Gusti Agung, Kade Suriadi, Dewa Ngakan, Ketut Putra Negara, Tjokorda Gede, Tirta Nindhia, I. Ketut, Adi Atmika, Made Dwi, Budiana Penindra, I. Made, Gatot Karohika
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引用次数: 0
摘要
活性炭(AC)是一种多功能吸附剂,由于其孔隙结构具有较大的孔隙体积和表面积,因此具有很高的吸附能力。然而,其孔隙结构特性在很大程度上受原材料的化学成分和制造条件的影响。本研究考察了活化加热速率参数对柚木锯屑 AC 中孔隙结构和亚甲基蓝吸附的影响。吸附剂分别在 105、750 和 700 °C 下脱水、碳化和活化,温度分别为 2 小时、50 分钟和 6 至 14 °C/分钟,氮气流速为 200 mL/分钟,持续 50 分钟。对 AC 的孔隙结构、近似物质、官能团、表面形态和亚甲基蓝吸附能力进行了多项表征。结果表明,活化加热速率为 10 °C/min 时,吸附甲基溴的性能和能力最佳。获得的 AC 具有 C-C 芳环官能团,无定形晶体结构,平面间长度为 3.03 Å,固定碳含量为 75.74 %,孔表面积为 126.279 m2/g,孔体积为 0.235 cc/g,微孔-介孔尺寸分布呈多模态。此外,亚甲基蓝的吸附能力为 13.48 毫克/克。
The Impact of Activation Heating Rate on Pore Structure in Teak Sawdust-Derived Activated Carbon and Its Application in Methylene Blue Adsorption
Activated carbon (AC) is a multifunctional adsorbent with a high adsorption capacity because of its pore structure comprising a large pore volume and surface area. However, its pore structure properties are largely influenced by the chemical composition and manufacturing conditions of the raw material. This study examined the effect of activation heating rate parameter on pore structure and methylene blue adsorption in teak sawdust AC. The adsorbent was dehydrated, carbonized and activated at 105, 750 and 700 °C for 2 h, 50 min, and 6 to 14 °C/min, with a nitrogen flow rate of 200 mL/min for 50 min. Several characterizations were carried out to identify pore structure, proximate substance, functional groups, surface morphology, and methylene blue-adsorption capacity of AC. The results showed that activation heating rate with the best properties and capacity of MB adsorption were adsorbed at a peak of 10 °C/min. AC obtained has a C-C aromatic rings functional group, an amorphous crystal structure, an interplanar length of 3.03 Å, 75.74 % fixed carbon, pore surface area of 126.279 m2/g, pore volume of 0.235 cc/g, and a multimodal micropore-mesopore size distribution. This is in addition to adsorption capability of 13.48 mg/g for methylene blue.