MF-HCl(M = Li+、Na+、$${text{NH}}_{4}^{ + }$$)蚀刻体系的成分对 Ti3C2Tx/TiOx 纳米复合材料气体传感性能的影响

IF 1.8 3区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR
E. P. Simonenko, A. S. Mokrushin, I. A. Nagornov, V. M. Sapronova, Yu. M. Gorban, Ph. Yu. Gorobtsov, T. L. Simonenko, N. P. Simonenko, N. T. Kuznetsov
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引用次数: 0

摘要

摘要 研究了 MF-HCl(M = Li+、Na+、\({text\{NH}}_{4}^{ + }\) 蚀刻体系的性质对基于 Ti3AlC2 MAX 相的 Ti3C2Tx MXenes 的合成、微观结构、相纯度、层间距离、功能表面基团的组成、热行为和所得产物的功函数的影响。在室温下,测试了通过微绘图仪印刷沉积的 Ti3C2Tx 受体层对多种气体分析物(H2、CO、NH3、NO2、O2、苯、丙酮、甲烷和乙醇)的气敏特性。在接触氟化钠和氟化铵的盐酸溶液后生成的 MXenes 中,检测到对氨的灵敏度增加;在使用 LiF-HCl 系统合成的样品中,检测到对一氧化碳的灵敏度增加。对所有三种受体材料都测得了较高的响应(每 100 ppm NO2 约 20-30%);但是,传感器的恢复过程要困难得多。为了改善传感特性,敏感的 Ti3C2Tx 层在空气环境中进行了相对低温的热处理,形成了 Ti3C2Tx/TiOx 纳米复合材料。研究发现,在极低的工作温度(125-175°C)下,部分氧化的 MXenes 对氧气有很高的选择性反应,这在使用 HCl-NaF 系统生产的材料中尤为典型。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Influence of the Composition of the MF–HCl (M = Li+, Na+, $${\text{NH}}_{4}^{ + }$$ ) Etching System on the Gas-Sensing Properties of Ti3C2Tx/TiOx Nanocomposites

Influence of the Composition of the MF–HCl (M = Li+, Na+, $${\text{NH}}_{4}^{ + }$$ ) Etching System on the Gas-Sensing Properties of Ti3C2Tx/TiOx Nanocomposites

Abstract

A study was made of the effect of the nature of the MF–HCl (M = Li+, Na+, \({\text{NH}}_{4}^{ + }\)) etching systems on the synthesis of Ti3C2Tx MXenes based on the Ti3AlC2 MAX phase, microstructure, phase purity, interlayer distance, composition of functional surface groups, thermal behavior, and work function of the resulting products. The gas-sensing properties of Ti3C2Tx receptor layers deposited by microplotter printing were tested to a wide range of gaseous analytes (H2, CO, NH3, NO2, O2, benzene, acetone, methane, and ethanol) at room temperature. An increased sensitivity to ammonia was detected for MXenes produced by exposure to hydrochloric acid solutions of sodium and ammonium fluorides, and an elevated sensitivity to carbon monoxide was determined for a sample synthesized using the LiF–HCl system. High responses (~20–30% per 100 ppm NO2) were measured for all three receptor materials; however, sensor recovery processes were much more difficult. To improve the sensory characteristics, the sensitive Ti3C2Tx layers were subjected to relatively low temperature heat-treatment in an air atmosphere to form Ti3C2Tx/TiOx nanocomposites. It was detected that partially oxidized MXenes exhibit a high selective response to oxygen at very low operating temperatures (125–175°C), which is especially typical of the material produced using the HCl–NaF system.

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来源期刊
Russian Journal of Inorganic Chemistry
Russian Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
3.10
自引率
38.10%
发文量
237
审稿时长
3 months
期刊介绍: Russian Journal of Inorganic Chemistry is a monthly periodical that covers the following topics of research: the synthesis and properties of inorganic compounds, coordination compounds, physicochemical analysis of inorganic systems, theoretical inorganic chemistry, physical methods of investigation, chemistry of solutions, inorganic materials, and nanomaterials.
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