Abdulqadier Hussien Al khazraji, Mostefe Khalid Mohammed, Alaa Hasan Fahmi, Sahar H. Mourad
{"title":"利用 γ-Al2O3 纳米粒子去除伊拉克原油中的硫化合物","authors":"Abdulqadier Hussien Al khazraji, Mostefe Khalid Mohammed, Alaa Hasan Fahmi, Sahar H. Mourad","doi":"10.4314/bcse.v38i5.4","DOIUrl":null,"url":null,"abstract":"γ-Al2O3 nanoparticles have been synthesized using aluminium(III) sulfate as a source of metal. Ceratonia silique leaves extract was used as a reducing agent and sodium hydroxide solution as a precipitating. XRD, BET, FE-SEM, EDX, and DLS Techniques were used to characterize the prepared alumina. The desulfurization process was applied by adsorption of sulfur compounds from Iraqi crude oil using the prepared γ-Al2O3 nanoparticles. The efficiency of aluminium oxide nanoparticles as an adsorbent was studied for different factors such as adsorbent quantity, contact time, pH, and temperature. The average size of γ-Al2O3 nanoparticles is 12.44 nm, with a size distribution of particles from 90 nm to 900 nm. The mixture was drained at 80 ºC, and then calcined at 600 ºC, BET analysis shows a high surface area (72.03 m2 g-1) and uniform pore sizes of Al2O3 NPs. The FE-SEM images showed that the nanoparticles appeared smooth and cylinder-shaped within the average size of 100.53 nm. The obtained results of removal of the sulfur compounds from crude oil using γ-Al2O3 nanoparticles showed a high desulfurization and were achieved with adsorbent at specific conditions: 150 min, 0.5 g of adsorbent, temperature at 25 ºC and acidic medium pH = 2. \nKEY WORDS: Crude oil, γ-Al2O3 nanoparticles, Ceratonia siliqua leaves extract \nBull. Chem. Soc. Ethiop. 2024, 38(5), 1241-1250. \nDOI: https://dx.doi.org/10.4314/bcse.v38i5.4 ","PeriodicalId":9501,"journal":{"name":"Bulletin of the Chemical Society of Ethiopia","volume":null,"pages":null},"PeriodicalIF":1.3000,"publicationDate":"2024-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Removal of sulfur compounds from Iraqi crude oil using γ-Al2O3 nanoparticles\",\"authors\":\"Abdulqadier Hussien Al khazraji, Mostefe Khalid Mohammed, Alaa Hasan Fahmi, Sahar H. Mourad\",\"doi\":\"10.4314/bcse.v38i5.4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"γ-Al2O3 nanoparticles have been synthesized using aluminium(III) sulfate as a source of metal. Ceratonia silique leaves extract was used as a reducing agent and sodium hydroxide solution as a precipitating. XRD, BET, FE-SEM, EDX, and DLS Techniques were used to characterize the prepared alumina. The desulfurization process was applied by adsorption of sulfur compounds from Iraqi crude oil using the prepared γ-Al2O3 nanoparticles. The efficiency of aluminium oxide nanoparticles as an adsorbent was studied for different factors such as adsorbent quantity, contact time, pH, and temperature. The average size of γ-Al2O3 nanoparticles is 12.44 nm, with a size distribution of particles from 90 nm to 900 nm. The mixture was drained at 80 ºC, and then calcined at 600 ºC, BET analysis shows a high surface area (72.03 m2 g-1) and uniform pore sizes of Al2O3 NPs. The FE-SEM images showed that the nanoparticles appeared smooth and cylinder-shaped within the average size of 100.53 nm. The obtained results of removal of the sulfur compounds from crude oil using γ-Al2O3 nanoparticles showed a high desulfurization and were achieved with adsorbent at specific conditions: 150 min, 0.5 g of adsorbent, temperature at 25 ºC and acidic medium pH = 2. \\nKEY WORDS: Crude oil, γ-Al2O3 nanoparticles, Ceratonia siliqua leaves extract \\nBull. Chem. Soc. Ethiop. 2024, 38(5), 1241-1250. \\nDOI: https://dx.doi.org/10.4314/bcse.v38i5.4 \",\"PeriodicalId\":9501,\"journal\":{\"name\":\"Bulletin of the Chemical Society of Ethiopia\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.3000,\"publicationDate\":\"2024-07-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Bulletin of the Chemical Society of Ethiopia\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.4314/bcse.v38i5.4\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Bulletin of the Chemical Society of Ethiopia","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.4314/bcse.v38i5.4","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Removal of sulfur compounds from Iraqi crude oil using γ-Al2O3 nanoparticles
γ-Al2O3 nanoparticles have been synthesized using aluminium(III) sulfate as a source of metal. Ceratonia silique leaves extract was used as a reducing agent and sodium hydroxide solution as a precipitating. XRD, BET, FE-SEM, EDX, and DLS Techniques were used to characterize the prepared alumina. The desulfurization process was applied by adsorption of sulfur compounds from Iraqi crude oil using the prepared γ-Al2O3 nanoparticles. The efficiency of aluminium oxide nanoparticles as an adsorbent was studied for different factors such as adsorbent quantity, contact time, pH, and temperature. The average size of γ-Al2O3 nanoparticles is 12.44 nm, with a size distribution of particles from 90 nm to 900 nm. The mixture was drained at 80 ºC, and then calcined at 600 ºC, BET analysis shows a high surface area (72.03 m2 g-1) and uniform pore sizes of Al2O3 NPs. The FE-SEM images showed that the nanoparticles appeared smooth and cylinder-shaped within the average size of 100.53 nm. The obtained results of removal of the sulfur compounds from crude oil using γ-Al2O3 nanoparticles showed a high desulfurization and were achieved with adsorbent at specific conditions: 150 min, 0.5 g of adsorbent, temperature at 25 ºC and acidic medium pH = 2.
KEY WORDS: Crude oil, γ-Al2O3 nanoparticles, Ceratonia siliqua leaves extract
Bull. Chem. Soc. Ethiop. 2024, 38(5), 1241-1250.
DOI: https://dx.doi.org/10.4314/bcse.v38i5.4
期刊介绍:
The Bulletin of the Chemical Society of Ethiopia (BCSE) is a triannual publication of the Chemical Society of Ethiopia. The BCSE is an open access and peer reviewed journal. The BCSE invites contributions in any field of basic and applied chemistry.