<sub>2</sub> powder improved their ability to capture sparks that then propagate into glowing embers. The results show that MnO<sub>2</sub> does indeed considerably improve the ignition efficiency of tinder material over untreated tinder, both in terms of the point of first ignition and the total number of ignitions achieved. It was observed, however, that the incidental addition of pyrite dust onto a tinder over the course of an experiment also appeared to improve its ability to capture sparks. Supplemental experiments using tinder pre-mixed with powdered pyrite confirmed this hypothesis, suggesting pyrite powder similarly expedites fire production. While this finding may raise questions regarding the need for collecting MnO<sub>2</sub> for this purpose, its potential utility may lie in (1) its relative softness compared to pyrite, making it much easier to grind or scrape into powder, and (2) the greater potential for MnO<sub>2</sub>-bearing deposits to yield larger quantities of usable raw material compared to pyrite-bearing outcrops, making it relatively more abundant in some areas. Thus, when available, it is clear that adding MnO<sub>2</sub> to tinder would have noticeably reduced the time and energy required to produce fire, making it a potentially novel Neandertal innovation complementary to the fire-making process.</p></div>","PeriodicalId":8214,"journal":{"name":"Archaeological and Anthropological Sciences","volume":"16 8","pages":""},"PeriodicalIF":2.1000,"publicationDate":"2024-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s12520-024-02047-9.pdf","citationCount":"0","resultStr":"{\"title\":\"Lucky strike: testing the utility of manganese dioxide powder in Neandertal percussive fire making\",\"authors\":\"Andrew C. Sorensen\",\"doi\":\"10.1007/s12520-024-02047-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Late Middle Palaeolithic Neandertals in France are known to have engaged in the collection and grinding of black minerals rich in manganese dioxide (MnO<sub>2</sub>), generally presumed for symbolic use as powdered pigments. However, lab-based experiments conducted by Heyes and colleagues (Sci Rep 6: 22159, 2016) have shown that the addition of powdered MnO<sub>2</sub> to wood turnings both reduces the temperature required for combustion by ca. 80–180 °C and significantly increases the rate of combustion. This special pyrotechnic property of powdered MnO<sub>2</sub> may have been observed and leveraged by Neandertals to aid in fire making—a technology known to Neandertals in this region by at least 50,000 years ago. To test this idea, a series of actualistic fire-making experiments were performed to determine the practical applicability of MnO<sub>2</sub> as a tinder-enhancing additive. The flint-and-pyrite percussive fire-making method was employed to produce sparks that were directed onto eight different types of tinder common to temperate Northwest Europe to determine if and to what degree the addition of MnO<sub>2</sub> powder improved their ability to capture sparks that then propagate into glowing embers. The results show that MnO<sub>2</sub> does indeed considerably improve the ignition efficiency of tinder material over untreated tinder, both in terms of the point of first ignition and the total number of ignitions achieved. It was observed, however, that the incidental addition of pyrite dust onto a tinder over the course of an experiment also appeared to improve its ability to capture sparks. Supplemental experiments using tinder pre-mixed with powdered pyrite confirmed this hypothesis, suggesting pyrite powder similarly expedites fire production. While this finding may raise questions regarding the need for collecting MnO<sub>2</sub> for this purpose, its potential utility may lie in (1) its relative softness compared to pyrite, making it much easier to grind or scrape into powder, and (2) the greater potential for MnO<sub>2</sub>-bearing deposits to yield larger quantities of usable raw material compared to pyrite-bearing outcrops, making it relatively more abundant in some areas. Thus, when available, it is clear that adding MnO<sub>2</sub> to tinder would have noticeably reduced the time and energy required to produce fire, making it a potentially novel Neandertal innovation complementary to the fire-making process.</p></div>\",\"PeriodicalId\":8214,\"journal\":{\"name\":\"Archaeological and Anthropological Sciences\",\"volume\":\"16 8\",\"pages\":\"\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2024-07-29\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://link.springer.com/content/pdf/10.1007/s12520-024-02047-9.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Archaeological and Anthropological Sciences\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s12520-024-02047-9\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ANTHROPOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Archaeological and Anthropological Sciences","FirstCategoryId":"89","ListUrlMain":"https://link.springer.com/article/10.1007/s12520-024-02047-9","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ANTHROPOLOGY","Score":null,"Total":0}
Lucky strike: testing the utility of manganese dioxide powder in Neandertal percussive fire making
Late Middle Palaeolithic Neandertals in France are known to have engaged in the collection and grinding of black minerals rich in manganese dioxide (MnO2), generally presumed for symbolic use as powdered pigments. However, lab-based experiments conducted by Heyes and colleagues (Sci Rep 6: 22159, 2016) have shown that the addition of powdered MnO2 to wood turnings both reduces the temperature required for combustion by ca. 80–180 °C and significantly increases the rate of combustion. This special pyrotechnic property of powdered MnO2 may have been observed and leveraged by Neandertals to aid in fire making—a technology known to Neandertals in this region by at least 50,000 years ago. To test this idea, a series of actualistic fire-making experiments were performed to determine the practical applicability of MnO2 as a tinder-enhancing additive. The flint-and-pyrite percussive fire-making method was employed to produce sparks that were directed onto eight different types of tinder common to temperate Northwest Europe to determine if and to what degree the addition of MnO2 powder improved their ability to capture sparks that then propagate into glowing embers. The results show that MnO2 does indeed considerably improve the ignition efficiency of tinder material over untreated tinder, both in terms of the point of first ignition and the total number of ignitions achieved. It was observed, however, that the incidental addition of pyrite dust onto a tinder over the course of an experiment also appeared to improve its ability to capture sparks. Supplemental experiments using tinder pre-mixed with powdered pyrite confirmed this hypothesis, suggesting pyrite powder similarly expedites fire production. While this finding may raise questions regarding the need for collecting MnO2 for this purpose, its potential utility may lie in (1) its relative softness compared to pyrite, making it much easier to grind or scrape into powder, and (2) the greater potential for MnO2-bearing deposits to yield larger quantities of usable raw material compared to pyrite-bearing outcrops, making it relatively more abundant in some areas. Thus, when available, it is clear that adding MnO2 to tinder would have noticeably reduced the time and energy required to produce fire, making it a potentially novel Neandertal innovation complementary to the fire-making process.
期刊介绍:
Archaeological and Anthropological Sciences covers the full spectrum of natural scientific methods with an emphasis on the archaeological contexts and the questions being studied. It bridges the gap between archaeologists and natural scientists providing a forum to encourage the continued integration of scientific methodologies in archaeological research.
Coverage in the journal includes: archaeology, geology/geophysical prospection, geoarchaeology, geochronology, palaeoanthropology, archaeozoology and archaeobotany, genetics and other biomolecules, material analysis and conservation science.
The journal is endorsed by the German Society of Natural Scientific Archaeology and Archaeometry (GNAA), the Hellenic Society for Archaeometry (HSC), the Association of Italian Archaeometrists (AIAr) and the Society of Archaeological Sciences (SAS).